Spatial and seasonal variations in suspended particulate matter concentration and composition in the Persian Gulf: From dust deposition and sediment resuspension to biological production in the regulation of the particulate trace elements.

The present document is intended to fill the knowledge gap on spatiotemporal variation of suspended particulate matter (SPM) concentration and composition by collecting samples from 26 stations during two contrasting seasons of summer and winter. The horizontal distribution of surface SPM is characterized by hotspots (up to 4.0 mg/l) along the river estuaries which sharply declined to <1 mg/l in the offshore region. The average SPM concentration for surface, 25 m, and near-bottom decreased from summer to winter by a factor of 1.1, 1.3, and 1.7, respectively. In the offshore region, the particle composition was dominated by particulate organic matter which accounted for 66 % of bulk SPM. The concentration of opaline silica increased from summer to winter presumably from the bloom of diatoms. The concentration of particulate trace elements in winter decreased in the order of Fe â‰« Ba > Mn ≈ Zn > Ni ≈ Cr â‰« Pb > Cd. The non-crustal portion is the predominant fraction for most trace metals and shows enrichment relative to the upper continental crust, local soil background, and deposited dust that is highest for Cd and lowest for Mn.

Microplastic occurrence in finfish and shellfish from the mangroves of the northern Gulf of Oman.

This study was conducted to assess microplastic (MP) pollution in some aquatic animals inhabiting planted and natural mangrove swamps in the northern Gulf of Oman. The KOH-NaI solution was used to retrieve MPs from the gastrointestinal tracts of animals. The highest MP prevalence was recorded in crabs (41.65 %) followed by fish (33.89 %) and oysters (20.8 %). The abundance of MPs in examined animals varied from zero in Sphyraena putnamae to 11 particles in a Rhinoptera javanica specimen. When polluted-only animals were considered, the mean abundance of MPs significantly varied among species and between locations. The mean density of ingested MPs was higher in the planted mangrove animals (1.79 ± 2.89 vs. 1.21 ± 2.25 n/individual; mean ± SD). Among the examined fish species, R. javanica ingested the highest number of MPs (3.83 ± 3.93 n/individual; mean ± SD). The polyethylene/ polypropylene fragments or fibers of average 1900 µm size were recorded as predominant (>50 % occurrence) MP particles.

Seasonal variations, potential bioavailability, and ecological risk of phosphorus species in the coastal sediments of the Makran.

Eutrophication and algal blooms occur frequently in coastal waters of the Makran, for which phosphorus is an important driving factor. Therefore, in this study, sequential extraction procedure was used to evaluate abundance of five phosphorus chemical species. Total phosphorus (TP) concentration ranged from 672.3 to 2031.9 µg/g in pre-monsoon and 771.7 to 2095.7 µg/g in post-monsoon. More than 87% of TP was inorganic P and contribution of organic phosphorus was low. Potential bioavailable P (PBAP) comprised of 52.1 and 35.5% of TP in the pre and post-monsoon, respectively. Average phosphorus pollution index was higher than one in all stations and seasons, implying that sediments in the study area are polluted by phosphorus and are under eutrophication risk. Thus, in the future, foregoing information will be important for assessment of phosphorus loading and pollution in the Makran.

Hypoxia in the Persian Gulf and the Strait of Hormuz.

In this article dissolved oxygen results of research cruises through the Persian Gulf during 2018-2019 are discussed. The results showed that summer to autumn hypoxia occurred mainly at depths ≥ 50 m to the bottom. This seasonal hypoxia started in late summer reaching its greatest severity in mid-autumn with an area of 50,000 km2 in the Persian Gulf. The minimum oxygen measured at the near-bottom layer of the western basin in autumn (25.8 µmol/kg) was lower than any previous measurement in the open waters of the Persian Gulf. In the Strait of Hormuz, the seasonal hypoxia appeared in summer in the near bottom of the most eastern part at the Iranian side. pHT values recorded in hypoxic waters were as low as what is predicted for surface ocean under ocean acidification in 2100. Considering the results, we suggest evaluating the effects of hypoxia and acidification on the Persian Gulf ecosystems.

Microplastic pollution in the littoral sediments of the northern part of the Oman Sea.

Microplastics (MPs) have been increasingly detected as environmental pollutants in the marine systems. Currently, there is no information about the microplastic pollution in the littoral sediments of the northern Oman Sea, and this problem was addressed in the present study for the first time. Sediment samples were collected at eight sampling stations. MPs were extracted by the flotation method and then, counted and categorized according to their shape, size, and color. Composition of the MPs was determined by ATR-FTIR spectroscopy. MPs were observed in all the stations and their abundance ranged from 138.3 ± 4.5 to 930.3 ± 49.1 particles·kg-1. The major polymer constituent was Polyethylene, followed by Polypropylene, and Nylon. Fibers and fragments were dominant shapes of the MPs. Our results confirmed the prevalence of the MPs as anthropogenic pollutants in the area and highlighted the importance of management actions and education on environmental protection for reduction of the marine debris.

Highly sensitive colorimetric determination of amoxicillin in pharmaceutical formulations based on induced aggregation of gold nanoparticles.

A novel, simple and highly sensitive colorimetric method is developed for determination of Amoxicillin (AMX). The system is based on aggregation of citrate-capped gold nanoparticles (AuNP) in acetate buffer (pH=4.5) in the presence of the degradation product of Amoxicillin (DPAMX). It was found that the color of gold nanoparticles changed from red to purple and the intensity of surface plasmon resonance (SPR) peak of AuNPs decreased. A new absorption band was appeared in the wavelength range of 600-700nm upon addition of DPAMX. The absorbance ratio at the wavelength of 660 and 525nm (A660/A525) was chosen as the analytical signal indirectly related to AMX concentration. The linearity of the calibration graph was found over the concentration range of 0.3-4.5µM AMX with a correlation coefficient of 0.9967. Under the optimum experimental conditions, the detection limit was found to be 0.15µM. The applicability of the method was successfully demonstrated by analysis of AMX in pharmaceutical formulations including capsules and oral suspensions.

Development of a sensitive and selective Riboflavin sensor based on carbon ionic liquid electrode.

The electrochemical properties of Riboflavin adsorbed on carbon ionic liquid electrode (CILE) were studied by cyclic voltammetry. A film with a surface coverage of up to 3.3x10(-9) mol cm(-2) was formed after 10 min exposure time. Electron transfer coefficient and rate constant of electron transfer across the modified electrode were found to be 0.43 and 3.03 s(-1), respectively. Differential pulse voltammetry was used for the determination of Riboflavin. Two linear working ranges of 0.8-110 nM and 0.11-1.0 microM were obtained with correlation coefficients of 0.998 and 0.996, respectively. The experimental detection limit was obtained as 0.1 nM. The relative standard deviation for five replicate analyses was 4.7%. Other soluble vitamins had no significant interferences and the electrode was used for the determination of Riboflavin in pharmaceutical products, nutrition and beverages.