1.
Dalton Trans
; 42(4): 1159-67, 2013 Jan 28.
Article
in English
| MEDLINE
| ID: mdl-23117289
ABSTRACT
A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.