1.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 6): m759-60, 2012 Jun 01.
Article
in English
| MEDLINE
| ID: mdl-22719318
ABSTRACT
The title double mol-ecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues. The Cd(II) atom adopts a near-regular CdO(6) octa-hedral coordination geometry. The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O-Hâ¯O and N-Hâ¯O hydrogen bonds are observed. No thermal anomalies corresponding to possible phase transitions were observed in DSC (differential scanning calorimetry) measurements and the 93â K structure is almost the same as the room-temperature structure.