Different surface treatment strategies on etchable CAD-CAM materials: Part 1-Effect on the surface morphology.

STATEMENT OF PROBLEM: Polymer-based computer-aided design and computer-aided manufacturing (CAD-CAM) materials have either a high content of ceramic filler particles or a ceramic network structure. Proper etching of these materials is challenging. Therefore, it is relevant to assess different surface etching strategies and morphological alterations as a result of these techniques. PURPOSE: The purpose of this 2-part in vitro study was to evaluate different etching strategies on the surface roughness and its relationship to the surface contact angle with a subsequent morphological characterization of different CAD-CAM materials. MATERIAL AND METHODS: Two CAD-CAM polymer-based materials and 1 CAD-CAM ceramic material were selected for this study. The materials were treated with different strategies, including a combination of airborne-particle abrasion and an application of 9% hydrofluoric acid etching. After the surface treatment, roughness measurements (Sa) were assessed by using an optical profilometer on an area of 1.47 mm2. Subsequently, the contact angle on the surface was examined by means of the sessile drop technique and an optical contact angle meter. The data were analyzed by using a 2-way analysis of variance, the post hoc Tukey test (α=.05), and the Pearson correlation coefficient. RESULTS: The 3 materials tested showed an increase in surface roughness when treated with surface airborne-particle abrasion. However, the materials with polymer in their composition concomitantly increased the contact angle. More hydrophilic surfaces were observed when hydrofluoric acid was applied, regardless of the composition of the materials. The surface roughness presented a strong positive linear tendency in the surface treatments used. CONCLUSIONS: The application of airborne-particle abrasion on the surface of the polymer-based CAD-CAM materials increased the roughness and contact angle. However, the application of acid etching after the airborne-particle abrasion decreased the contact angle for polymer-based CAD-CAM materials, resulting in considerable enhancement of the surface quality for proper bonding.

Different surface treatment strategies on etchable CAD-CAM materials: Part II-Effect on the bond strength.

STATEMENT OF PROBLEM: Bonding to recently launched polymer-based computer-aided design and computer-aided manufacturing (CAD-CAM) materials has been challenging. Evidence regarding etching strategies for dual-phase CAD-CAM materials is sparse, but adequate bonding is crucial for the clinical success and longevity of a restoration. PURPOSE: The purpose of this 2-part in vitro study was to evaluate and compare the effect of surface treatment strategies on the microshear bond strength and work of adhesion of polymer-based and ceramic materials. In addition, chemical elements present on the surface and the interface morphology after using those strategies were also assessed. MATERIALS AND METHODS: Two CAD-CAM polymer and 1 CAD-CAM ceramic materials were selected for this in vitro study. The materials were subjected to different surface treatment strategies, including airborne-particle abrasion and the application of 9% hydrofluoric acid. Specimens were submitted to microshear bond strength before and after thermocycling, and the failure mode was classified. The work of adhesion was calculated based on the water-to-air surface tension of 72.8 mN.m-1 and the Young- Dupré equation. The surfaces were submitted to energy-dispersive X-ray spectroscopy, and the interfaces were analyzed using a scanning electron microscope. Data were subjected to 2-way ANOVA and the Tukey post hoc test (α=.05). RESULTS: The highest microshear bond strength means were observed for the polymer-based materials when hydrofluoric acid or airborne-particle abrasion was applied. The 3 materials tested showed a decrease in microshear bond strength after thermocycling, except for applying airborne-particle abrasion to 1 of the polymer-based material tested. The ceramic material tested showed a high microshear bond strength with the application of airborne-particle abrasion and hydrofluoric acid combined. The work of adhesion varied across the materials and presented high means when hydrofluoric acid was used. CONCLUSIONS: A combination of airborne-particle abrasion plus hydrofluoric acid should be considered for polymer-based or feldspathic ceramic CAD-CAM materials. In this in vitro study, both etching procedures combined produced higher bonding values for all materials tested.

Evaluation of silver methenamine method for nanoleakage.

OBJECTIVES: The aim of this study was to evaluate nanoleakage patterns following silver methenamine staining of restorations bonded with a total-etch single bottle system, a self-etching primer system and a total-etch single bottle system after collagen depletion. METHODS: The dentin bonding systems used in this study were Prime and bond 2.1 (PB) and Clearfil SE Bond (CSEB). Cavities were made in grounded labial surfaces of 15 extracted bovine lower incisors, randomly divided into 3 Groups. Group 1 (PB), Group 2 (CSEB) and Group 3 (PB/SH) PB after collagen depletion with sodium hypochlorite (SH). The specimens were restored, sectioned and submitted to silver methenamine staining, polished and observed with low-vacuum back-scattered SEM. One way ANOVA and multiple-comparison Tukey's test were used for statistical analysis of the leakage scores. RESULTS: PB presented significantly greater silver deposition and a distinct pattern when compared to CSEB. No silver deposition was detected for PB after collagen depletion. SIGNIFICANCE: The dentine bonding systems tested were unable to prevent nanoleakage when used according to the manufacturers' instructions; however, CSEB presented a lower level of silver deposition. Collagen depletion prior to PB application may prevent nanoleakage occurrence in dentine walls. Silver methenamine staining may be a useful method for detection of nanoleakage in dentine when the collagen fibrils remain exposed within the hybrid layers.