ABSTRACT
We present a method for incorporating image-charge effects into the description of charge transport through molecular devices. A simple model allows us to calculate the adjustment of the transport levels, due to the polarization of the electrodes as charge is added to and removed from the molecule. For this, we use the charge distributions of the molecule between two metal electrodes in several charge states, rather than in gas phase, as obtained from a density-functional theory-based transport code. This enables us to efficiently model level shifts and gap renormalization caused by image-charge effects, which are essential for understanding molecular transport experiments. We apply the method to benzene di-amine molecules and compare our results with the standard approach based on gas phase charges. Finally, we give a detailed account of the application of our approach to porphyrin-derivative devices recently studied experimentally by Perrin et al. [Nat. Nanotechnol. 8, 282 (2013)], which demonstrates the importance of accounting for image-charge effects when modeling transport through molecular junctions.
ABSTRACT
The magnetic field and temperature dependence of the transverse and longitudinal plasmons in SmLa(0.8)Sr(0.2)CuO(4-delta) have been investigated. A transition between a vortex-glass and a vortex-liquid regime, which revealed different field dependencies of the resonance frequencies, could be clearly observed. The positions and the spectral weights of the plasmons were successfully described using the multilayer model [Phys. Rev. B 64, 024530 (2001)], which takes the compressibility of the electronic liquid into account. The absolute value of the compressibility is close to that of a two-dimensional noninteracting electron gas.
ABSTRACT
We investigated the temperature dependence and c-axis magnetic field dependence of the Josephson plasma resonance in optimally doped Tl2Ba2CaCu2O8 thin films and underdoped YBa2Cu3O6.5 (YBCO) ortho-II single crystals using infrared spectroscopy. We obtained the c-axis penetration depths, at low temperature, in zero fields of about 20 and 7 microm, respectively. While the temperature dependencies of the resonances in the two compounds are very similar, the magnetic field dependence in YBCO is much weaker. We attribute this weak magnetic field dependence to the lower anisotropy of YBCO and interpret the observed behaviors in terms of thermal fluctuations and pinning of pancake vortices.
ABSTRACT
We present microwave and infrared measurements on SmLa0.8Sr0.2CuO4-delta, which are direct evidence for the existence of a transverse optical plasma mode, observed as a peak in the c-axis optical conductivity. This mode appears as a consequence of the existence of two different intrinsic Josephson couplings between the CuO2 layers, one with a Sm2O2 block layer, and the other one with a (La,Sr)2O2-delta block layer. From the frequencies and the intensities of the collective modes we determine the value of the compressibility of the two dimensional electron fluid in the copper oxygen planes.
ABSTRACT
Six patients with ankle joint's injuries had with muscle transposition by peroneus brevis. We observed them for three months. The important point was functional state of sort tissue. Wound healing of these patients were per primam except one of them. None of the patients had functional deficit.
