Evidence of Tribological Adaptation Controlled by Tribosynthesis of FeWO4 on an WC-Reinforced Electron Beam M2 Steel Coating Rubbed against a HSS Disk in a Range of Sliding Speeds.

In the present work, the tribological experiments on sliding the electron beam composite M2+WC coating have been carried out with characterization of the sample microstructures and phases both before and after the testing using metallography, SEM, EDS, and XRD. The sliding in the speed range 0.8-3.6 m/s resulted in simultaneous reduction in both wear rate and coefficient of friction with the sliding speed. Investigations showed that such a tribological adaptation was due to the tribochemical generation of lubricative FeWO4 and Fe2WO6 mixed oxides and the generation of a mechanically mixed composite layer on the worn surfaces that consisted of carbide fragments, an oxidized metal matrix, and was lubricated by in-situ formed mixed iron-tungsten oxides.