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Chem Commun (Camb) ; 54(51): 6979-6982, 2018 Jun 21.
Article in English | MEDLINE | ID: mdl-29796494

ABSTRACT

Successful synthesis of the first transuranium metal-organic frameworks (TRU-MOFs) involving tetravalent Np4+ is reported. These compounds were obtained from the controlled hydrolysis of Np4+ in the presence of dicarboxylate ligands. The final structures contain the [Np6O4(OH)4(H2O)6]12+ unit, which were never crystallized before with tetravalent neptunium, associated with ditopic ligands.

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