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1.
Model systems for flavoenzyme activity: flavin-functionalised SAMs as models for probing redox modulation through hydrogen bonding.
Cooke, Graeme; Duclairoir, Florence M A; John, Phillip; Polwart, Neil; Rotello, Vincent M.
Chem Commun (Camb) ; (19): 2468-9, 2003 Oct 07.
Article in English | MEDLINE | ID: mdl-14587735

ABSTRACT

We report the fabrication of flavin-functionalised self-assembled monolayers upon gold electrodes and their subsequent redox modulation via hydrogen bonding to 2,6-diethylamidopyridine.


Subject(s)
Flavins/chemistry , Amides/chemistry , Electrolysis , Enzymes, Immobilized , Flavoproteins/chemistry , Hydrogen Bonding , Hydrogen-Ion Concentration , Kinetics , Molecular Structure , NADH, NADPH Oxidoreductases/chemistry , Oxidation-Reduction , Pyridines/chemistry
2.
Electrochemically controlled interactions between TTF-based dendrimers and an electron-rich oligomer.
Beeby, Andrew; Bryce, Martin R; Christensen, Christian A; Cooke, Graeme; Duclairoir, Florence M A; Rotello, Vincent M.
Chem Commun (Camb) ; (24): 2950-1, 2002 Dec 21.
Article in English | MEDLINE | ID: mdl-12536761

ABSTRACT

Electrochemically controlled interactions have been shown to occur between TTF containing dendrimers 1 and 2 and the electron-rich oligomer 3.

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