High Performance Piezoelectric Nanogenerators Based on Polyvinylidene Fluoride-Graphene Nanoribbon Composite Thin Films.

In this study, a highly efficient, sensitive, and lightweight piezoelectric nanogenerator (PENG) is developed using graphene nanoribbons (GNRs) incorporated into the polyvinylidene fluoride (PVDF) matrix. Unzipping multi-walled carbon nanotubes is an effective and scalable strategy for synthesizing graphene nanoribbons. The synthesized GNRs are employed to prepare nanometer-scale piezoelectric polymer composite films showing higher piezoelectric performance than neat PVDF. The impact of GNR concentration in the PVDF matrix on the electroactive phase content and piezoelectric properties of the composites is systematically investigated. X-ray diffraction (XRD) and Fourier-transformed infrared spectroscopy (FT-IR) analysis demonstrate an increase in the electroactive ß and γ phases of PVDF by incorporating GNRs in the composites. With the optimized concentration of GNRs (1 wt%), the fabricated piezoelectric device can generate open-circuit voltage and an output power density of 26 V and 16.52 µWcm2, respectively. It is also found that the PVDF-GNR 1 nanogenerator can be used to generate electrical power by converting mechanical energy from different human activities such as wrist bending, palm tapping, and toe tapping. The findings indicate that (PVDF-GNR 1) PENG can be applied in self-powered portable and wearable electronic devices.

Evaluation of Istanbul from the environmental components' perspective: what has changed during the pandemic?

This study aims to determine the 1-year change over the pandemic period in Istanbul, the megacity with the highest population in Turkey, based on environmental components. Among the environmental topics, water consumption habits, changes in air quality, changes due to noise elements, and most importantly, the changes in usage habits of disposable plastic materials that directly affect health have been revealed. The results obtained showed that, in Istanbul, 8.1 × 108 gloves should be considered waste, and considering the population living in districts along coastal areas, the number of waste masks that are likely to end up in the sea was 325.648 pieces/day. The results of the air quality and noise measurements during the pandemic showed that reductions in parallel with human activities were recorded with the lockdown effect. The average noise values of the districts along both sides of the Bosporus, where urbanization is concentrated, were between 50 and 59 dB. The precautions taken during the pandemic have had an effective role in reducing air pollution in Istanbul. In the measurements, the parameters with effective reductions were PM10 (7-47%), PM2.5 (13-48%), NO2 (13-38%), and SO2 (10-56%). As a result, Istanbul's year of changes during the pandemic period, in terms of water, air, noise, and solid plastic wastes, which are the most important components of the environment, is presented.