Spatial analysis of leachate penetration at Lemna dumpsite, Calabar: Implications for sustainable waste management in Cross River State.

This study rigorously investigated the spatial analysis of leachate penetration at Lemna dumpsite, located in Calabar, Cross River State, Nigeria. Purposeful soil sampling, performed at specific intervals (5 m, 25 m, and 50 m) along the Electrical Resistivity profile line within the dumpsite, was augmented by water sample collection from five boreholes near Lemna dumpsite. Utilizing Electrical Resistivity Tomography (ERT) and Vertical Electric Sounding (VES) survey techniques, resistivity data were systematically gathered to comprehensively analyze the Leachate Penetration in the Lemna dumpsite. Laboratory analysis of soil and borehole water quality focused on Benzene, Toluene, Ethylbenzene, and Xylene (BTEX), with paired sample t-tests applied for statistical scrutiny. Analyzing the ERT and VES data employed sophisticated techniques embedded in Resistivity Two Dimension Invasion software and Advanced Geosciences Incorporation Earth Imager software. Substantial disparities (p < 0.05) emerged in the paired sample t-tests for BTEX in soil compared to National Environmental Standard Regulation and Enforcement Agency (NESREA) limits. Similarly, BTEX in borehole water displayed significant differences (p < 0.05) when compared to World Health Organization (WHO) standards, raising alarming concerns about the safety and portability of groundwater in the area. The examination of dumpsite leachate penetration revealed a resistivity anomaly of 8.01 Ωm and an inverse depth of 12.4 m, underscoring profound environmental implications and necessitating immediate remediation efforts. Additionally, Vulnerability and Aquifer Protective Capacity Index (VES) results, with a rating of <0.1, indicated severely compromised aquifer protective capacity, emphasizing the vulnerability of groundwater resources to further contamination. Our study advocates for strategic management, remediation, and monitoring measures to prevent contamination and safeguard water quality in the region.

Reliable Tilt-depth estimates based on the stable computation of the tilt angle using robust vertical derivatives.

The Tilt-depth is a popular approach for determining depths of magnetic sources. As this method is based on the distance between contour levels of the tilt angle, it can lead to inaccurate depth estimates when the contour lines are distorted by the presence of noise. In this paper, we stabilize the Tilt-depth method based on the computation of stable vertical derivative obtained by the ß-VDR method. The presented method is demonstrated on synthetic magnetic anomalies and real magnetic data from the Arabian Shield. The results obtained from the synthetic examples coincide well with the actual depths. These results proved the utility of the presented method in cases where the field is corrupted by noise. The real example shows that the presented method can provide valuable information on subsurface structures of the area where the Tilt-depth estimates are consistent with the result of the horizontal tilt angle. The findings show that the presented method is less sensitive to noise and can provide source edges and depths more clearly and with higher accuracy.

Predicting sediment yield on different landuse surfaces in Calabar River Catchment, Nigeria.

This study predicts sediment yield on various landuse surfaces within the Calabar River Catchment, Nigeria. Five experimental plots of 31 by 23 cm (representing urban, farm, grass, bare, and forest surfaces) were established on a convex slope series with a 20% gradient, oriented along the slope strike. Rainfall, morphological, and hydraulic stations were derived for each plot. Multiple regressions and Factor analysis were employed to analyse the collected data. The research identifies critical factors influencing sediment yield, such as rainfall amount, rainfall intensity, slope gradient, slope length, sand, silt, clay, vegetation cover, and infiltration capacity. The results (p < 0.05) indicate that slope length, sand, silt, clay, infiltration capacity, and vegetation cover significantly influence sediment yield for urban, farmland, grassland, and bare surfaces, respectively. Factor analysis revealed strong correlations between sediment yield, silt, rainfall amount, rainfall intensity, and slope gradient. Case-wise diagnostics predictions indicate sediment yields for urban, bare, farm, grass, and vegetation-covered surfaces as 14.95 kg, 33.91 kg, 28.78 kg, 33.50 kg, and 5.66 kg, respectively. The regression model, with case-wise diagnostic residual statistics and standard prediction coefficients, provides valuable insights. For example, the forest surface exhibited a minimum sediment yield of -1.413 kg/m2 with each unit decrease in forest area, emphasising the significance of vegetation cover in sediment retention. Conversely, bare surfaces showed a maximum sediment yield of 0.843 kg/m2 with each unit increase in bare surface area, highlighting their heightened vulnerability to sediment erosion. Considering the implications of these findings, the development of urban master plans that incorporate well-designed landscaping and drainage systems is crucial, particularly in high rainfall catchments like the study area. Such measures can effectively mitigate sediment yield and address the adverse effects of land use changes on different surfaces.

Lithospheric structural dynamics and geothermal modeling of the Western Arabian Shield.

Understanding the dynamics of suturing and cratonisation and their implications are vital in estimating the link between the lithospheric mantle architecture and geothermal resources. We propose new interpretations of the Western Arabian Shield's geodynamic styles and geothermal anomalies. In this work, features of the crust and mantle were interpreted from geophysical modeling to unravel the structural dynamics between the Arabian Shield and the Red Sea rift, as well as the influence of these mechanisms on the uplift of the Cenozoic basalts. Estimates of the lower crust thermal properties were also achieved. Spectral properties of the potential field were used to define the Curie isotherm, heat fluxes, geothermal gradients, radiogenic heat production, Moho configuration, and lithosphere-asthenosphere boundary. Results show new structural styles, micro-sutures, and significant thermal anomalies. The defined geothermal patterns were inferred to be due to localized initiation of tectonic and asthenospheric disequilibrium during the rifting episodes within the Red Sea. Also, magma mixing is initiated by the northward migration of magma from the Afar plume towards the Western Arabian Shield which drives local mantle melts beneath the western Arabia, thereby providing the pressure field required for magma ascent. The ascendant magma flow provides the heating source of geothermal reservoirs within the Western Arabian Shield. However, there are indications that during the episodes of rifting within the Red Sea and/or ancient Pan-African activities, the mixing process may have been altered resulting in crustal thinning and creating pathways of ascendant magma flow along the MMN volcanic line. Integrating geophysical and geothermal models indicated new zones of suturing and extensional tectonics between the amalgamated terranes. The geodynamic interpretation shows a new redistribution of terranes and continuous compressional and transtentional movements within the Arabian Shield.

Large-scale geological structures of the Egyptian Nubian Shield.

Integration of potential field- and structural data make it possible to trace surface and subsurface large-scale geological structures of the Egyptian Nubian Shield (ENS). Obtained results indicate that the Northern Eastern Desert (NED) of the ENS is dominated by relatively younger (c. 580 Ma) E-W and NE-SW trending extensional structures that were controlled by the evolution and retreat of the Cadomian Arc. Density of such extensional structures increases with depth as displayed by the potential data. The prevailing structural trends in the Central Eastern Desert (CED) are NW-SE and WNW-ESE. Both trends are highly prompted by the timing of deformation upon the Najd Fault System, and are themselves dissected by a relatively younger NE-SW shearing trend. Lineament density in the CED is subordinate for both subsurface and near surface structures. The South Eastern Desert exhibits compressional and extrusion-related structures of two main prominent trends; WNW-to-NW (to the western part) and the N-, NNE- to NE (to the eastern part). The previously mentioned Neoproterozoic trends are remarkably influenced by the Oligocene-Miocene Red Sea-Gulf of Suez rift related fractures in the vicinity of the rift shoulder. The remarkable change in trends and densities of structural trends, especially in the NED, is interpreted in terms of concealing of the older structures by the younger extensional structures which in turns reflect an N-ward progressive deformation in the entire ENS. Gravity data are more appropriate in delineating the structural trends compared to the magnetic data which are largely affected by lithological variations and/or alteration zones and magnetic mineralogy.

Integrating mineralogy, geochemistry and aeromagnetic data for detecting Fe-Ti ore deposits bearing layered mafic intrusion, Akab El-Negum, Eastern Desert, Egypt.

This study delineated the Fe-Ti oxide deposit concurrencies on the layered mafic intrusion in Gabal Akab El-Negum (GAN), South Eastern Desert, Egypt, using aeromagnetic mapping and chemical analysis of the hosted mafic rocks and mineralogical studies. Aeromagnetic data was improved using the enhanced horizontal gradient amplitudeto detect the primary structures (edges/contacts/faults) that control the distribution of Fe-Ti ore deposit. GAN layered gabbros are differentiated into troctolite, olivine-, pyroxene-, and hornblende-gabbros. These mafic rocks primarily comprise plagioclase, olivine, pyroxene, and hornblende with Fe-Ti ores (magnetite and ilmenite). The significant variation in Mg# of clinopyroxene between 0.70 and 0.82 indicates the importance of fractional crystallization in developing layered mafic intrusion. Clinopyroxene and plagioclase thermometry yielded low temperatures similar to the fractionated primary basaltic magma. The pairs of magnetite-ilmenite minerals in gabbros provide equilibrium temperatures of 539.44-815.56, and high fO2, reflecting various cooling and subsolidus reequilibration phases of minerals. The enrichment of GAN gabbros in light rare-earth elements relative to heavy rare-earth elements indicates the interaction between the Fe-Ti rich mantle and the fractionated tholeiitic magmas in the back-arc setting, generating Fe-Ti oxide ores.

Plume-MOR decoupling and the timing of India-Eurasia collision.

The debatable timing of India-Eurasia collision is based on geologic, stratigraphic, kinematic, and tectonic evidence. However, the collision event disturbed persistent processes, and the timing of disturbance in such processes could determine the onset of India-Eurasia collision precisely. We use the longevity of Southeast Indian Ridge (SEIR)-Kerguelen mantle plume (KMP) interaction cycles along the Ninetyeast ridge (NER) as a proxy to determine the commencement of India-Eurasia collision. The geochemical signature of the KMP tail along the NER is predominantly that of long-term coupling cycles, that was perturbed once by a short-term decoupling cycle. The long-term coupling cycles are mainly of enriched mid-ocean ridge basalts (E-MORBs). The short-term decoupling cycle is mostly derived from two distinct sources, MOR and plume separately, whereas the KMP is still being on-axis. The onset of India-Eurasia collision led to continental materials recycling into the mantle; hence the abrupt enrichment in incompatible elements at ca. 55 Ma, the MOR-plume on-axis decoupling, and the abrupt slowdown in the northward drift of the Indian plate was induced by the onset of India-Eurasia collision, thereafter MOR-plume recoupled.