ABSTRACT
The morphology of virgin reactor powder (RP) of high-density polyethylene (HDPE) with MW = 160,000 g/mol was investigated using DSC, SEM, SAXS, and WAXS methods. The morphological SEM analysis showed that the main morphological units of RP are macro- and micro-shish-kebab structures with significantly different geometric dimensions, as well as individual lamellae of folded chain crystals. A quantitative analysis of an asymmetric SAXS reflection made it possible to reveal the presence of several periodic morphoses in the RP with long periods ranging from 20 nm to 60 nm, and to correlate them with the observed powder morphology. According to the DSC crystallinity data, the thickness of the lamellae in each long period was estimated. Their surface energy was calculated in the framework of the Gibbs-Thompson theory. The presence of regular and irregular folds on the surface of different shish-kebab lamellae was discussed. The percentage of identified morphoses in the RP was calculated. It has been suggested that the specific structure of HDPE RP is due to the peculiarity of polymer crystallization during suspension synthesis in a quasi-stationary regime, in which local overheating and inhomogeneous distribution of shear stresses in a chemical reactor are possible.
ABSTRACT
A novel approach for performing in situ and real-time beam monitoring, based on dielectric meta-hologram, is proposed and demonstrated. The ultrathin dielectric meta-hologram projects a portion of the beam power onto a screen to provide a visual indicator of the spatial intensity distribution of a Gaussian laser beam, as well as its waist position along the optical axis. Specifically, we demonstrate simple monitoring of the spot size, astigmatism, lateral position, and position along the optical axis of the beam. Good agreement is found with both theory and conventional knife-edge beam profiler measurements. This in situ beam monitoring approach could provide a highly useful tool for numerous optical applications.
ABSTRACT
We present and study theoretically a new design approach for obtaining wide angle, highly efficient, all-dielectric metasurfaces. As a concrete example we focus on optimizing flat beam deflector for both the infra-red and visible spectral regions. Transmission efficiencies of up to 87.2% are obtained theoretically for deflection angle of 65° in visible (580nm) spectrum and up to 82% for deflection angle of 30.5° at telecom wavelength (1550nm). The enhanced efficiencies at wide deflection angles are obtained by genetic optimization of the nano-structures comprising the metasurface. Compared to previously employed design approaches, our approach enhances the transmission efficiency substantially without sacrificing rectangular grid arrangement and facilitates the realization of wide angle flat deflectors and holograms/lenses.
ABSTRACT
The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify (137)Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured (137)Cs levels were found to be very low (usually < 1 Bq kg(-1) wet wt) (137)Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.
