Unlocking Agronutrient Resources: Sorption Strategies for sugar-energy industry waste.

Vinasse and ash from sugarcane bagasse (SCB) are key byproducts in the sugar-energy industry. Vinasse is nutrient-rich but environmentally challenging, while sugarcane bagasse ash (SCBA) offers excellent adsorbent for treating effluents. This work aims to assess the effectiveness of SCBA in removing nitrogen (N) and potassium (K) nutrients from Vinasse. Simulated standard solutions of K2SO4 and (NH4)2HPO4 were used to mimic the nutrient concentrations in Vinasse and optimize experimental parameters such as adsorbent mass and contact time. Kinetic and isotherm models were also applied to elucidate the underlying adsorption mechanisms. Structural, morphological, and thermal analyses revealed the micro-mesoporous and heterogeneous nature of SCBA, primarily composed of SiO2 (quartz and cristobalite). The sorption assessment indicated the ideal conditions involved lower SCBA masses (2.5 g) and 6 h of contact time for the simulated standard solutions. The replicated conditions for Vinasse (at an adjusted sorption time of 24 h) demonstrated nutrient sorption and pH correction of the Vinasse, attributed to the alkaline nature of SCBA. Analysis of the sorption kinetic models for K+ and NH4+ revealed that SCBA interacts diffusively with the environment, not necessarily controlled by adsorption on active sites, indicating non-uniform characteristics. The sorption isotherms for K+ and NH4+ showed the non-linearized Freundlich model was the most suitable, indicating the adsorption sites with varying energy levels and a multilayer sorption process. In conclusion, we successfully demonstrated the sorption of nutrients from Vinasse by SCBA, enhancing the value of these residues and mitigating their environmental impact when used in agricultural applications.

Charged-cellulose nanofibrils as a nutrient carrier in biodegradable polymers for enhanced efficiency fertilizers.

An enhanced efficiency fertilizer (EEF) is essential for sustainable agriculture, and here, we evaluated cellulose nanofibrils (CNF) as a nutrient carrier dispersed in biodegradable polymeric matrices. CNF were functionalized with negative (CNF-) and positive (CNF+) charges to improve (i) the CNF-nutrient and (ii) the CNF-polymeric matrix interactions. The CNF encapsulated the KNO3 nutrient by spray drying (microcapsules) and then inserted into a poly (hydroxybutyrate)/starch-based matrix by melt-compounding (tablets). These materials were morphologically, structurally, and thermally characterized before and after biodegradation. Nutrient release profiles showed the microcapsules released the nutrients for up to 1 h, while the tablets did for 8 h in water and over 80 days in soil. Tablets with CNF- released NO3- faster than K+, and those with CNF+ behaved inversely. Besides, the biodegradation efficiencies were up to 75 % in 120 days. The CNF charges affected nutrient release and the matrix biodegradation, ensuring the matrices were harmless to the environment.

A review of advances over 20 years on polysaccharide-based polymers applied as enhanced efficiency fertilizers.

Over the last 20 years, polysaccharide-based materials have garnered attention in the enhanced efficiency fertilizers (EEFs) research. Biodegradability, non-toxicity, water-solubility, swellability, and ease of chemical modification make these polymers suitable for agricultural applications. In this review, the polysaccharides-based EEFs advances are summarized over the polymer and co-materials selection, the methods, and the chemical/structure aspects necessary for an appropriate production. We also briefly discuss terminologies, nutrient release mechanisms, biodegradation, and future trends. The most used polysaccharides are chitosan, starch, and alginate, and the non-Fickian model most describes the release mechanism. It is dependent on the relaxation of polymer chains by the matrix swelling followed by the nutrient diffusion. EEFs-polymers-based should be designed as more packed and less porous structures to avoid the immediate contact of the fertilizer with the surrounding water, improving fertilizer retention. Furthermore, the preparation methods will determine the scale-up of the material.

Micronutrients encapsulation by starch as an enhanced efficiency fertilizer.

Developing different paths to achieve sustainable agriculture is no longer an option; it is a necessity. EEF materials are alternatives to improve the efficacy of the agrochemicals in the soil and plant, reducing wasting and environmental contamination. The present work aims to develop EEF materials based on starch and micronutrients, considering few works address EEFs materials with micronutrients. Monoelementary dispersions of gelatinized starch with micronutrients (Fe, Cu, Mn) were spray-dried and thermally, structurally, and morphologically characterized. We evaluated water-medium nutrient release, release kinetics, and the swelling degree. Different micronutrients affect morphology, size distribution, swelling degree, release, kinetics, and interaction between polymer-nutrient. Bigger particle sizes achieved a higher swelling degree, which led to decreased micronutrient release in the water. The Peppas-Sahlin model mainly ruled the release kinetics (fitted to all the materials). This result confirmed our hypothesis that a swelling starch delays the release.

Biodegradation and viability of chitosan-based microencapsulated fertilizers.

Enhanced efficiency fertilizers (EEF) are an important subject for sustainable materials. It is fundamental for the released nutrient and biodegradation in the soil to have synergy to ensure material harmlessness. Chitosan, montmorillonite, and KNO3 were considered to develop the EEF because of the high biodegradation potential of the final product. We correlated the material biodegradability and release in water and soil to their formulation. We assume the materials are biodegradable since the biodegradation efficiency achieved over 30 %. As the nutrient diffusion and matrix degradation happen concomitantly, we also observed that the clay delays degradation and the KNO3 improved it. Likewise, the storage period can change the biodegradability properties once the material started to degrade. Hereupon, the amount of nutrient delivered will match the amount consumed by the plant, the matrix will degrade and no residue will be left in the soil.

Chitosan spray-dried microcapsule and microsphere as fertilizer host for swellable - controlled release materials.

A fertilizer delivery system based on chitosan (Ch) or chitosan/montmorillonite clay (Ch/MMt) was developed by spray drying technique using 2-fluid (2FN) and 3-fluid (3FN) nozzles. 2FN provided solid microspheres and 3FN formed microcapsules structures. Morphology is dependent upon formulation and the type of nozzle used. As higher the number of the components (polymer, clay and sodium tripolyphosphate (TPP)) in the microparticles more collapsed and non-shaped spheres are generated. Different structures provided distinct nutrient releasing profiles. Higher swelling values (∼500%) and slower fertilizer releasing process (under 70% in the firsts measurements) are observed for microcapsules. This phenomenon occurs due to entrapped nutrient by an extra chitosan outer layer. The swelling-controlled release mechanism was observed for both microcapsules and microspheres instead of diffusion-controlled. Swelling characteristic was confirmed in soil medium since after water irrigation higher fertilizer releases were observed.

Optical and Thermal Stability of Oligofluorene/Rubber Luminescent Blend.

This paper proposes to obtain homogeneous and stable blends of oligo(9,9-dioctylfluorene)-co-phenylene (OF), a conjugated oligomer with strong tendency of formation of excimers in the solid state, and nitrile rubber (NBR). This rubber protection reduces the formation of polymer excimers in the films. The fluorene oligomer was synthesized via Suzuki reaction and incorporated in the nitrile rubber. The films were formed by spin coating and casting techniques on the proportions of 1, 5, 10, 20 and 50 % (w/w) of OF in the nitrile rubber (NBR). The structural, optical and thermal properties of the films were evaluated with infrared, UV-Vis, fluorescence and thermogravimetry, respectively. The nitrile rubber proved to be essential for the preparation of homogeneous and stable films, since it was not possible to obtain films with only fluorene using the above-mentioned techniques. Furthermore, luminescent properties of OF are unchanged and the excimers formation in the solid state decrease suggesting the efficiency of nitrile rubber as the matrix for making films.

Chitosan-Montmorillonite microspheres: A sustainable fertilizer delivery system.

Controlled release fertilizers are efficient tools that increase the sustainability of agricultural practices. However, the biodegradability of the matrices and the determination of the release into soil still require some investigation. This paper describes the preparation of potassium-containing microspheres based on chitosan and montmorillonite clay and the in situ soil release. The chitosan-montmorillonite microspheres were prepared using a coagulation method and different proportions of montmorillonite. The structural, thermal and morphological properties as well the water swelling and fertilizer sorption capacity were evaluated. The best formulations were applied in soil, and the fertilizer release was monitored using time-domain reflectometry (TDR). Montmorillonite clay provides better sorption properties than the chitosan microspheres because of the rough and porous surface. Due to these properties, high levels of fertilizer were sorbed onto the material. ChMMT33-containing potassium shows two specific periods of fertilizer release: the first one lasted approximately three days and was assigned to the external fertilizer on the microspheres. The second was assigned to the internal fertilizer. TDR is an important and fast tool and was used to determine the fertilizer release and the ion movement in the soil.