Perovskite interface defect passivation with poly(ethylene oxide) for improving power conversion efficiency of the inverted solar cells.

Inverted perovskite solar cells (PSCs) attract researchers' attention for their potential application due to the low-temperature fabrication, negligible hysteresis and compatibility with multi-junction cells. However, the low-temperature fabricated perovskite films containing excessive undesired defects are not benefit for improving the performance of the inverted PSCs. In this work, we used a simple and effective passivation strategy that Poly(ethylene oxide) (PEO) polymer as an antisolvent additive to modify the perovskite films. The experiments and simulations have shown that the PEO polymer can effectively passivate the interface defects of the perovskite films. The defect passivation by PEO polymers suppressed non-radiative recombination, resulting in an increase in power conversion efficiency (PCE) of the inverted devices from 16.07% to 19.35%. In addition, the PCE of unencapsulated PSCs after PEO treatment maintains 97% of its original stored in a nitrogen atmosphere for 1000 h.

Electrical performance of efficient quad-crescent-shaped Si nanowire solar cell.

The electrical characteristics of quad-crescent-shaped silicon nanowire (NW) solar cells (SCs) are numerically analyzed and as a result their performance optimized. The structure discussed consists of four crescents, forming a cavity that permits multiple light scattering with high trapping between the NWs. Additionally, new modes strongly coupled to the incident light are generated along the NWs. As a result, the optical absorption has been increased over a large portion of light wavelengths and hence the power conversion efficiency (PCE) has been improved. The electron-hole (e-h) generation rate in the design reported has been calculated using the 3D finite difference time domain method. Further, the electrical performance of the SC reported has been investigated through the finite element method, using the Lumerical charge software package. In this investigation, the axial and core-shell junctions were analyzed looking at the reported crescent and, as well, conventional NW designs. Additionally, the doping concentration and NW-junction position were studied in this design proposed, as well as the carrier-recombination-and-lifetime effects. This study has revealed that the high back surface field layer used improves the conversion efficiency by [Formula: see text] 80%. Moreover, conserving the NW radial shell as a low thickness layer can efficiently reduce the NW sidewall recombination effect. The PCE and short circuit current were determined to be equal to 18.5% and 33.8 mA[Formula: see text] for the axial junction proposed. However, the core-shell junction shows figures of 19% and 34.9 mA[Formula: see text]. The suggested crescent design offers an enhancement of 23% compared to the conventional NW, for both junctions. For a practical surface recombination velocity of [Formula: see text] cm/s, the PCE of the proposed design, in the axial junction, has been reduced to 16.6%, with a reduction of 11%. However, the core-shell junction achieves PCE of 18.7%, with a slight reduction of 1.6%. Therefore, the optoelectronic performance of the core-shell junction was marginally affected by the NW surface recombination, compared to the axial junction.