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Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin.
Han, Yuan-Zhang; Sanford, Melanie S; England, Michael D; Groves, John T.
Chem Commun (Camb) ; (5): 549-51, 2006 Feb 07.
Article in English | MEDLINE | ID: mdl-16432579

ABSTRACT

A new and remarkably facile sp3-C-O bond forming reaction of beta-hydroxyalkyl Rh porphyrins to form epoxides has been discovered and its mechanism investigated.


Subject(s)
Biomedical Research , Epoxy Compounds/chemistry , Hydroxides/chemistry , Porphyrins/chemistry , Rhodium/chemistry , Alkylation , Carbon/chemistry , Catalysis , Magnetic Resonance Spectroscopy , Molecular Structure , Oxygen/chemistry , Stereoisomerism
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