ABSTRACT
This review reports on the recent advances in the synthesis and physico-chemical properties of palladium-containing perovskites. Initially, the perovskite structure is briefly reviewed, then palladium-containing perovskites synthesis and physico-chemical properties are detailed. The applications of palladium-containing perovskites in catalysis; namely, NO reduction, methane combustion, methanol as well as ethanol oxidation, are briefly highlighted. The involvement and the important contribution of palladium-containing perovskites in cross-coupling reactions, especially Suzuki-Miyaura, Sonogashira, Ulmann and Grignard, are discussed.
Subject(s)
Calcium Compounds/chemistry , Nanostructures/chemistry , Nanostructures/ultrastructure , Oxides/chemistry , Palladium/chemistry , Titanium/chemistry , Catalysis , Crystallization/methods , Particle SizeABSTRACT
Controlled titanium alkoxide mineralization in the presence of phosphonated, dendrimeric nano-building blocks provides a new family of hierarchically porous dendrimer-bridged titanium dioxide materials.