ABSTRACT
Trifluralin [2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzenamine], metolachlor [2-chloro-N-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) aceta mide], and metribuzin [4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4,-triazin-5(4H) -one] were selected to study adsorption and leaching potentials related to pollution on Commerce silty clay loam soil near Baton Rouge, Louisiana. At a I:10 soil/water ratio, the Koc values for trifluralin, metolachlor and metribuzin were 875, 135, and 96, respectively. Leaching of these herbicides was evaluated in soil columns (5.4 cm i.d. x 26 cm long). Total recoveries of the herbicides applied to the soil column were 73.1% +/- 4.1%. When the soil columns were leached with three pore volumes of water, the distributions of trifluralin in soil and leachate were 99.993% and 0.007% of the total recoveries, respectively. The distributions of metolachlor was 65.27% in soil and 34.7% in leachate. The distributions of metribuzin was 11.42% in soil and 88.58% in leachate. The results showed that metolachlor and metribuzin were readily leached, while trifluralin was strongly adsorbed to soil. Leaching of three herbicides in the soil column followed the leaching trends of their calculated leaching indices 1.41 x 10(4), 4.18 x 10(6), and 3.38 x 10(8) for trifluralin, metolachlor, and metribuzin, respectively. The results of the study demonstrated the potential of pollution for metolachlor and metribuzin to be leached into the ground water in soils with shallow aquifer.
Subject(s)
Acetamides/chemistry , Herbicides/chemistry , Soil Pollutants , Triazines/chemistry , Trifluralin/chemistry , Acetamides/isolation & purification , Adsorption , Herbicides/isolation & purification , Kinetics , Soil Pollutants/isolation & purification , Triazines/isolation & purification , Trifluralin/isolation & purificationABSTRACT
Water, lipid, and mineral composition were determined for metacarpals, phalanges, livers, and antlers from 219 free-ranging white-tailed deer (Odocoileus virginianus) collected on six properties in East Feliciana Parish, Louisiana (USA) to provide baseline data and to identify sources of composition variation. Metacarpal and phalangeal composition varied primarily with deer age; liver composition varied with deer sex.
Subject(s)
Body Composition , Deer/metabolism , Minerals/analysis , Age Factors , Animals , Antlers/chemistry , Body Water/chemistry , Bone and Bones/chemistry , Female , Lipids/analysis , Liver/chemistry , Louisiana , Male , Metacarpus/chemistry , Nutritional Status , Reference Values , Sex Characteristics , Specific Gravity , ToesABSTRACT
Two commercially important species of Louisiana crayfish, Procambarus clarkii (Girard) and P. acutus acutus (Girard), from the Atchafalaya River Basin, from open ponds and from the sediment and water of these environs were sampled three times during two consecutive fishing (production) seasons. The abdominal muscle and hepatopancreatic tissue were analyzed separately. Lead, mercury, and cadmium, if present, were in concentrations below the detection limit. In the hepatopancreatic tissue, barium was present in concentrations below 8 mg/kg, copper 11-15 mg/kg, and iron below 640 mg/kg. Abdominal muscle samples had less than 3 mg/kg of most metals. Locations with the highest levels of metal residues in sediment were not necessarily locations where crayfish had the highest levels in their tissues.
