ABSTRACT
In recent years, solar seawater desalination has been considered to be a promising and cost-effective technique to produce clean sources for water treatment and water deficiency. In addition, this technique shows high photothermal conversion efficiency by solar collectors to transfer solar energy into heat and the transformation of molecules in the capillaries of solar evaporators. In this study, we report the preparation of graphene-supported MIL-125 with polyurethane foam (MGPU) for solar steam generation. We modified MGPU by using the plasmonic nanoparticles of Ag and a polymer of polyaniline to increase the evaporation rate. Polyurethane foam can float on the surface of water and self-pump water by its hydrophilic porous structure, superior thermal insulation capabilities, and easy fabrication. MIL-125 has a high salt rejection and higher water permeability. It can reduce the affinity between water molecules and the pore surface of membrane, making it simple for water molecules to move through the pores. GO is a great alternative for steam generation applications since it exhibits broad-band light. The strong solar absorption, photothermal conversion efficiency, and photoreaction efficiency are enhanced by the use of silver nanoparticles in the photoreaction. The salt resistance capability is enhanced in saline water in the presence of polyaniline in a composite. Under one solar irradiation, the Ag/PANI/GO@MIL-125 (Ag-PMG) nanocomposite demonstrates an average 1.26 kg m2 h-1 rate of evaporation and an efficiency as high as 90%. The composite exhibits remarkable stability and durability after more than 10 cycles of use without a noticeable decrease in activity. In addition, the composite exhibits excellent organic dye removal from contaminated water and generates pure condensed freshwater. The antibacterial photoactivity of the photocatalysts was examined against B. subtilis and E. coli. The results demonstrate that Ag-PMG shows higher antibacterial activity than MIL-125 and PMG. It was shown that the presence of rGO, PANI, and Ag in the sample enhances the antimicrobial activity.
ABSTRACT
The removal of harmful organic dyes from aqueous solutions has drawn the attention of scientists because of the substantial threat they pose to society's worldwide health. Hence, it is crucial to design an adsorbent that is both very effective in removing dyes and has the benefit of being inexpensive. In the present work, Cs salts of tungstophosphoric acid (CPW) supported mesoporous Zr-mSiO2 (mZS) with varying extents of Cs ions have been prepared by a two-step impregnation technique. Accordingly, a lowering in the surface acidity modes was observed after Cs exchanged protons of H3W12O40 and formed salts immobilized on the mZS support. After exchanging the protons with Cs ions, the characterization results revealed that the primary Keggin structure was unaltered. Moreover, the Cs exchanged catalysts had higher surface area than the parent H3W12O40/mZS, suggesting that Cs reacts with H3W12O40 molecules to create new primary particles with smaller sizes possessing inter-crystallite centers with a higher dispersion degree. With an increase in Cs content and thus a decrease in the acid strength and surface acid density, the methylene blue (MB) monolayer adsorption capacities on CPW/mZS catalysts were increased and reached an uptake capacity of 359.9 mg g-1 for Cs3PW12O40/mZS (3.0CPW/mZS). The catalytic formation of 7-hydroxy-4-methyl coumarin was also studied at optimum conditions and it is found that the catalytic activity is influenced by the amount of exchangeable Cs with PW on the mZrS support, which is in turn influenced by the catalyst acidity. The catalyst kept approximately the initial catalytic activity even after the fifth cycle.
ABSTRACT
There is an urgent need to improve engineering and synthetic chemistry, either through the use of eco-friendly starting materials or the proper design of novel synthesis routes. This reduces the contamination of toxic chemicals and helps the disposal of organic dyes. In the current work, a metal-organic framework-based Sr(ii) was fabricated to achieve the desired goal for dye removal and catalysis. Sr-MOF-based phosphotungstic acid (PWA/Sr-MOF) was hydrothermally synthesized to study its adsorption and catalytic activities. Remarkably, about 99.9% of crystal violet (CV) dye was removed using PWA/Sr-MOF within 90 min at room temperature. Various factors have been studied to investigate the optimum conditions such as pH of solution, initial dye concentration, contact time, and temperature. The maximum adsorption capacity of CV dye was reached after 90 min and well fitted the pseudo-second kinetic order and Langmuir adsorption isotherm. Coumarin and xanthene reactions were chosen to test the catalytic activity of the prepared PWA/Sr-MOF at 373 K. Furthermore, structural and chemical characterization of the fabricated samples was obtained using FT-IR, XRD, TGA, DTA, TEM, EDX, and XPS. PWA/Sr-MOF can be considered as a promising and green framework in the material design used to study catalytic and adsorption performances.
ABSTRACT
A highly porous adsorbent based on a metal-organic framework was successfully designed and applied as an innovative adsorbent in the solid phase for the heavy metal removal. MIL-125 was densely decorated by 2-imino-4-thiobiuret functional groups, which generated a green, rapid, and efficacious adsorbent for the uptake of Hg(ii) and Pb(ii) from aqueous solutions. ITB-MIL-125 showed a high adsorption affinity toward mercury(ii) ions of 946.0 mg g-1 due to covalent bond formation with accessible sulfur-based functionality. Different factors were studied, such as the initial concentration, pH, contact time, and competitive ions, under same circumstances at the room temperature. Moreover, the experimental adsorption data were in excellent agreement with the Langmuir adsorption isotherm and pseudo-second order kinetics. At a high concentration of 100 ppm mixture of six metals, ITB-MIL-125 exhibited a high adsorption capacity, reaching more than 82% of Hg(ii) compared to 62%, 30%, 2%, 1.9%, and 1.6% for Pb(ii), Cu(ii), Cd(ii), Ni(ii), and Zn(ii), respectively.
