Soft periodic microstructures containing liquid crystals.

An empty polymeric structure has been realized by combining a high precision level optical holographic setup and a selective microfluidic etching process. The distinctive features of the realized periodic microstructure enabled aligning several kinds of liquid crystal (LC) compounds, without the need of any kind of surface chemistry or functionalization. In particular, it has been possible to exploit light sensitive LCs for the fabrication of all-optical devices, cholesteric and ferroelectric LCs for ultrafast electro-optical switches, and a common LC for a two-dimensional periodic structure with high anisotropy. All-optical and electro-optical experiments, performed for investigating the samples in terms of switching voltages and response times, confirm good performances of the realized devices.

Blue-shifted random-laser-mode selection in gain-assisted anisotropic complex fluids.

Random laser action in organic materials is of great topical interest that is fueled by the rapid development of active compounds and new dye molecules. We propose a pure-diffusive model to describe the strong connection established between a dye-host interaction and the scattering when considering an anisotropic complex fluid. The model considers multiple scattering induced by dielectric tensor fluctuations and a suitable quantistic description for light amplification in order to explain the generation of the narrow-band blue-shifted lasing mode experimentally observed in such systems. We also find that the introduction of a strong intermolecular force field provides the condition to enhance diffusive processes. The agreement between experimental observations and simulations advances the understanding of the physical mechanism behind mode selection in these systems.

Mechanically generated surface chirality at the nanoscale.

A substrate coated with an achiral polyimide alignment layer was scribed bidirectionally with the stylus of an atomic force microscope to create an easy axis for liquid crystal orientation. The resulting noncentrosymmetric topography resulted in a chiral surface that manifests itself at the molecular level. To show this unambiguously, a planar-aligned negative dielectric aniostropy achiral nematic liquid crystal was placed in contact with the surface and subjected to an electric field E. The nematic director was found to undergo an azimuthal rotation approximately linear in E. This so-called "surface electroclinic effect" is a signature of surface chirality and was not observed when the polyimide was treated for a centrosymmetric topography, and therefore was nonchiral.

Coherent backscattering and dynamical light localization in liquid crystals driven throughout chaotic regimes.

An important effect of dynamical localization of light waves in liquid crystal electro-hydrodynamic instabilities is reported by investigating coherent backscattering effects. Recurrent multiple scattering in dynamic and chaotic complex fluids lead to a cone of enhanced backscattered light. The cone width and the related mean free path dependence on the dynamic scattering regimes emphasize the diverse light localization scales related to the internal structures present in the sample. The systems investigated up to now were mainly nano-powdered solutions or biological tissues, without any external control on the disorder. Here, an anisotropic complex fluid is "driven" throughout chaotic regimes by an external electric field, giving rise to dynamics that evolve through several spatio-temporal patterns.

Patterning-induced surface chirality and modulation of director twist in a nematic cell.

A substrate coated with a polyimide alignment layer is scribed bidirectionally with the stylus of an atomic force microscope to create an easy axis for liquid-crystal orientation. The resulting noncentrosymmetric topography breaks two-dimensional inversion symmetry and results in a spatial amplitude modulation of an imposed twisted nematic state. This is observed optically as spatially periodic light and dark stripes. When the alignment layer is scribed unidirectionally the centrosymmetric topography maintains inversion symmetry, and no stripes are observed. The appearance of the twist modulation is consistent with a chiral term in the free energy.

Statistical analysis of random lasing emission properties in nematic liquid crystals.

A statistical analysis of random lasing events observed in dye-doped nematic-liquid-crystal films is reported. The occurrence of random laser action in such complex fluids is due to residual resonances in the multiple scattering of spontaneously emitted photons. The Shannon entropy and a local-Poisson test are used here in order to quantitatively characterize the chaotic behavior of laser spikes and gain further understanding of the mechanisms underlying the lasing effect in strongly scattering organized fluids arising by an unexpected interplay of localization and amplification.

Random lasing in freely suspended dye-doped nematic liquid crystals.

Random lasing in fully disordered systems having organic and inorganic nature has been the subject of extensive studies since the beginning of the past decade. The interest mainly emerges from the unexpected role played by disorder in the laser action. The disorder was considered detrimental for the optical feedback in cavity laser, until it was demonstrated that multiple-scattering materials including a gain medium act as random laser. Here, a completely new approach is reported, where freely suspended complex fluid films doped with fluorescent molecules under optical excitation generate narrowband lasing peaks. The constellation of localized modes is selected by properly choosing the gain profile. The idea to have laser action in absence of mirrors and boundaries realizes an unparalleled tunable and moldable laser source.