Enhanced photocatalytic performance of auto-combusted nanoparticles for photocatalytic degradation of azo dye under sunlight illumination and hydrogen fuel production.

In this study, an innovative nanomaterial was synthesized for hydrogen production from methanolysis on sodium borohydride (NaBH4) in order to be a solution for future energy problems. The nanocomposite containing FeCo, which does not contain noble metals, and whose support material is Polyvinylpyrrolidone (PVP), was synthesized by means of a thermal method. TEM, XRD and FTIR characterization methods were used for the analysis of the morphological and chemical structure of the nanocomposite. Nanocomposite particle size was found to be 2.59 nm according to XRD analysis, and 5.45 nm according to TEM analysis for scale of 50 nm. For catalytic properties of nanomaterial in the methanolysis reaction of NaBH4, temperature, catalyst, substrate, and reusability experiments were carried out and kinetic calculations were obtained. Among the activation parameters of FeCo@PVP nanoparticles, turnover frequency, enthalpy, entropy and activation energy were calculated as 3858.9 min-1, 29.39 kJ/mol, -139.7 J/mol.K, and 31.93 kJ/mol, respectively. As a result of the reusability test of the obtained FeCo@PVP nanoparticles catalysts, which was carried out for 4 cycles, the catalytic activity was 77%. Catalytic activity results are given in comparison with the literature. In addition, the photocatalytic activity of FeCo@PVP NPs was evaluated against MB azo dye under solar light irradiation for 75 min and was found to be as 94%.

Photocatalytic investigation of textile dyes and E. coli bacteria from wastewater using Fe3O4@MnO2 heterojunction and investigation for hydrogen generation on NaBH4 hydrolysis.

Various impurities found nowadays in water can be detrimental to human health. This work focused on utilizing Fe3O4@MnO2 nanocomposite for cleaning organic contaminants from water, including rhodamine B (RhB) and Escherichia coli (E. coli). Analysis methods such as XRD, UV-vis, TEM, and FTIR were used to describe the nanocomposite. The results showed that the developed nanocomposite has good photocatalytic activity against pollutants in wastewater. The E. coli was destroyed after 90 min, and the RhB photodegradation rate was 75%. Moreover, the Fe3O4@MnO2 efficiency as a catalyst for producing hydrogen as an alternative energy source was tested. According to the calculations, the nanomaterial's turnover frequency, activation energy, enthalpy, and entropy are 1061.3 h-1, 28.93 kJ/mol, 26.38 kJ/mol, and -128.41 J/mol.K, respectively. Four reusability tests were completed, and the average reusability was 78%. The obtained data indicated the excellent potential for the developed Fe3O4@MnO2 nanomaterial to act as an adsorbent, thus representing an alternative to the classical depollution methods. This study showed that nanoparticles have a photocatalytic effect against pathogenic bacteria and RhB azo dye in polluted waters and offer an effective catalytic activity to produce hydrogen as an alternative energy source.

One-step synthesized biogenic nanoparticles using Linum usitatissimum: Application of sun-light photocatalytic, biological activity and electrochemical H2O2 sensor.

This study aimed to synthesize Ag NPs as a green catalyst for photocatalytic activity and to examine their biological activities. It was determined that they have high activity in catalytic and biological activities. The green synthesis which is an environmentally friendly and inexpensive method was used to synthesize Ag-NPs using Linum usitatissimum as a reducing agent. Transmission electron microscopy (TEM), infrared to Fourier transform infrared (FTIR) spectroscopy, UV-Visible (UV-Vis) spectroscopy, and X-ray diffraction (XRD) were used to characterize the Ag NPs. In UV-Vis examination, Ag-NPs had intense peaks in the 435 nm region. The antibacterial activity of Ag NPs was investigated, and Ag NPs showed a high lethal effect against S. aureus, E. coli, B. subtilis, and MRSA. In addition, Ag NPs were tested for anticancer activity against the HT-29 colon cancer cell line, MDA-MB-231 breast cancer cell line, healthy cell line L929-Murine Fibroblast cell Lines, and MIA PaCa-2 human pancreatic cancer cell line at various concentrations (1-160 µg/mL) and showed a high anticancerogenic properties against MDA-MB-231 cells. Ag NPs showed the ability of DNA cleavage activity. Also, the antioxidant activity of Ag NPs against DPPH was found to be 80% approximately. Furthermore, the photocatalytic activity of Ag NPs against methylene blue (MB) was determined to be 67.13% at the 180th min. In addition, it was observed that biogenic Ag NPs have high electrocatalytic activity for hydrogen peroxide (H2O2) detection. In the sensor based on Ag NPs, linearity from 1 µM to 5 µM was observed with a detection limit (LOD) of 1.323 µM for H2O2. According to these results, we conclude that the biogenic Ag NPs synthesized using Linum usitatissimum extract can be developed as an efficient biological agent as an antibacterial and anticancer also can be used as a photocatalyst for industrial wastewater treatment to prevent wastewater pollution.

Efficient green photocatalyst of silver-based palladium nanoparticles for methyle orange photodegradation, investigation of lipid peroxidation inhibition, antimicrobial, and antioxidant activity.

Nanotechnology is an interdisciplinary study that has been developing worldwide in recent years and has a serious impact on human life. The fact that the nanoparticles of plant origin are clean, non-toxic, and biocompatible has enabled new fields of study. The Hibiscus sabdariffa (H. sabdariffa) plant has been attracted by scientists because of its impact on health and many other areas. The lipid peroxidation inhibiting activity, antioxidant properties, and antimicrobial properties of H. sabdariffa plant with Ag-Pd metal was ditermined. For the total phenolic component, gallic acid was used as the standard and quarcetin was used for the total flavonoid. The lipid peroxidation inhibition activity of Ag-Pd NPs in ethanol extract was found to be very well compared to the positive control (BHA). The lowest and highest concentrations of DPPH radical scavenging activity were 82.178-97.357%, whereas for BHA these values were found to be 84.142-94.142%. The highest concentration of Ag-Pd NPs at 200 µg/mL the DPPH radical quenching activity was higher than BHA. Ag-Pd NPs showed a good antimicrobial activity against certain pathogenic microorganisms such as Bacillus subtilis, Enterococcus faecalis, Escherichia coli, Pseudomonas aeruginosa, Candida albicans, which are the causative agents of various diseases in humans. The photodegradation activity of Ag-Pd NPs also investigated against Methyl orange dye (MO) under sunlight irradiation for 120 min and was found to be as 67.88.

Facile synthesis of biogenic palladium nanoparticles using biomass strategy and application as photocatalyst degradation for textile dye pollutants and their in-vitro antimicrobial activity.

Among biological applications, plant-mediated Pd NPs for multi-drug resistance (MDR) developed in pathogenic bacteria were synthesized with the help of biomass of lemon peel, a biological material, with a non-toxic, environmentally friendly, human-nature green synthesis method. Characterization of synthesized Pd NPs was carried out by UV-Vis spectrometry, Transmissive Electron Microscopy (TEM), X-ray diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR) techniques. According to TEM analysis, Pd NPs were confirmed to be in a spherical shape and the mean particle size was determined to be 4.11 nm. The crystal structure of Pd NPs was checked using XRD analysis and the mean particle size was observed to be 6.72 nm. Besides, the antibacterial activity of Pd NPs was determined against Escherichia coli (E. coli) (ATCC 8739), Bacillus subtilis (B. subtilis ATCC 6633), Staphylococcus aureus (S. aureus ATCC 6538), Klebsiella pneumoniae (K. pneumoniae ATCC 11296) and Serratia marcescens (S. marcescens ATCC) bacteria. Antibacterial activity was determined to be high in Pd NPs which is in conformance with the results acquired. The Pd NPs showed good photocatalytic activity, after 90 min illumination, about 81.55% and 68.45% of MB and MO respectively were catalysed by the Pd NPs catalyst, and 74.50% of RhB dyes were removed at 120 min of illumination. Within the scope of this project, it is recommended to use Pd NPs obtained by the green synthesis in the future as an antibacterial agent in biomedical use and for the cleaning of polluted waters.

Phyto-mediated synthesis of nanoparticles and their applications on hydrogen generation on NaBH4, biological activities and photodegradation on azo dyes: Development of machine learning model.

This work reports the synthesis of the silver-platinum bimetallic nanoparticles (N@Pt-Ag BNPs) reduced by an ethanolic extract of black seed (Nigella sativa, N) using the green synthesis method, these nanoparticles show a great antibacterial, anticancer, and catalytic activity. The characterization of physicochemical properties of Ag-Pt BNP was carried out using UV-visible spectroscopy (Uv-vis), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and Transmission electron microscope (TEM) analysis. The structural morphology shows that the N@Pt-Ag BNPs are spherical particles with a diameter of 5.6 nm. The cytotoxic effects of N@Pt-Ag BNPs were examined by MTT test in human breast cancer, human colon cancer, human pancreatic cancer, L929-Murine fibroblast cells. N@Pt-Ag BNPs have been observed to be much more effective in breast cancer cell lines. The cytotoxic effect of N@Pt-Ag BNPs against healthy L929-murine fibroblast cell lines was not observed. Also, high antibacterial activity on each of the bacteria Escherichia coli (E. coli), Bacillus subtilis (B. subtilis), Methicillin-resistant Staphylococcus aureus (MRSA), Staphylococcus aureus (S. aureus), where we note that most strains of E. coli and S. aureus were damaged with a 73% percentage, 67% bacterial inhibition respectively. The results of the catalytic activities of N@Pt-Ag BNPs were obtained by performing the hydrolysis experiments of sodium borohydride (NaBH4). According to the results obtained, TOF, enthalpy, entropy, and activation energy, values were found to be 2497.14 h-1, 13.52 kJ/mol, -137.47 J/mol.K, 16.02 kJ/mol, respectively. N@Pt-Ag BNPs were found to be highly effective catalysts for hydrogen production which this was also confirmed by the machine learning model. The photocatalytic activity of N@Pt-Ag BNPs was tested against methylene blue (MB) dye and the highest activity was found as 80%.