High-current space-charge-limited pulses using ultrashort laser pulses.

The maximum current that can be delivered by a 1-D vacuum diode is limited due to the space-charge reduction of the accelerating field. For a steady-state operation, this is given by the Child-Langmuir space-charge limit. However, for pulsed diode sources, the instantaneous current can be much higher than this limit, as long as the pulse length is much less than the transit time across the diode gap. This enables the generation of high current pulses with pulse durations of the order of tens of picoseconds using photocathodes driven by ultrashort laser pulses. The generation of such short and powerful electromagnetic pulses is important for numerous applications such as ultrawideband radar or as photocathode sources for accelerators. In this work, the limiting current pulse is investigated in the case of a very short, square-top initial pulse and it is found that these pulses propagate in a self-similar manner, remaining as a square-top charge cloud in space throughout their acceleration and propagation. The resultant current and pulse duration turn out to be dependent on only three parameters, which are the applied voltage, the vacuum transit time, and the fraction of the saturation charge density in the initial charge cloud. The resultant scaling of the resultant peak current and pulse duration are calculated numerically as a function of starting sheet-charge density, allowing the calculation of the resultant pulses for any ultrashort, pulse-driven vacuum photodiode design.

X-ray radiation monitor for measuring solids content in fluid fine tailings.

The extraction of bitumen from oil sands produces fluid fine tailings (FFT) consisting mainly of water, sands, clay, and residual bitumen. Generally, devices with radioactive sources are used to measure the variation of FFT density or solids concentration inline, but to date there is no suitable device for in situ monitoring in tailings storage facilities such as large tailings ponds. In this study, an alternative method using high-resolution spectrometry based on a low radiation intensity source and a cadmium telluride (CdTe) detector was used to measure the solids content in tailings samples based on X-ray attenuation. The radiation source used in the experiment was a 1 µCi 133 Ba. GEANT4, a Monte Carlo-based simulation code that calculates the transmission of radiation through matter, was used to simulate the results of this study and build calibration curves that can determine the solids content concentration based on measured sample composition. Experiments and simulations were performed on various concentrations of both actual FFT samples from tailings facilities and kaolin as a model material. Good agreement between the experimental and simulation results was observed, paving the way for a potential real-time solids content measurement system that could be deployed over large areas to measure the settling of FFT in tailings ponds.

Optimal Laguerre-Gaussian modes for high-intensity optical vortices.

With increasing interest in using orbital angular momentum (OAM) modes in high-power laser systems, accurate mathematical descriptions of the high-intensity modes at focus are required for realistic modeling. In this work, we derive various high-intensity orbital angular momentum focal spot intensity distributions generated by Gaussian, super-Gaussian, and ideal flat-top beams common to high-power laser systems. These intensity distributions are then approximated using fitted Laguerre-Gaussian basis functions as a practical way for describing high-power OAM beams in theoretical and numerical models.

Off-axis spiral phase mirrors for generating high-intensity optical vortices.

In this work, we present a novel, to the best of our knowledge, and practical method for generating optical vortices in high-power laser systems. Off-axis spiral phase mirrors are used at oblique angles of incidence in the beam path after amplification and compression, allowing for the generation of high-power optical vortices in almost any laser system. An off-axis configuration is possible via modification of the azimuthal gradient of the spiral phase helix and is demonstrated with a simple model using a discrete spiral staircase. This work presents the design, fabrication, and implementation of off-axis spiral phase mirrors in both low- and high-power laser systems.

Observation of long-range dipole-dipole interactions in hyperbolic metamaterials.

Dipole-dipole interactions (V dd) between closely spaced atoms and molecules are related to real photon and virtual photon exchange between them and decrease in the near field connected with the characteristic Coulombic dipole field law. The control and modification of this marked scaling with distance have become a long-standing theme in quantum engineering since dipole-dipole interactions govern Van der Waals forces, collective Lamb shifts, atom blockade effects, and Förster resonance energy transfer. We show that metamaterials can fundamentally modify these interactions despite large physical separation between interacting quantum emitters. We demonstrate a two orders of magnitude increase in the near-field resonant dipole-dipole interactions at intermediate field distances (10 times the near field) and observe the distance scaling law consistent with a super-Coulombic interaction theory curtailed only by absorption and finite size effects of the metamaterial constituents. We develop a first-principles numerical approach of many-body dipole-dipole interactions in metamaterials to confirm our theoretical predictions and experimental observations. In marked distinction to existing approaches of engineering radiative interactions, our work paves the way for controlling long-range dipole-dipole interactions using hyperbolic metamaterials and natural hyperbolic two-dimensional materials.

Spectral calibration of EBT3 and HD-V2 radiochromic film response at high dose using 20 MeV proton beams.

Radiochromic film is used extensively in many medical, industrial, and scientific applications. In particular, the film is used in analysis of proton generation and in high intensity laser-plasma experiments where very high dose levels can be obtained. The present study reports calibration of the dose response of Gafchromic EBT3 and HD-V2 radiochromic films up to high exposure densities. A 2D scanning confocal densitometer system is employed to carry out accurate optical density measurements up to optical density 5 on the exposed films at the peak spectral absorption wavelengths. Various wavelengths from 400 to 740 nm are also scanned to extend the practical dose range of such films by measuring the response at wavelengths removed from the peak response wavelengths. Calibration curves for the optical density versus exposure dose are determined and can be used for quantitative evaluation of measured doses based on the measured optical densities. It was found that blue and UV wavelengths allowed the largest dynamic range though at some trade-off with overall accuracy.

Mode conversion efficiency to Laguerre-Gaussian OAM modes using spiral phase optics.

An analytical model for the conversion efficiency from a TEM00 mode to an arbitrary Laguerre-Gaussian (LG) mode with null radial index spiral phase optics is presented. We extend this model to include the effects of stepped spiral phase optics, spiral phase optics of non-integer topological charge, and the reduction in conversion efficiency due to broad laser bandwidth. We find that through optimization, an optimal beam waist ratio of the input and output modes exists and is dependent upon the output azimuthal mode number.

A dynamic strategy for wavelength sensing using the diffracted orders of a grating.

We propose a strategy for real time multicolour detection of light emitting particles under flow conditions, using the diffracted orders of a grating. The method relies on the fact that the spatial (angular/linear) separation between the orders of a diffraction grating is a wavelength dependent quantity. Thus, the difference in arrival times at a fixed detector for neighbouring orders produced by a moving, light-emitting particle can be used as a wavelength sensing mechanism. We demonstrate this functionality using a prototype PDMS microfluidic device that incorporates a focusing transmission grating. A key attribute of this approach is that it requires only a single sensitive detector, such as a photomultiplier tube, in contrast to many conventional approaches which require multiple sensitive detectors or a detector array.

Reduced Ensemble Plasmon Line Widths and Enhanced Two-Photon Luminescence in Anodically Formed High Surface Area Au-TiO2 3D Nanocomposites.

Localized surface plasmon resonances (LSPR) in TiO2 nanorod and nanotube arrays decorated by gold nanoparticles can be exploited to improve photocatalytic activity, enhance nonlinear optical coefficients, and increase light harvesting in solar cells. However, the LSPR typically has a low quality factor, and the resonance is often obscured by the Urbach tail of the TiO2 band gap absorption. Attempts to increase the LSPR extinction intensity by increasing the density of gold nanoparticles on the surface of the TiO2 nanostructures invariably produce peak broadening due to the effects of either agglomeration or polydispersity. We present a new class of hybrid nanostructures containing gold nanoparticles (NPs) partially embedded in nanoporous/nanotubular TiO2 by performing the anodization of cosputtered Ti-Au thin films containing a relatively high ratio of Au:Ti. Our method of anodizing thin film stacks containing alternate layers of Ti and TiAu results in very distinctive LSPR peaks with quality factors as high as 6.9 and ensemble line widths as small as 0.33 eV even in the presence of an Urbach tail. Unusual features in the anodization of such films are observed and explained, including oscillatory current transients and the observation of coherent heterointerfaces between the Au NPs and anatase TiO2. We further show that such a plasmonic NP-embedded nanotube structure dramatically outperforms a plasmonic NP-decorated anodic nanotube structure in terms of the extinction coefficient, and achieves a strongly enhanced two-photon fluorescence due to the high density of gold nanoparticles in the composite film and the plasmonic local field enhancement.

Photophysics and energy transfer studies of Alq3 confined in the voids of nanoporous anodic alumina.

We report on a hierarchical nanoarchitecture wherein distinct chromophores are deterministically placed at two different types of sites in a nanoporous metal oxide framework. One chromophore, namely Tris(8-hydroxyquinoline)aluminium(III) (Alq3), is embedded in the 1-2 nm sized nanovoids of anodic aluminum oxide (AAO) and another chromophore (carboxyfluorescein or pyrenebutyric acid) is anchored in the form of a monolayer to the surface of the walls of the cylindrical nanopores (- 20 nm in diameter) of AAO. We found the luminescence maximum to occur at 492 nm, blueshifted by at least 18 nm from the value in solutions and thin films. The excited state decay of Alq3 molecules in nanovoids was found to be biexponential with a fast component of 338 ps and a slower component of 2.26 ns, different from Alq3 thin films and solutions. Using a combination of steady state and time-resolved luminescence studies, we found that efficient Forster-type resonance energy transfer (FRET) from Alq3 in the nanovoids to the carboxyfluorescein monolayer could be used to pump the emission of surface-bound chromophores. Conversely, the emission of nanovoid-confined Alq3 could be pumped by energy transfer from a pyrenebutyric acid monolayer. Such intra-nanoarchitecture interactions between chromophores deterministically placed in different spatial locations are important in applications such as organic light emitting diodes, chemical sensors, energy transfer fluorescent labels, light harvesting antennas and organic spintronics.

Permanent fine tuning of silicon microring devices by femtosecond laser surface amorphization and ablation.

We demonstrate the fine tuning capability of femtosecond laser surface modification as a permanent trimming mechanism for silicon photonic components. Silicon microring resonators with a 15 µm radius were irradiated with single 400 nm wavelength laser pulses at varying fluences. Below the laser ablation threshold, surface amorphization of the crystalline silicon waveguides yielded a tuning rate of 20 ± 2 nm/J · cm(-2)with a minimum resonance wavelength shift of 0.10nm. Above that threshold, ablation yielded a minimum resonance shift of -1.7 nm. There was some increase in waveguide loss for both trimming mechanisms. We also demonstrated the application of the method by using it to permanently correct the resonance mismatch of a second-order microring filter.

Femtosecond laser tuning of silicon microring resonators.

Femtosecond laser modification is demonstrated as a possible method for postfabrication tuning of silicon microring resonators. Single 400 nm femtosecond laser pulses were used to modify the effective index of crystalline silicon microring waveguides by either amorphization or surface nanomilling depending on the laser fluence. Both blue- and redshifts in the microring resonance could be achieved without imparting significant degradation to the device quality factor.

Surface-enhanced raman scattering (SERS) detection of low concentrations of tryptophan amino acid in silver colloid.

The surface-enhanced Raman scattering (SERS) spectrum of L-tryptophan has been studied in the concentration range 1.4 × 10(-8) to 5 × 10(-4) M. A borohydride-reduced silver colloid was employed as the nanoparticle enhancing agent and different electrolytes have been tested for activation of the colloid. The optimum conditions have been determined for achieving high sensitivity of detection. The experimental procedure developed, which includes the use of a composite electrolyte (a mixture of NaHCO(3) and NaCl) for colloid activation, results in very high enhancement of the Raman signal (up to 10(8)). This gives the possibility of studying SERS spectra of L-tryptophan at concentrations as low as 10(-8) M, which is several orders of magnitude lower than previously reported in the literature. The observed SERS spectra were very reproducible and were detectable 2 minutes after mixing, reaching maximum strength approximately 15 minutes after mixing. The spectral characteristics were stable over the entire period of observation. We have found that SERS spectra of tryptophan in silver colloid differ in several features at low (below ∼10(-5) M) and at high (above ∼10(-4) M) concentrations. The most important difference is the absence of the peak near 1000 cm(-1) at low concentrations, which is usually assigned to the indole ring breathing mode. The observed spectra allow us to suggest that at low concentrations Trp molecules bind to the surface through the indole ring, which remains flat on the surface. This is in contrast to the previously reported observation of SERS spectra from Trp performed at concentration levels above 10(-5) M.

Optical resolution photoacoustic microscopy using novel high-repetition-rate passively Q-switched microchip and fiber lasers.

Optical-resolution photoacoustic microscopy (OR-PAM) is a novel imaging technology for visualizing optically absorbing superficial structures in vivo with lateral spatial resolution determined by optical focusing rather than acoustic detection. Since scanning of the illumination spot is required, OR-PAM imaging speed is limited by both scanning speed and laser pulse repetition rate. Unfortunately, lasers with high repetition rates and suitable pulse durations and energies are not widely available and can be cost-prohibitive and bulky. We are developing compact, passively Q-switched fiber and microchip laser sources for this application. The properties of these lasers are discussed, and pulse repetition rates up to 100 kHz are demonstrated. OR-PAM imaging was conducted using a previously developed photoacoustic probe, which enabled flexible scanning of the focused output of the lasers. Phantom studies demonstrate the ability to image with lateral spatial resolution of 7±2 µm with the microchip laser system and 15±5 µm with the fiber laser system. We believe that the high pulse repetition rates and the potentially compact and fiber-coupled nature of these lasers will prove important for clinical imaging applications where real-time imaging performance is essential.

Passively Q-switched Yb3+:NaY(WO4)2 laser with GaAs saturable absorber.

Passively Q-switched Yb(3+):NaY(WO(4))(2) lasers have been demonstrated using a GaAs saturable absorber. Under continuous wave pump mode, significant pulse shortening effects have been observed at high pump powers. At a pump power of 12 W, stable Q-switched output has been obtained with a pulse duration of 5 ns, pulse repetition rate of 83 kHz and a pulse to pulse timing jitter of less than 2%. With pulsed pump mode, much longer pulse duration and reduced pulse stability have been observed. It is proposed that the heating of GaAs may play an important role in the Q-switched operations under CW pump conditions.

High-peak-power subnanosecond passively Q-switched ytterbium-doped fiber laser.

A passively Q-switched ytterbium doped fiber laser has been demonstrated with a Cr(4+):yttrium aluminum garnet saturable absorber and distributed stimulated Brillouin scattering. A linearly polarized output with approximately 375 kW peak power and a pulse duration as short as 490 ps have been obtained. A theoretical model is developed to simulate passive Q switching with the stimulated Brillouin scattering, which shows good agreement with the experiment.

Two-wavelength ytterbium-doped fiber laser with sustained relaxation oscillation.

Dual-wavelength radiation around 1044 nm and 1070 nm has been generated directly from a cladding pumped Yb-doped fiber laser. Outputs of the two wavelengths exhibit sustained relaxation oscillation with anticorrelated dynamics. Modeling of the transient built up of the free-running laser shows the two-wavelength behavior can be attributed to the existence of two gain peaks of Yb-doped fiber under intermediate pump conditions.

Two-wavelength passively Q-switched ytterbium doped fiber laser.

A high power passively Q-switched dual wavelength Yb fiber laser using a Cr4+:YAG saturable absorber has been realized. Two wavelengths centered at 1040 nm and 1070 nm are generated directly from the cladding pumped Yb doped fiber laser. The pulse trains exhibit regions of stability and instability dependent on the pump power. At a pump power of 7.8 W, 1040 nm and 1070 nm pulses are generated alternatively, with pulse durations of 105 ns, pulse-repetition rates of 32 KHz and average pulse energies of 56 microJ and 47 microJ, respectively. A theoretical model is developed to simulate the two-wavelength Q-switched operation, which gives qualitative agreement with the experimental observations.

Elemental analysis using micro laser-induced breakdown spectroscopy (microLIBS) in a microfluidic platform.

We present here a non-labeled, elemental analysis detection technique that is suitable for microfluidic chips, and demonstrate its applicability with the sensitive detection of sodium (Na). Spectroscopy performed on small volumes of liquids can be used to provide a true representation of the composition of the isolated fluid. Performing this using low power instrumentation integrated with a microfluidic platform makes it potentially feasible to develop a portable system. For this we present a simple approach to isolating minute amounts of fluid from bulk fluid within a microfluidic chip. The chip itself contains a patterned thin film resistive element that super-heats the sample in tens of microseconds, creating a micro-bubble that extrudes a micro-droplet from the microchip. For simplicity a non-valved microchip is used here as it is highly compatible to a continuous flow-based fluidic system suitable for continuous sampling of the fluid composition. We believe such a nonlabeled detection technique within a microfluidic system has wide applicability in elemental analysis. This is the first demonstration of laser-induced breakdown spectroscopy (LIBS) as a detection technology in conjunction with microfluidics, and represents first steps towards realizing a portable lower power LIBS-based detection system.

Photoluminescence emission profiles of Y(2)O(3) : Eu films composed of high-low density stacks produced by glancing angle deposition.

Periodic high-/low-index film stacks composed of Y(2)O(3) : Eu were grown by glancing angle deposition on silicon and fused silica substrates. Postdeposition annealing at temperatures from 600 to 1000 degrees C for 1 h in air was performed to activate photoluminescence. Absolute photoluminescence spectra were obtained as a function of observation angle. The angular emission distribution was non-Lambertian, with peak emission at angles of 50 to 60 degrees with respect to substrate normal. Spectroscopic transmittance and ellipsometry measurements were performed to characterize the films. Using this description, we were able to reproduce the angular photoluminescence patterns of the films.