ABSTRACT
The article refers to new polycaprolactone (PCL) composites with high concentration of calcium carbonate (CC). The objective of the present study was the manufacturing of PCL-based biodegradable composites, containing from 24 to 75 % of CC by mass, along with analyses of changes in selected properties of the obtained PCL composites, occurring upon various amounts of CC. Importantly, in the study relatively cheap and unmodified kind of CC has been used to determine the changeover cost of produced composites. Qualitative and quantitative analyses in addition to structure analysis of the obtained composites, including the distribution of the filler particles and their average dimensions were conducted. Furthermore, the mechanical and thermal properties, mass melt flow rate and the density have been determined. Finally, a commercially important economic analysis has been presented. A significant influence of CC on the mechanical properties of PCL was found. Specifically, the reduction of its relative elongation at break and impact strength, as well as the increase of its flexural modulus and bending strength. An increase in the thermal stability of the produced composites was also observed, however the characteristic temperatures of phase transitions as well as the degree of crystallinity did not change significantly. Considering the results of the density tests, an increase in the CC content resulted in a significant decrease in the unit price of the produced composites. This is of particular application importance, because a lower cost material with new properties could be obtained.
ABSTRACT
To assess the impact of graphite fillers on the thermal processing of graphite/poly(lactic acid) (PLA) composites, a series of the composite samples with different graphite of industrial grade as fillers was prepared by melt mixing. The average size of the graphite grains ranged between 100 µm and 6 µm. For comparative purposes, one of the carbon fillers was expandable graphite. Composites were examined by SEM, FTIR, and Raman spectroscopy. As revealed by thermogravimetric (TG) analyses, graphite filler slightly lowered the temperature of thermal decomposition of the PLA matrix. Differential scanning calorimetry (DSC) tests showed that the room temperature crystallinity of the polymer matrix is strongly affected by the graphite filler. The crystallinity of the composites determined from the second heating cycle reached values close to 50%, while these values are close to zero for the neat polymer. The addition of graphite to PLA caused a slight reduction in the oxidation induction time (OIT). The melt flow rate (MFR) of the graphite/PLA composites was lower than the original PLA due to an increase in flow resistance associated with the high crystallinity of the polymer matrix. Expandable graphite did not cause changes in the structure of the polymer matrix during thermal treatment. The crystallinity of the composite with this filler did not increase after first heating and was close to the neat PLA MFR value, which was extremely high due to the low crystallinity of the PLA matrix and delamination of the filler at elevated temperature.
