ABSTRACT
It is known that glow discharges with a water anode inject and form solvated electrons at the plasma-liquid interface, driving a wide variety of reduction reactions. However, in systems with a water cathode, the production and role of solvated electrons are less clear. Here, we present evidence for the direct detection of solvated electrons produced at the interface of an argon plasma and a water cathode via absorption spectroscopy. We further quantify their yield using the dissociative electron attachment of chloroacetate, measuring a yield of 1.04 ± 0.59 electrons per incident ion, corresponding to approximately 100% faradaic efficiency. Additionally, we estimate a yield of 2.09 ± 0.93 hydroxyl radicals per incident ion. Comparison of this yield with other findings in the literature supports that these hydroxyl radicals are likely formed directly in the liquid phase rather than by diffusion from the vapor phase.
ABSTRACT
When a nonthermal plasma and a liquid form part of the same circuit, the liquid may function as a cathode, in which case electrons are emitted from the liquid into the gas to sustain the plasma. As opposed to solid electrodes, the mechanism of this emission has not been established for a liquid, even though various theories have attempted to explain it via chemical processes in the liquid phase. In this work, we tested the effects of the interfacial chemistry on electron emission from water, including the role of pH as well as the hydroxyl radical, the hydrogen atom, the solvated electron, and the presolvated electron; it was found that none of these species are critical to sustain the plasma. We propose an emission mechanism where electrons, generated from ionized water molecules in the uppermost monolayers of solution, are emitted into the plasma directly from the conduction band of the water.
