Correlations between the Structures and Spectra of Protonated Water Clusters.

Badger's rule-like correlations between OH stretching frequencies and intensities and the OH bond length are used to develop a spectral mapping procedure for studies of pure and protonated water clusters. This approach utilizes the vibrationally averaged OH bond lengths, which were obtained from diffusion Monte Carlo simulations that were performed using the general potential developed by Yu and Bowman. Good agreement is achieved between the spectra obtained using this approach and previously reported spectra for H+(H2O)n clusters, with n = 3, 4, and 5, as well as their perdeuterated analogues. The analysis of the spectra obtained by this spectral mapping approach supports previous work that assigned the spectrum of H+(H2O)6 to a mixture of Eigen and Zundel-like structures. Analysis of the calculated spectra also suggests a reassignment of the frequency of one of the transitions that involves the OH stretching vibration of the OH bonds in the hydronium core in the Eigen-like structure of H+(H2O)6 from 1917 cm-1 to roughly 2100 cm-1. For D+(D2O)6, comparison of the measured spectrum to those obtained by using the spectral mapping approach suggests that the carrier of the measured spectrum is one or more of the isomers of D+(D2O)6 that contain a four-membered ring and two flanking water molecules. While there are several candidate structures, the two flanking water molecules most likely form a chain that is bound to the hydronium core.

Isotope Effects in the Zundel-Eigen Isomerization of H+(H2O)6.

The isomerization pathway between the energetically low-lying Zundel and Eigen isomers of the protonated water hexamer was investigated using high-level ab initio calculations including a treatment of zero-point corrections. On the basis of these calculations, the Zundel-Eigen isomerization was found to proceed through a stable intermediate isomer, which consists of a four-membered ring with two single acceptor water molecules. The inclusion of vibrational zero-point energy is shown to be important for accurately establishing the relative energies of the three relevant isomers involved in the Zundel-Eigen isomerization. Diffusion Monte Carlo calculations including anharmonic vibrational effects show that all three isomers of H+(H2O)6 and D+(D2O)6 have well-defined structures. The energetic ordering of the three isomers changes upon deuteration. The implications of these results for the vibrational spectra of H+(H2O)6 and D+(D2O)6 are also discussed.

Isotope Effects on Ground and Excited States of Ethyl Cation, H+(C2H4).

The structure and spectra of ethyl cation, H+(C2H4), and its deuterated analogues are investigated using diffusion Monte Carlo (DMC). These calculations all show that the ground state wave function for H+(C2H4) is localized near the minimum energy configuration in which the excess proton is in a bridging configuration, although the amplitude of the vibrational motions of the bridging proton is large. Deuteration of the bridging proton reduces the amplitude of this motion, while deuteration of only the ethylenic hydrogen atoms in H+(C2D4) has little effect on the amplitude of the motion of the bridging proton. Excited states that are accessed by spectroscopically observed transitions in H+(C2H4) are calculated using fixed-node DMC. The calculated and measured frequencies for the states with one quantum of excitation in the ethylenic CH stretching vibrations show good agreement. We also explore the excited state with one quantum of excitation in the proton transfer vibration of the bridging proton and obtain a frequency of 616 cm-1 for H+(C2H4). This frequency increases to 629 cm-1 in H+(C2D4). Deuteration decreases this frequency to 491 and 495 cm-1 in D+(C2H4) and D+(C2D4), respectively. The effects of partial deuteration on the frequencies of the CH stretching vibrations, and the corresponding probability amplitudes are also explored. Finally, we report the vibrationally averaged rotational constants for the four isotopologues of ethyl cation considered in this study.

Fast Near Ab Initio Potential Energy Surfaces Using Machine Learning.

A machine-learning based approach for evaluating potential energies for quantum mechanical studies of properties of the ground and excited vibrational states of small molecules is developed. This approach uses the molecular-orbital-based machine learning (MOB-ML) method to generate electronic energies with the accuracy of CCSD(T) calculations at the same cost as a Hartree-Fock calculation. To further reduce the computational cost of the potential energy evaluations without sacrificing the CCSD(T) level accuracy, GPU-accelerated Neural Network Potential Energy Surfaces (NN-PES) are trained to geometries and energies that are collected from small-scale Diffusion Monte Carlo (DMC) simulations, which are run using energies evaluated using the MOB-ML model. The combined NN+(MOB-ML) approach is used in variational calculations of the ground and low-lying vibrational excited states of water and in DMC calculations of the ground states of water, CH5+, and its deuterated analogues. For both of these molecules, comparisons are made to the results obtained using potentials that were fit to much larger sets of electronic energies than were required to train the MOB-ML models. The NN+(MOB-ML) approach is also used to obtain a potential surface for C2H5+, which is a carbocation with a nonclassical equilibrium structure for which there is currently no available potential surface. This potential is used to explore the CH stretching vibrations, focusing on those of the bridging hydrogen atom. For both CH5+ and C2H5+ the MOB-ML model is trained using geometries that were sampled from an AIMD trajectory, which was run at 350 K. By comparison, the structures sampled in the ground state calculations can have energies that are as much as ten times larger than those used to train the MOB-ML model. For water a higher temperature AIMD trajectory is needed to obtain accurate results due to the smaller thermal energy. A second MOB-ML model for C2H5+ was developed with additional higher energy structures in the training set. The two models are found to provide nearly identical descriptions of the ground state of C2H5+.

Using Diffusion Monte Carlo Wave Functions to Analyze the Vibrational Spectra of H7O3+ and H9O4.

An approach for evaluating spectra from ground state probability amplitudes (GSPA) obtained from diffusion Monte Carlo (DMC) simulations is extended to improve the description of excited state energies and allow for coupling among vibrational excited states. This approach is applied to studies of the protonated water trimer and tetramer, and their deuterated analogs. These ions provide models for solvated hydronium, and analysis of these spectra provides insights into spectral signatures of proton transfer in aqueous environments. In this approach, we obtain a separable set of internal coordinates from the DMC ground state probability amplitude. A basis is then developed from products of the DMC ground state wave function and low-order polynomials in these internal coordinates. This approach provides a compact basis in which the Hamiltonian and dipole moment matrix are evaluated and used to obtain the spectrum. The resulting spectra are in good agreement with experiment and in many cases provide comparable agreement to the results obtained using much larger basis sets. In addition, the compact basis allows for interpretation of the spectral features and how they evolve with cluster size and deuteration.

Guided Diffusion Monte Carlo: A Method for Studying Molecules and Ions That Display Large Amplitude Vibrational Motions.

Diffusion Monte Carlo provides an effective and efficient approach for calculating ground state properties of molecular systems based on potential energy surfaces. The approach has been shown to require increasingly large ensembles when intra- and intermolecular vibrations are weakly coupled. We recently proposed a guided variant of diffusion Monte Carlo to address these challenges for water clusters [Lee, V. G. M.; McCoy, A. B. J. Phys. Chem. A 2019, 123, 8063-8070]. In the present study, we extend this approach and apply it to more strongly bound molecular ions, specifically CH5+ and H+(H2O)n=1-4. For the protonated water systems, we show that the guided DMC approach that was developed for studies of (H2O)n can be used to describe the OH stretches and HOH bends in the solvating water molecules, as well as the free OH stretches in the hydronium core. For the hydrogen bonded OH stretches in the H3O+ core of H+(H2O)n and the CH stretches in CH5+, we develop adaptive guiding functions based on the instantaneous structure of the ion of interest. Using these guiding functions, we demonstrate that we are able to obtain converged zero-point energies and ground state wave functions using ensemble sizes that are as small as 10% the size that is needed to obtain similar accuracy from unguided calculations.