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Angew Chem Int Ed Engl ; 53(37): 9851-5, 2014 Sep 08.
Article in English | MEDLINE | ID: mdl-25088979

ABSTRACT

A simple method to convert readily available carboxylic acids into sulfinate salts by employing an interrupted Barton decarboxylation reaction is reported. A medicinally oriented panel of ten new sulfinate reagents was created using this method, including a key trifluoromethylcyclopropanation reagent, TFCS-Na. The reactivity of six of these salts towards C-H functionalization was field-tested using several different classes of heterocycles.


Subject(s)
Sulfinic Acids/chemistry , Sulfinic Acids/chemical synthesis , Acids, Heterocyclic , Catalysis , Models, Molecular , Molecular Structure
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