Urea-rich sodium alginate-based hydrogel fertilizer as a water reservoir and slow-release N carrier for tomato cultivation under different water-deficit levels.

In this study, a new eco-friendly urea-rich sodium alginate-based hydrogel with a slow-release nitrogen property was prepared, and its effectiveness was evaluated in the cultivation of tomato plants under different water stress levels. The structure and performance of the hydrogel were investigated by FTIR, XRD, TGA, DTG, and SEM. The swelling and release experiments showed that prepared urea-rich hydrogel exhibited a high-water holding capacity (412 ± 4 g/g) and showed a sustained and slow nitrogen release property. A greenhouse pot experiment was conducted using two hydrogel levels (0.1 and 0.5 wt%) under two water deficit levels (30 and 70 % based on required water irrigation). Germination tests indicated that the developed hydrogel fertilizer has no phytotoxicity and has a positive impact on the germination rate even under water deficit conditions. The application of hydrogel fertilizer at 0.5 wt% significantly (p > 0.05) enhanced plant growth parameters such as leaf number, chlorophyll content, stem diameter, and plant length compared to the control treatment. The magnitude of the responses to the hydrogel fertilizer application depended on the concentration of applied hydrogel fertilizer and stress severity with the most positive effects on the growth and yield of tomato observed at a level of 0.5 %. Tomato yield was significantly enhanced by 19.58 %-12.81 %, 18.58 %-22.02 %, and 39.38 %-43.18 % for the plant amended with hydrogel at 0.1-0.5 wt% and grown under water deficit levels of 0, 30, and 70 %, respectively, compared to the control treatment.

Correction: Recent advances in nano-fertilizers: synthesis, crop yield impact, and economic analysis.

Correction for 'Recent advances in nano-fertilizers: synthesis, crop yield impact, and economic analysis' by Badr-Eddine Channab et al., Nanoscale, 2024, https://doi.org/10.1039/d3nr05012b.

Recent advances in nano-fertilizers: synthesis, crop yield impact, and economic analysis.

The escalating global demand for food production has predominantly relied on the extensive application of conventional fertilizers (CFs). However, the increased use of CFs has raised concerns regarding environmental risks, including soil and water contamination, especially within cereal-based cropping systems. In response, the agricultural sector has witnessed the emergence of healthier alternatives by utilizing nanotechnology and nano-fertilizers (NFs). These innovative NFs harness the remarkable properties of nanoparticles, ranging in size from 1 to 100 nm, such as nanoclays and zeolites, to enhance nutrient utilization efficiency. Unlike their conventional counterparts, NFs offer many advantages, including variable solubility, consistent and effective performance, controlled release mechanisms, enhanced targeted activity, reduced eco-toxicity, and straightforward and safe delivery and disposal methods. By facilitating rapid and complete plant absorption, NFs effectively conserve nutrients that would otherwise go to waste, mitigating potential environmental harm. Moreover, their superior formulations enable more efficient promotion of sustainable crop growth and production than conventional fertilizers. This review comprehensively examines the global utilization of NFs, emphasizing their immense potential in maintaining environmentally friendly crop output while ensuring agricultural sustainability.

Nanocellulose: Structure, modification, biodegradation and applications in agriculture as slow/controlled release fertilizer, superabsorbent, and crop protection: A review.

This review investigates the potential of nanocellulose in agriculture, encompassing its structure, synthesis, modification, and applications. Our investigation of the characteristics of nanocellulose includes a comprehensive classification of its structure. Various mechanical, chemical and enzymatic synthesis techniques are evaluated, each offering distinct possibilities. The central role of surface functionalization is thoroughly examined. In particular, we are evaluating the conventional production of nanocellulose, thus contributing to the novelty. This review is a pioneering effort to comprehensively explore the use of nanocellulose in slow and controlled release fertilizers, revolutionizing nutrient management and improving crop productivity with reduced environmental impact. Additionally, our work uniquely integrates diverse applications of nanocellulose in agriculture, ranging from slow-release fertilizers, superabsorbent cellulose hydrogels for drought stress mitigation, and long-lasting crop protection via nanocellulose-based seed coatings. The study ends by identifying challenges and unexplored opportunities in the use of nanocellulose in agriculture. This review makes an innovative contribution by being the first comprehensive study to examine the multiple applications of nanocellulose in agriculture, including slow-release and controlled-release fertilizers.

Superabsorbent hydrogels based on natural polysaccharides: Classification, synthesis, physicochemical properties, and agronomic efficacy under abiotic stress conditions: A review.

Superabsorbent polymers (SAPs) are a class of polymers that have attracted tremendous interest due to their multifunctional properties and wide range of applications. The importance of this class of polymers is highlighted by the large number of publications, including articles and patents, dealing with the use of SAPs for various applications. Within this framework, this review provides an overview of SAPs and highlights various key aspects, such as their history, classification, and preparation methods, including those related to chemically or physically cross-linked networks, as well as key factors affecting their performance in terms of water absorption and storage. This review also examines the potential use of polysaccharides-based SAPs in agriculture as soil conditioners or slow-release fertilizers. The basic aspects of SAPs, and methods of chemical modification of polysaccharides are presented and guidelines for the preparation of hydrogels are given. The water retention and swelling mechanisms are discussed in light of some mathematical empirical models. The nutrient slow-release kinetics of nutrient-rich SAPs are also examined on the basic of commonly used mathematical models. Some examples illustrating the advantages of using SAPs in agriculture as soil conditioners and agrochemical carriers to improve crop growth and productivity are presented and discussed. This review also attempts to provide an overview of the role of SAPs in mitigating the adverse effects of various abiotic stresses, such as heavy metals, salinity, and drought, and outlines future trends and prospects.

Effect of sodium alginate-based superabsorbent hydrogel on tomato growth under different water deficit conditions.

The main challenge facing agriculture today is water scarcity. At present, agriculture consumes around 70 % of the planet's freshwater, much of which is lost through evaporation, leaching and runoff. This wastage, combined with the increased frequency and severity of droughts linked to climate change, is having a considerable negative impact on crops. As a result, the food security of people living in regions with limited water resources is threatened. In this regard, efficient water management using water-saving materials and soil additives such as superabsorbent polymers (SAPs) are recognized as an effective strategy to boost water use efficiency by plants and improve agricultural productivity. The present study fits with this strategy and aims to investigate the effect of new sodium alginate-based hydrogel-treated sandy loam soil on seed emergence and growth of tomatoes as a crop model under different water-deficit stress levels. A set of pot experiments was conducted in a greenhouse chamber using sandy loam soil amended with two levels of hydrogel (0.1 % and 0.5 % by weight) along with untreated control, all under water-deficit stress at three levels: 30 % of the daily amount of required irrigation water (DARW) for different growing cycles (severe stress), 70 % DARW (mild stress), and 100 % DARW (normal irrigation conditions). The germination test showed the absence of phytotoxicity of the developed hydrogel and confirmed its suitability in protecting seedlings from drought stress. Greenhouse experiment results demonstrated that water stress and levels of applied hydrogel significantly (P < 0.05) affected plant growth parameters such as plant height, stem diameter, number of leaves, chlorophyll content, fresh weight, and dry weight compared with the treatments without SAPs. The developed sodium alginate-based SAPs showed relevant agronomical benefits under drought stress by retaining more water and nutrients, thus it had the potential to be used in agriculture for better water management along with significant environmental benefits.

A comprehensive review on starch: Structure, modification, and applications in slow/controlled-release fertilizers in agriculture.

This comprehensive review thoroughly examines starch's structure, modifications, and applications in slow/controlled-release fertilizers (SRFs) for agricultural purposes. The review begins by exploring starch's unique structure and properties, providing insights into its molecular arrangement and physicochemical characteristics. Various methods of modifying starch, including physical, chemical, and enzymatic techniques, are discussed, highlighting their ability to impart desirable properties such as controlled release and improved stability. The review then focuses on the applications of starch in the development of SRFs. It emphasizes the role of starch-based hydrogels as effective nutrient carriers, enabling their sustained release to plants over extended periods. Additionally, incorporating starch-based hydrogel nano-composites are explored, highlighting their potential in optimizing nutrient release profiles and promoting plant growth. Furthermore, the review highlights the benefits of starch-based fertilizers in enhancing plant growth and crop yield while minimizing nutrient losses. It presents case studies and field trials demonstrating starch-based formulations' efficacy in promoting sustainable agricultural practices. Overall, this review consolidates current knowledge on starch, its modifications, and its applications in SRFs, providing valuable insights into the potential of starch-based formulations to improve nutrient management, boost crop productivity, and support sustainable agriculture.

Alginate@ZnCO2O4 for efficient peroxymonosulfate activation towards effective rhodamine B degradation: optimization using response surface methodology.

A facile chemical procedure was utilized to produce an effective peroxy-monosulfate (PMS) activator, namely ZnCo2O4/alginate. To enhance the degradation efficiency of Rhodamine B (RhB), a novel response surface methodology (RSM) based on the Box-Behnken Design (BBD) method was employed. Physical and chemical properties of each catalyst (ZnCo2O4 and ZnCo2O4/alginate) were characterized using several techniques, such as FTIR, TGA, XRD, SEM, and TEM. By employing BBD-RSM with a quadratic statistical model and ANOVA analysis, the optimal conditions for RhB decomposition were mathematically determined, based on four parameters including catalyst dose, PMS dose, RhB concentration, and reaction time. The optimal conditions were achieved at a PMS dose of 1 g l-1, a catalyst dose of 1 g l-1, a dye concentration of 25 mg l-1, and a time of 40 min, with a RhB decomposition efficacy of 98%. The ZnCo2O4/alginate catalyst displayed remarkable stability and reusability, as demonstrated by recycling tests. Additionally, quenching tests confirmed that SO4˙-/OH˙ radicals played a crucial role in the RhB decomposition process.

Comparison of moroccan argain nut shell and olive cake combustion to determine the best combustible for CHP system and for the thermodynamic cycle.

The current research aims to valorize Moroccan agricultural waste by using it as a combustible fuel. The physicochemical properties of argan cake were determined and the results were compared with other studies of argain nut shell and olive cake. A comparison of argain nuts shell, argain cake, and olive cake was carried out in order to determine the best combustible in terms of energy, emissions and thermal efficiency cycle. The CFD modeling of their combustion was presented using Ansys fluent software, The Reynolds averaged Navier-Stokes (RANS) method is the foundation of the numerical approach, which models the turbulent flow using realizable. k-ε, A non-premixed combustion model is used for the gas phase, and a Lagrangian approach is chosen for the discrete second phase, there was a good agreement between the numerical and experimental data, as well as Wolfram Mathematica 13.1 is used to predict the mechanical work generated by the Stirling engine, and the result encourages the use of studied biomasses as combustible in order to generate heat and power.

Starch-based controlled release fertilizers: A review.

Starch, as a widely available renewable resource, has the potential to be used in the production of controlled-release fertilizers (CRFs) that support sustainable agriculture. These CRFs can be formed by incorporating nutrients through coating or absorption, or by chemically modifying the starch to enhance its ability to carry and interact with nutrients. This review examines the various methods of creating starch-based CRFs, including coating, chemical modification, and grafting with other polymers. In addition, the mechanisms of controlled release in starch-based CRFs are discussed. Overall, the potential benefits of using starch-based CRFs in terms of resource efficiency and environmental protection are highlighted.