1.
Eur J Mass Spectrom (Chichester)
; 27(2-4): 101-106, 2021 Apr.
Article
in English
| MEDLINE
| ID: mdl-34187348
ABSTRACT
Alkali metal chloroaurates(III) were analysed by laser desorption ionization mass spectrometry. Among a number of generated gas-phase ionic clusters, the unusual ions [MAu2Cl5]- (were M stands for Na, K, Rb, Cs) were detected. The spectra of metastable ions and quantum mechanics calculations show the presence of unprecedented Au(I)-Au(II) interactions in the clusters.
