PCDD/F- and PAH-emission from house heating systems.

Combustion experiments were carried out in different house heating systems using various fuels. The emission samples and the chimney soot samples were analyzed for polychlorinated dibenzo-p-dioxins/furans (PCDD/F) and polycyclic-aromatic-hydrocarbons (PAH). The PCDD/F-concentrations in fluegases using untreated wood were in the range of 2-25 pg I-TE/m3. The combustion of paper, cartons, painted wood and wood with 2-5% PVC gave PCDD/F-concentrations from 38 to 952 pg I-TE/m3 and 380 to 2,240 ng I-TE/kg (chimney soot). The PAH-concentrations in flue gas were about 30 times higher using an old technology in relation to a new one.

Polyhalogenated dibenzo-p-dioxins and dibenzofurans in the exhaust air during textile processings.

5 textile finishing processes were investigated for polychlorinated dibenzo-p-dioxins/furans (PCDD/F), polybrominated dibenzo-p-dioxins/furans (PBDD/F) and mixed polychlorinated-brominated dibenzo-p-dioxins/furans (PBCDD/F). For the purpose of these investigations the complete balance--dioxins input from the raw textiles, output over the finished textiles and output through the air path--was done. In the exhaust air only small PXDD/F concentration were detected. The textiles contain before and after the process nearly the same PCDD/F-concentrations. The concentrations of PBCDD/F arises after the process. Only the chimney depositions contain higher PCDD/F-concentrations up to 1,806.1 ng I-TE/kg, PBDD/F-concentrations up to 1,572.6 ng/kg and PBCDD/F-concentrations up to 40,801.4 ng/kg.