Influence of denture brushing on the surface properties and color stability of CAD-CAM, thermoformed, and conventionally fabricated denture base resins.

PURPOSE: To assess the influence of denture brushing on the surface roughness, hardness, and color stability of conventional, thermoformed, and CAD-CAM denture base materials. MATERIALS AND METHODS: Seven different denture base materials were included in this study; conventional heat-polymerized acrylic resin (PMMA) served as control, polyamide, acetal, two categories of milled acrylic discs (AvaDent and IvoCad), and two categories of 3D-printed resins (NextDent and FormLabs). The specimens were constructed according to manufacturers' instructions and then subjected to simulated brushing (20,000 cycles). According to the brushing method, the specimens were split into three groups, no brushing, brushing with water, and brushing with toothpaste. Surface roughness, hardness, and color change were evaluated before and after brushing. Collected data were analyzed using ANOVA, and post-hoc Tukey's tests (α = 0.05). RESULTS: A significant difference was noted between the surface roughness of the tested materials before and after denture brushing (p < 0.05), and milled resin showed the least Ra values. Denture brushing with water significantly increased the Ra of PMMA (p = 0.004) and IvoCad (p = 0.032), while brushing using toothpaste did not show a significant increase. The brushing protocols did not alter the hardness of tested materials except that of PMMA (p = 0.001). The color stability of the tested materials showed comparable results with both brushing protocols. CONCLUSION: The tested properties showed variations between the types of denture base resins. Hardness and color stability of CAD-CAM and thermoformed denture base resins were not altered by denture brushing and showed comparable results with both brushing methods. Surface roughness was the only property that showed alteration after denture brushing.

Repair Bond Strength of Conventionally and Digitally Fabricated Denture Base Resins to Auto-Polymerized Acrylic Resin: Surface Treatment Effects In Vitro.

Denture base fracture is one of the most annoying problems for both prosthodontists and patients. Denture repair is considered to be an appropriate solution rather than fabricating a new denture. Digital denture fabrication is widely spreading nowadays. However, the repair strength of CAD-CAM milled and 3D-printed resins is lacking. This study aimed to evaluate the effect of surface treatment on the shear bond strength (SBS) of conventionally and digitally fabricated denture base resins. One l heat-polymerized (Major base20), two milled (IvoCad, AvaDent), and three 3D-printed (ASIGA, NextDent, FormLabs) denture base resins were used to fabricate 10 × 10 × 3.3 acrylic specimens (N = 180, 30/resin, n = 10). Specimens were divided into three groups according to surface treatment; no treatment (control), monomer application (MMA), or sandblasting (SB) surface treatments were performed. Repair resin was bonded to the resin surface followed by thermocycling (5000 cycles). SBS was tested using a universal testing machine where a load was applied at the resin interface (0.5 mm/min). Data were collected and analyzed using ANOVA and a post hoc Tukey test (α = 0.05). SEM was used for failure type and topography of fractured surfaces analysis. The heat-polymerized and CAD-CAM milled groups showed close SBS values without significance (p > 0.05), while the 3D-printed resin groups showed a significant decrease in SBS (p < 0.0001). SBS increased significantly with monomer application (p < 0.0001) except for the ASIGA and NextDent groups, which showed no significant difference compared to the control groups (p > 0.05). All materials with SB surface treatment showed a significant increase in SBS when compared with the controls and MMA application (p < 0.0001). Adhesive failure type was observed in the control groups, which dramatically changed to cohesive or mixed in groups with surface treatment. The SBS of 3D-printed resin was decreased when compared with the conventional and CAD-CAM milled resin. Regardless of the material type, SB and MMA applications increased the SBS of the repaired resin and SB showed high performance.

Assessment of polyethylene/Zn-ionic as a diesel fuel sulfur adsorbent: gamma radiation effect and response surface methodology.

Irradiated waste high-density polyethylene@Zn/ionic liquid novel composite well-fabricated via coacervation method was irradiated by gamma-irradiation and studied the effect of that radiation on the desulfurization process. The prepared composites were characterized by various analytical techniques as follows: X-ray diffraction (XRD), Fourier-Transform infrared (FT-IR), X-ray photoelectron spectrometer (XPS), scanning electron microscope (SEM), High Resolution Transmission Electron Microscopy (HRTEM), N2-adsorption-desorption isotherm, and thermal gravimetric analysis (TG/DTA). The adsorptive desulfurization process of benzothiophene (BT) and dibenzothiophene (DBT) which are harmful compounds in diesel model fuel was investigating using the irradiated and unirradiated composite. The results illustrated that the unirradiated and irradiated composites exhibit an adequate adsorption capacity reached (50-75 mg S/g) and (60-85 mg S/g) for BT and DBT, respectively. The adsorption process over the prepared adsorbents follows the pseudo-second-order kinetic models. The irradiated composite exhibited more adsorption capacity than the unirradiated one due to the radiation generated more surface area and created proton-bond donor sites in the composite surface, which increases the interaction between the surface and sulfur species. The adsorption capacity and adsorption percentage for irradiated and unirradiated composites towards (SCCs) were studied using response surface methodology based on the central composite design (CCD). The thermodynamic factors (∆H°, ∆G°, and ∆S°) reveal that these processes are endothermic adsorption processes. The irradiated PEt @Zn/IL was re-used without significant loss of adsorption activity. This novel irradiated PEt @Zn/IL is the first time used as an adsorbent with an advantage that includes its excellent adsorption capacity, which ensures the product will be efficient in a real process such as the petrochemical industry.

Prevalence of partial edentulism and RPD design in patients treated at College of Dentistry, Imam Abdulrahman Bin Faisal University, Saudi Arabia.

This study aimed to investigate the prevalence of partial edentulism, RPD type, design, and components and their frequency of use by patients at the prosthodontic clinics of the College of Dentistry, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia. The prepared surveys, laboratory authorization forms, and images of the RPD metal frameworks on casts were used for data collection. Two calibrated investigators studied the digital photographs to identify the Kennedy classification, type of RPD, major connector, clasp assembly, and other details. Data was collected and analyzed statistically. The results showed that the most common class of partial edentulism was Kennedy class I, whereas class IV was the least (p < 0.001). Sixty two percent of fabricated RPDs had metal frameworks, whereas 37.2% were frameless. RPI was the most frequently used clasp assembly (38.9%), a significant finding in Kennedy class I(p < 0.01). The maxillary anteroposterior palatal strap and mandibular lingual plate were the most commonly used major connectors, at 41.2% and 60.8%, respectively. Conclusions: Simple RPD design that accomplishes the treatment objectives as well as proper communication with a well-trained dental technician would promote the success of RPDs.

Effect of Henna Addition on the Surface Roughness and Hardness of Polymethylmethacrylate Denture Base Material: An in vitro Study.

AIM: This study aimed to evaluate the effect of the addition of various henna-which can have antifungal properties-on the surface roughness and hardness of polymethylmethacrylate (PMMA) denture base material. MATERIALS AND METHODS: A total of 99 rectangular-shaped (10 × 20 × 3 mm3) specimens were prepared from heat-cured acrylic resin and divided into one control group without the addition of henna and five test groups, which were prepared by adding Yamanihenna powder to polymer at concentrations of 1, 2.5, 5, 7.5, and 10 wt%. The polymer was added to the monomer, mixed, packed, and processed using the conventional water bath method. After processing, specimens were finished and polished, then kept in distilled water for 48 ± 2 hours. A profilom-eter and Vickers hardness tester were used to measure surface roughness and hardness respectively. Statistical data analysis was conducted via Statistical Package for the Social Sciences (SPSS) version 20.0 (IBM, USA). The independent sample t-test was used and p ≤ 0.05 was considered statistically significant. RESULTS: The addition of henna at varying concentrations significantly increased the surface roughness values (p ≤ 0.01) while decreasing hardness (p ≤ 0.0001). The most favorable addition value was 1% henna between all henna groups. CONCLUSION: The addition of henna to the acrylic resin may negatively affect the surface properties of PMMA acrylic denture base. CLINICAL SIGNIFICANCE: Antimicrobial denture with minimum deterioration effects on its physical properties could be achieved with henna addition to denture base material in low concentration. However, 1% henna showed the best results between the henna groups as regards roughness and hardness values.