Effect of Rheological Properties of Polymer Solution on Polymer Flooding Characteristics.

Polymer flooding is an appropriate enhanced oil recovery (EOR) process that can increase macroscopic sweep efficiency. We examined two polymeric superpushers at different salinities (10,000 and 42,000 ppm of NaCl and 18,000 ppm of CaCl2) and temperatures (30 to 75 °C) as polymer-flooding agents for the EOR process. Rheological and thixotropic tests were attempted to find shear viscosity change when the polymer solutions were introduced under different salinity and temperatures, followed by describing the rheological behavior with the two most common rheological models used for polymer solutions, and then a quadratic model with Design-Expert to detect the effective parameters. Core flooding tests were conducted afterward to determine the final proposed fluid. An increase in the concentration of monovalent ions and the addition of divalent ions adversely affected both types of polymers used, which was similar to the effects of a temperature increase. The Flopaam 3630S at 1000 ppm has more stability under harsh conditions and enables 22% and 38% oil recovery in carbonate and sandstone core rocks, respectively. Consequently, Flopaam 3630S can be the perfect polymer agent for different chemical flooding procedures in high-salinity oil reservoirs.

An overview on the enhanced gas condensate recovery with novel and green methods.

A consideration of the negative environmental aspects of fossil fuels has made natural gas the best choice to meet the human demand for energy. The condensate gas reservoir is one source of gases that tolerates skin problems (liquid blockage). Conventional methods for inhibiting or removing liquid blockages are momentary treatments, non-eco-friendly, and expensive. Therefore, new methods have been introduced, such as wettability alteration toward liquid repellency, renewable energies, thermochemical reactions and waves for heating reservoirs, and CO2 injection. This paper reviews the methods for altering the wettability of porous media by fluorochemicals, fluorinated nanoparticles (NPs), and free fluorocarbon materials from natural substances. NPs, particularly silicon-based types, as a green, clean, and emerging technology that are more compatible with the environment, were investigated for their ability to alter the wettability and upgrade conventional materials, such as polymers and surfactants. The feasibility of using renewable energies, thermochemical reactions, and waves for heating the gas condensate reservoir to overcome the skin problem and return the reservoir to the reasonable and economical gas production is reviewed. Finally, CO2 injection is introduced as a multi-purpose green method to enhance gas condensate recovery and allow CO2 sequestration.

Artificial Neural Network to Forecast Enhanced Oil Recovery Using Hydrolyzed Polyacrylamide in Sandstone and Carbonate Reservoirs.

Polymer flooding is an important enhanced oil recovery (EOR) method with high performance which is acceptable and applicable on a field scale but should first be evaluated through lab-scale experiments or simulation tools. Artificial intelligence techniques are strong simulation tools which can be used to evaluate the performance of polymer flooding operation. In this study, the main parameters of polymer flooding were selected as input parameters of models and collected from the literature, including: polymer concentration, salt concentration, rock type, initial oil saturation, porosity, permeability, pore volume flooding, temperature, API gravity, molecular weight of the polymer, and salinity. After that, multilayer perceptron (MLP), radial basis function, and fuzzy neural networks such as the adaptive neuro-fuzzy inference system were adopted to estimate the output EOR performance. The MLP neural network had a very high ability for prediction, with statistical parameters of R2 = 0.9990 and RMSE = 0.0002. Therefore, the proposed model can significantly help engineers to select the proper EOR methods and API gravity, salinity, permeability, porosity, and salt concentration have the greatest impact on the polymer flooding performance.

Core-Shell Structured Magnetite-Poly(diphenylamine) Microspheres and Their Tunable Dual Response under Magnetic and Electric Fields.

Core-shell type poly(diphenylamine)-coated magnetite (Fe3O4-PDPA) microspheres were designed and adopted as a novel actively tunable smart material which is responsive under both electric and magnetic fields. Their morphology, chemical structure, crystalline structure, and thermal properties were characterized using scanning electron microscopy, transmission electron microscope, Fourier transform-infrared spectroscopy, X-ray diffraction, and a thermal gravimetric analyzer. Their magnetic and dielectric properties were determined using vibrating-sample magnetometer and an LCR meter, respectively. They were dispersed in silicone oil and their electrorheological (ER) and magnetorheological (MR) responses under the electric and magnetic fields, respectively, were examined. The formation of chain structure of Fe3O4-PDPA based E/MR fluid under the application of electric field or magnetic field was observed by an optical microscopy and the sedimentation stability was observed by a Turbiscan optical analyzer system. It was observed that the yield stress, ER efficiency, and leakage current density increased with an increase in the particle concentration, while the slope of the electric field-dependent yield stress decreased. Several models such as the Bingham model, Herschel-Bulkley model, and Cho-Choi-Jhon equations were used to describe the shear stress curves of the ER fluid; the curves fitted well. For the dielectric properties, the two types of ER fluids tested displayed the same relaxation time and distribution; however, the one with the higher concentration had a higher dielectric constant and polarizability. The Fe3O4-PDPA based MR fluid (10 vol %) exhibited typical MR properties. In addition, the Herschel-Bulkley model matched well with the shear stress curves under a magnetic field.

Conformance control in oil reservoir based on magnetorheological behavior of nanoparticle suspension.

Water shut off and performance control in oil reservoirs involve many techniques both for reducing the water cut and for enhancing oil production with the aim of making it economical and environmental friendly. Therefore, suitable nanoparticles for injection in an oil reservoir regarding nano size, spherical morphology, and better dispersibility were synthesized by one step, facile, and inexpensive method and then characterized in this work. In addition, new magnetorheological (MR) fluids based on the crude oil and the nanoparticles were developed, and the analysis of their rheological properties carried out by rotational and oscillation tests showed their ability of forming gel-like structure. Furthermore, from the core flooding experiment investigated, values of both resistance factor and residual resistance factor showed that the MR fluids exhibit a solid-like form with the magnetical field applied in oil reservoirs, thereby reducing the water cut.