ABSTRACT
Alkali activated fly ash (AAFA) based geopolymer concrete structure is getting attention due to its eco-friendly construction characteristics and improved engineering properties. However, comprehensive studies on the structural performance of hardened properties of AAFA geopolymer concrete is not well addressed, especially on non-linear fracture behavior. This paper aims to present the reinforcement ratio effect on the flexural performance and non-linear fracture characteristics of alkali activated fly ash based geopolymer concrete beams. Sixteen finite element (FE) and four experimental models were used to study the effect of reinforcement ratio on the flexural performance and non-linear fracture characteristics. Four groups of concrete specimens with an average compressive strength of 19.30 MPa, 32.60 MPa, 38.2,0 MPa, and 41.70 MPa were utilized under this study. To investigate the effect of reinforcement ratio on flexural performance of the beams, reinforcement ratios of 0.03, 0.042, 0.045, and 0.063 were used for each compressive strength class. The result showed that the ultimate load carrying capacity of the beam showed significant improvement by about 36.38% by increasing of reinforcement ratio from 0.03 to 0.063 by keeping the compressive strength of concrete constant. However, it was observed that the effect of compressive strength was not such substantial as reinforcement ratio in enhancing the ultimate load bearing capacity. The experimental result showed that the increase in ultimate load by keeping the reinforcement ratio constant is about 12.20% for different compressive strength. Furthermore, the crack formation in the concrete was highly associated with the tensile reinforcement ratio, i.e., smaller reinforcement ratio led to higher strain growth in the concrete. Moreover, the validation study between the numerical simulation and test results showed a good agreement.
ABSTRACT
The study of geopolymers has become an interesting concern for many scientists, especially in the infrastructure sector, due to having inherently environmentally friendly properties and fewer energy requirements in production processes. Geopolymer attracts many scientists to develop practical synthesis methods, useful in industrial-scale applications as supplementary material for concrete. This study investigates the geopolymerization of fly ash and geothermal silica-based dry activator. The dry activator was synthesized between NaOH and silica geothermal sludge through the calcination process. Then, the geopolymer mortar was produced by mixing the fly ash and dry activator with a 4:1 (wt./wt.) ratio. After mixing homogeneously and forming a paste, the casted paste moved on to the drying process, with temperature variations of 30, 60, and 90 °C and curing times of 1, 3, 5, 7, 14, 21, 28 days. The compressive strength test was carried out at each curing time to determine the geopolymer's strength evolution and simulate the reaction's kinetics. In addition, ATR-FTIR spectroscopy was also used to observe aluminosilicate bonds' formation. The higher the temperature, the higher the compressive strength value, reaching 22.7 MPa at 90 °C. A Third-order model was found to have the highest R2 value of 0.92, with the collision frequency and activation energy values of 1.1171 day-1 and 3.8336 kJ/mol, respectively. The utilization of coal fly ash and silica geothermal sludge as a dry activator is, indeed, an approach to realize the circular economy in electrical power generations.
