ABSTRACT
Interlayered thin-film nanocomposite (TFN) membranes have shown the potential to boost nanofiltration performance for water treatment applications including the removal of organic micropollutants (OMPs). However, the effects of substrates have been overlooked when exploiting and evaluating the efficacy of certain kinds of interlayers in tailoring membrane performance. Herein, a series of TFN membranes were synthesized on different porous substrates with identical interlayers of metal-organic framework nanosheets. It was revealed that the interlayer introduction could narrow but not fully eliminate the difference in the properties among the polyamide layers formed on different substrates, and the membrane performance variation was prominent in distinct aspects. For substrates with small pore sizes exerting severe water transport hindrance, the introduced interlayer mainly enhanced membrane water permeance by affording the gutter effect, while it could be more effective in reducing membrane pore size by improving the interfacial polymerization platform and avoiding PA defects when using a large-pore-size substrate. By matching the selected substrates and interlayers well, superior TFN membranes were obtained with simultaneously higher water permeance and OMP rejections compared to three commercial membranes. This study helps us to objectively understand interlayer efficacies and attain performance breakthroughs of TFN membranes for more efficient water treatment.
ABSTRACT
Development of well-constructed metal-organic framework (MOF) membranes can bring about breakthroughs in nanofiltration (NF) performance for water treatment applications, while the relatively loose structures and inevitable defects usually cause low rejection capacity of MOF membranes. Herein, a confined interfacial polymerization (CIP) method is showcased to synthesize polyamide (PA)-modified NF membranes with MOF nanosheets as the building blocks, yielding a stepwise transition from two-dimensional (2D) MOF membranes to polyamide NF membranes. The CIP process was regulated by adjusting the loading amount of piperazine (PIP)-grafted MOF nanosheets on substrates and the additional content of free PIP monomers distributed among the nanosheets, followed by the reaction with trimesoyl chloride in the organic phase. The prepared optimal membrane exhibited a high Na2SO4 rejection of 98.4% with a satisfactory water permeance of 37.4 L·m-2·h-1·bar-1, which could be achieved by neither the pristine 2D MOF membranes nor the PA membranes containing the MOF nanosheets as the conventional interlayer. The PA-modified MOF membrane also displayed superior stability and enhanced antifouling ability. This CIP strategy provides a novel avenue to develop efficient MOF-based NF membranes with high ion-sieving separation performance for water treatment.
Subject(s)
Metal-Organic Frameworks , Nylons , Polymerization , ChloridesABSTRACT
Nanofiltration (NF) membranes have been widely used in various fields including water treatment and other separation processes, while conventional thin film composite (TFC) membranes with polyamide (PA) selective layers suffer the problems of fouling and chlorine intolerance. Due to the abundant hydrophilic hydroxyl groups and ester bonds free from chlorine attack, the TFC membranes composed of polyester (PE) or polyester-amide (PEA) selective layers have been proven to possess enhanced anti-fouling properties and superior chlorine resistance. In this review, the research progress of PE and PEA nanofiltration membranes is systematically summarized according to the variety of hydroxyl-containing monomers for membrane fabrication by the interfacial polymerization (IP) reaction. The synthesis strategies as well as the mechanisms for tailoring properties and performance of PE and PEA membranes are analyzed, and the membrane application advantages are demonstrated. Moreover, current challenges and future perspectives of the development of PE and PEA nanofiltration membranes are proposed. This review can offer guidance for designing high-performance PE and PEA membranes, thereby further promoting the efficacy of nanofiltration.
