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1.
Phys Rev Lett ; 132(24): 240805, 2024 Jun 14.
Article in English | MEDLINE | ID: mdl-38949370

ABSTRACT

In many natural and engineered systems, unknown quantum channels act on a subsystem that cannot be directly controlled and measured, but is instead learned through a controllable subsystem that weakly interacts with it. We study quantum channel discrimination (QCD) under these restrictions, which we call hidden system QCD. We find sequential protocols achieve perfect discrimination and saturate the Heisenberg limit. In contrast, depth-1 parallel and multishot protocols cannot solve hidden system QCD. This suggests sequential protocols are superior in experimentally realistic situations.

2.
J Chem Theory Comput ; 19(8): 2230-2247, 2023 Apr 25.
Article in English | MEDLINE | ID: mdl-37001026

ABSTRACT

We extend molecular bootstrap embedding to make it appropriate for implementation on a quantum computer. This enables solution of the electronic structure problem of a large molecule as an optimization problem for a composite Lagrangian governing fragments of the total system, in such a way that fragment solutions can harness the capabilities of quantum computers. By employing state-of-art quantum subroutines including the quantum SWAP test and quantum amplitude amplification, we show how a quadratic speedup can be obtained over the classical algorithm, in principle. Utilization of quantum computation also allows the algorithm to match─at little additional computational cost─full density matrices at fragment boundaries, instead of being limited to 1-RDMs. Current quantum computers are small, but quantum bootstrap embedding provides a potentially generalizable strategy for harnessing such small machines through quantum fragment matching.

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