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1.
Molecules ; 28(2)2023 Jan 09.
Article in English | MEDLINE | ID: mdl-36677734

ABSTRACT

A detailed study of charge transport in the paramagnetic phase of the cage-cluster dodecaboride Ho0.8Lu0.2B12 with an instability both of the fcc lattice (cooperative Jahn−Teller effect) and the electronic structure (dynamic charge stripes) was carried out at temperatures 1.9−300 K in magnetic fields up to 80 kOe. Four mono-domain single crystals of Ho0.8Lu0.2B12 samples with different crystal axis orientation were investigated in order to establish the singularities of Hall effect, which develop due to (i) the electronic phase separation (stripes) and (ii) formation of the disordered cage-glass state below T*~60 K. It was demonstrated that a considerable intrinsic anisotropic positive component ρanxy appears at low temperatures in addition to the ordinary negative Hall resistivity contribution in magnetic fields above 40 kOe applied along the [001] and [110] axes. A relation between anomalous components of the resistivity tensor ρanxy~ρanxx1.7 was found for H||[001] below T*~60 K, and a power law ρanxy~ρanxx0.83 for the orientation H||[110] at temperatures T < TS~15 K. It is argued that below characteristic temperature TS~15 K the anomalous odd ρanxy(T) and even ρanxx(T) parts of the resistivity tensor may be interpreted in terms of formation of long chains in the filamentary structure of fluctuating charges (stripes). We assume that these ρanxy(H||[001]) and ρanxy(H||[110]) components represent the intrinsic (Berry phase contribution) and extrinsic (skew scattering) mechanism, respectively. Apart from them, an additional ferromagnetic contribution to both isotropic and anisotropic components in the Hall signal was registered and attributed to the effect of magnetic polarization of 5d states (ferromagnetic nano-domains) in the conduction band of Ho0.8Lu0.2B12.

2.
Adv Mater ; 32(10): e1906725, 2020 Mar.
Article in English | MEDLINE | ID: mdl-31997471

ABSTRACT

SmB6 has recently attracted considerable interest as a candidate for the first strongly correlated topological insulator. Such materials promise entirely new properties such as correlation-enhanced bulk bandgaps or a Fermi surface from spin excitations. Whether SmB6 and its surface states are topological or trivial is still heavily disputed however, and a solution is hindered by major disagreement between angle-resolved photoemission (ARPES) and scanning tunneling microscopy (STM) results. Here, a combined ARPES and STM experiment is conducted. It is discovered that the STM contrast strongly depends on the bias voltage and reverses its sign beyond 1 V. It is shown that the understanding of this contrast reversal is the clue to resolving the discrepancy between ARPES and STM results. In particular, the scanning tunneling spectra reflect a low-energy electronic structure at the surface, which supports a trivial origin of the surface states and the surface metallicity of SmB6 .

3.
J Phys Condens Matter ; 30(26): 265402, 2018 Jul 04.
Article in English | MEDLINE | ID: mdl-29790852

ABSTRACT

High-quality single crystals of LuB12 are grown using the induction zone melting method. The x-ray data are collected at temperatures 293, 135, 95, 50 K. The crystal structure of LuB12 can be refined with record low R-factor in the cubic Fm [Formula: see text] m symmetry group despite reiterated observations of the cubic symmetry distortions both in the unit-cell values and in the physical properties. A peculiar computing strategy is developed to resolve this contradiction. True symmetry of the electron-density distribution in LuB12 is proved to be much lower than cubic as a result, which correlates very accurately with anisotropy of transport properties of LuB12.

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