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1.
J Chem Theory Comput ; 20(11): 4869-4884, 2024 Jun 11.
Article in English | MEDLINE | ID: mdl-38818701

ABSTRACT

Comparisons between simulated and experimental adsorption isotherms in MOFs are fraught with challenges. On the experimental side, there is significant variation between isotherms measured on the same system, with a significant percentage (∼20%) of published data being considered outliers. On the simulation side, force fields are often chosen "off-the-shelf" with little or no validation. The effect of this choice on the reliability of simulated adsorption predictions has not yet been rigorously quantified. In this work, we fill this gap by systematically quantifying the uncertainty arising from force field selection on adsorption isotherm predictions. We choose methane adsorption, where electrostatic interactions are negligible, to independently study the effect of the framework Lennard-Jones parameters on a series of prototypical materials that represent the most widely studied MOF "families". Using this information, we compute an adsorption "consensus isotherm" from simulations, including a quantification of uncertainty, and compare it against a manually curated set of experimental data from the literature. By considering many experimental isotherms measured by different groups and eliminating outliers in the data using statistical analysis, we conduct a rigorous comparison that avoids the pitfalls of the standard approach of comparing simulation predictions to a single experimental data set. Our results show that (1) the uncertainty in simulated isotherms can be as large as 15% and (2) standard force fields can provide reliable predictions for some systems but can fail dramatically for others, highlighting systematic shortcomings in those models. Based on this, we offer recommendations for future simulation studies of adsorption, including high-throughput computational screening of MOFs.

2.
Chem Sci ; 15(8): 2857-2866, 2024 Feb 22.
Article in English | MEDLINE | ID: mdl-38404369

ABSTRACT

The synthesis of multivariate metal-organic frameworks (MOFs) is a well-known method for increasing the complexity of porous frameworks. In these materials, the structural differences of the ligands used in the synthesis are sufficiently subtle that they can each occupy the same site in the framework. However, multivariate or ligand scrambling approaches are rarely used in the synthesis of porous metal-organic polyhedra (MOPs) - the molecular equivalent of MOFs - despite the potential to retain a unique intrinsic pore from the individual cage while varying the extrinsic porosity of the material. Herein we directly synthesise scrambled cages across two families of lantern-type MOPs and find contrasting effects on their gas sorption properties. In one family, the scrambling approach sees a gradual increase in the BET surface area with the maximum and minimum uptakes associated with the two pure homoleptic cages. In the other, the scrambled materials display improved surface areas with respect to both of the original, homoleptic cages. Through analysis of the gas sorption isotherms, we attribute this effect to the balance of micro- and mesoporosity within the materials, which varies as a result of the scrambling approach. The gas uptake of the materials presented here underscores the tunability of cages that springs from their combination of intrinsic, extrinsic, micro- and meso-porosities.

3.
Gels ; 9(6)2023 Jun 07.
Article in English | MEDLINE | ID: mdl-37367139

ABSTRACT

A suite of composite materials comprising carbon xerogel content and TiO2 was synthesised via a modified sol-gel method. The textural, morphological, and optical properties of the composites were extensively characterised and correlated with the observed adsorption and photodegradation performances. The homogeneity and porous structure of the composites depended on the amount of TiO2 deposited in the carbon xerogel. During polymerisation, Ti-O-C linkages were formed, which favoured the adsorption and photocatalytic degradation of the target methylene blue dye. Adsorption was deemed favourable, and most accurately fitted by the Sips model, exhibiting a maximum uptake of 209 mg g-1 estimated for the sample containing 50% TiO2. However, the synergistic effect of adsorption and photocatalytic degradation for each composite depended on the amount of TiO2 deposited in the carbon xerogel. The dye degradation process for the composites with 50%, 70%, and 90% TiO2 improved by 37%, 11%, and 2%, respectively, after exposure to visible light after adsorption. Repeated runs demonstrated over 80% of activity was retained after four cycles. Thus, this paper provides insight into the optimal amount of TiO2 required within such composites for maximum removal efficiency via adsorption and visible light photocatalysis.

4.
Phys Chem Chem Phys ; 25(21): 14869-14878, 2023 May 31.
Article in English | MEDLINE | ID: mdl-37199074

ABSTRACT

The applicability of Raman spectroscopy for phase discrimination of metal-organic frameworks (MOFs) has been demonstrated with F4_MIL-140A(Ce) and F4_UiO-66(Ce); analogues prepared from the same metal and ligand sources. Each analogue exhibits unique Raman peaks, with significant differences in the low frequency region, which is more sensitive to structural variations. Non-invasive Raman monitoring of F4_MIL-140A(Ce) synthesis indicated evolution of a unique MOF Raman peak with reaction progress; conversion of this Raman signal to extent of crystallisation was in good agreement with reported reaction kinetics determined via a synchrotron diffraction method. Additionally, Raman spectroscopy indicated initial rapid consumption of the nitric acid modulator present in the reaction coinciding with an expected high probability of nucleation. Raman spectroscopy is a promising technique for rapid screening of MOFs and can be used to study the mechanism of their formation in situ with kinetic insight into both the solution and solid phases of the reaction medium.

5.
Chemistry ; 29(32): e202300732, 2023 Jun 07.
Article in English | MEDLINE | ID: mdl-37022280

ABSTRACT

Three new ligands containing a bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxydiimide unit have been used to assemble lantern-type metal-organic cages with the general formula [Cu4 L4 ]. Functionalisation of the backbone of the ligands leads to distinct crystal packing motifs between the three cages, as observed with single-crystal X-ray diffraction. The three cages vary in their gas sorption behaviour, and the capacity of the materials for CO2 is found to depend on the activation conditions: softer activation conditions lead to superior uptake, and one of the cages displays the highest BET surface area found for lantern-type cages so far.


Subject(s)
Metals , Ligands , Porosity , Biological Transport , Crystallography, X-Ray
6.
Molecules ; 27(23)2022 Dec 02.
Article in English | MEDLINE | ID: mdl-36500576

ABSTRACT

Recent studies on the removal of pollutants via adsorption include the use of carbon-based adsorbents, due to their high porosity and large surface area; however, such materials lack photoactive properties. This study evaluates the synergistic effect of integrated mesoporous carbon xerogel (derived from resorcinol formaldehyde) and titanium dioxide (TiO2) for combined adsorption and photodegradation application. The complex formed between carbon xerogel and TiO2 phase was investigated through FTIR, proving the presence of a Ti-O-C chemical linkage. The physicochemical properties of the synthesised adsorbent-photocatalyst were probed using FESEM, BET analysis and UV-Vis analysis. The kinetics, equilibrium adsorption, effect of pH, and effect of adsorbent dosage were investigated. The expansion of the absorbance range to the visible range was verified, and the corresponding band gap evaluated. These properties enabled a visible light response when the system was exposed to visible light post adsorption. Hence, an assistive adsorption-photodegradation phenomenon was successfully executed. The adsorption performance exhibited 85% dye degradation which improved to 99% following photodegradation. Further experiments showed the reduction of microorganisms under visible light, where no microbial colonies were observed after treatment, indicating the potential application of these composite materials.


Subject(s)
Environmental Pollutants , Photolysis , Titanium/chemistry , Adsorption , Carbon , Catalysis
7.
Gels ; 8(4)2022 Apr 01.
Article in English | MEDLINE | ID: mdl-35448117

ABSTRACT

A new strategy to synthesise carbon/TiO2 gel by a sol-gel method is proposed. Textural, morphological, and chemical properties were characterised in detail and the synthesised material was proven to be an active adsorbent, as well as a visible light photocatalyst. Homogenously distributed TiO2 is mesoporous with high surface area and, hence, exhibited a high adsorption capacity. The adsorption equilibrium experimental data were well explained by the Sips isotherm model. Kinetic experiments demonstrated that experimental data fitted a pseudo second order model. The modification in electronic structure of TiO2 resulted in a reduced bandgap compared to commercial P25. The absorption edge studied through UV-Vis shifted to the visible region, hence, daylight photocatalytic activity was efficient against degradation of MB dye, as an example pollutant molecule. The material was easily removed post treatment, demonstrating potential for employment in industrial water treatment processes.

8.
Gels ; 8(1)2022 Jan 15.
Article in English | MEDLINE | ID: mdl-35049595

ABSTRACT

The production of resorcinol-formaldehyde xerogels has yielded insight into the gelation processes underpinning their structures. In this work, the role of the cation species from the catalyst is probed by studying the simultaneous addition of sodium carbonate and calcium carbonate to a resorcinol-formaldehyde mixture. Twenty-eight xerogels were prepared by varying the solids content, catalyst concentration, and catalyst composition, and each was analysed for its textural properties, including the surface area and average pore diameter. The results indicate that the role of the cation is linked to the stabilisation of the clusters formed within the system, and that the Group II catalyst causes the salting out of the oligomers, resulting in fewer, larger clusters, hence, an increase in pore size and a broadening of the pore size distribution. The results provide insight into how these systems can be further controlled to create tailored porous materials for a range of applications.

9.
J Clin Psychol ; 78(7): 1267-1287, 2022 07.
Article in English | MEDLINE | ID: mdl-34993964

ABSTRACT

BACKGROUND: Prior research indicates that patients' personality traits are associated with psychotherapy processes and outcomes. However, the potential relevance of therapists' personality traits is less understood. METHODS: This is a scoping review of studies investigating associations between therapists' personality traits with treatment processes and outcomes. Three databases (Scopus, PsycINFO, and Web of Science) were searched, identifying 27 eligible studies synthesized using a narrative review of key findings. RESULTS: The influence of therapists' personality traits was studied in relation to therapeutic orientation, interpersonal skills, therapist competence and skill, model fidelity, treatment outcomes, therapeutic alliance, and therapist well-being. Findings indicate that therapists' personality traits are associated with the choice of therapeutic orientation and with interpersonal skills, but there is mixed evidence about associations with clinical outcomes. CONCLUSION: Therapists' personality traits are associated with therapeutic orientation and interpersonal skills. However, it remains unclear whether therapists' personality traits influence other aspects of therapeutic processes or outcomes.


Subject(s)
Professional-Patient Relations , Psychotherapists , Humans , Personality , Psychotherapy , Treatment Outcome
10.
Gels ; 7(3)2021 Sep 15.
Article in English | MEDLINE | ID: mdl-34563028

ABSTRACT

Resorcinol-formaldehyde (RF) gels are porous materials synthesized via a sol-gel reaction and subsequently dried, producing structures with high surface areas and low densities-properties that are highly attractive for use in various applications. The RF gel reaction takes place in the presence of a catalyst, either acidic or basic in nature, the concentration of which significantly impacts final gel properties. The full extent of the catalyst's role, however, has been subject to debate, with the general consensus within the field being that it is simply a pH-adjuster. The work presented here explores this theory, in addition to other theories postulated in the literature, through the synthesis and analysis of RF gels catalysed by mixtures of relevant compounds with varying concentrations. The relationship between catalyst concentration and initial solution pH is decoupled, and the individual roles of both the cation and the anion within the catalyst are investigated. The results presented here point towards the significance of the metal cation within the RF gel reaction, with similar structural properties observed for gels synthesized at constant Na+ concentrations, regardless of the initial solution pH. Furthermore, through the use of alternative cations and anions within catalyst compounds, the potential effects of ions on the stabilization of macromolecules in solution are explored, the results of which suggest a 'Hofmeister-like' series could be applicable within the catalysis of RF gel reactions.

11.
J Phys Chem B ; 125(7): 1960-1969, 2021 Feb 25.
Article in English | MEDLINE | ID: mdl-33591747

ABSTRACT

Assessing the efficacy of specific porous materials for use in various applications has been a central focus for many experimental studies over the years, with a view to altering the material properties according to the desired characteristics. The application potential for one such class of nanoporous materials-organic resorcinol-formaldehyde (RF) gels-is of particular interest, due to their attractive and adjustable properties. In this work, we simulate adsorption analysis using lattice-based mean field theory, both in individual pores and within three-dimensional porous materials generated from a kinetic Monte Carlo cluster aggregation model. We investigate the impacts of varying pore size and geometry on the adsorptive behavior, with results agreeing with those previously postulated in the literature. The adsorption analysis is carried out for porous materials simulated with varying catalyst concentrations and solids contents, allowing their structural properties to be assessed from resulting isotherms and the adsorption and desorption processes visualized using density color maps. Isotherm analysis indicated that both low catalyst concentrations and low solids contents resulted in structures with open transport pores that were larger in width, while high catalyst concentrations and solids contents resulted in structures with bottleneck pores that were narrower. We present results from both the simulated isotherms and pore size analysis distributions, in addition to results from RF gels synthesized in the lab and analyzed experimentally, with significant similarities observed between the two. Not only do the results of this comparison validate the kinetic Monte Carlo model's ability to successfully capture the formation of RF gels under varying synthesis parameters, but they also show significant promise for the tailoring of material properties in an efficient and computationally inexpensive manner-something which would be pivotal in realizing their full application potential, and could be applied to other porous materials whose formation mechanism operates under similar principles.

12.
Faraday Discuss ; 225: 133-151, 2021 Feb 01.
Article in English | MEDLINE | ID: mdl-33179673

ABSTRACT

The metal-organic framework (Me2NH2)2[Cd(NO2BDC)2] (SHF-81) comprises flattened tetrahedral Cd(O2CR)42- nodes, in which Cd(ii) centres are linked via NO2BDC2- ligands (2-nitrobenzene-1,4-dicarboxylate) to give a doubly interpenetrated anionic network, with charge balanced by two Me2NH2+ cations per Cd centre resident in the pores. The study establishes that this is a twinned α-quartz-type structure (trigonal, space group P3x21, x = 1 or 2), although very close to the higher symmetry ß-quartz arrangement (hexagonal, P6x22, x = 2 or 4) in its as-synthesised solvated form [Cd(NO2BDC)2]·2DMF·0.5H2O (SHF-81-DMF). The activated MOF exhibits very little N2 uptake at 77 K, but shows significant CO2 uptake at 273-298 K with an isosteric enthalpy of adsorption (ΔHads) at zero coverage of -27.4 kJ mol-1 determined for the MOF directly activated from SHF-81-DMF. A series of in situ diffraction experiments, both single-crystal X-ray diffraction (SCXRD) and powder X-ray diffraction (PXRD), reveal that the MOF is flexible and exhibits breathing behaviour with observed changes as large as 12% in the a- and b-axes (|Δa|, |Δb| < 1.8 Å) and 5.5% in the c-axis (|Δc| < 0.7 Å). Both the solvated SHF-81-DMF and activated/desolvated SHF-81 forms of the MOF exhibit linear negative thermal expansion (NTE), in which pores that run parallel to the c-axis expand in diameter (a- and b-axis) while contracting in length (c-axis) upon increasing temperature. Adsorption of CO2 gas at 298 K also results in linear negative expansion (Δa, Δb > 0; Δc < 0; ΔV > 0). The largest change in dimensions is observed during activation/desolvation from SHF-81-DMF to SHF-81 (Δa, Δb < 0; Δc > 0; ΔV < 0). Collectively the nine in situ diffraction experiments conducted suggest the breathing behaviour is continuous, although individual desolvation and adsorption experiments do not rule out the possibility of a gating or step at intermediate geometries that is coupled with continuous dynamic behaviour towards the extremities of the breathing amplitude.

13.
Gels ; 6(3)2020 Aug 05.
Article in English | MEDLINE | ID: mdl-32764292

ABSTRACT

Tailoring the properties of porous organic materials, such as resorcinol-formaldehyde gels, for use in various applications has been a central focus for many studies in recent years. In order to achieve effective optimisation for each application, this work aims to assess the impact of the various synthesis parameters on the final textural properties of the gel. Here, the formation of porous organic gels is modelled using a three-dimensional lattice-based Monte Carlo simulation. We model growth from monomer species into the interconnected primary clusters of a gel, and account for varying catalyst concentration and solids content, two parameters proven to control gel properties in experimental work. In addition to analysing the textural properties of the simulated materials, we also explore their fractal properties through correlation dimension and Hurst exponent calculations. The correlation dimension shows that while fractal properties are not typically observed in scattering experiments, they are possible to achieve with sufficiently low solids content and catalyst concentration. Furthermore, fractal properties are also apparent from the analysis of the diffusion path of guest species through the gel's porous network. This model, therefore, provides insight into how porous organic gels can be manufactured with their textural and fractal properties computationally tailored according to the intended application.

14.
Gels ; 6(3)2020 Jul 31.
Article in English | MEDLINE | ID: mdl-32751834

ABSTRACT

Resorcinol (R) and formaldehyde (F) gel synthesis has been well-studied along with alternative reagents. We present the synthesis of formaldehyde-based xerogels using chemically similar s-triazine precursors, with comparison to traditional analogues. The substitution ranges from tri-hydroxyl to tri-amine, with an intermediate species, allowing changing chemistry to be investigated. Each molecule (X) offers different acid/base properties, known to influence gel formation, as well as differences in crosslinking potential. Varying X/F ratios were selected to recreate the stoichiometry used in RF systems, where one represented higher F to match the increased reaction sites of the additives. X/C ratios were selected to probe different catalyst (C) ratios, while working within the range likely to produce viable gels. Results obtained show little impact for ammeline as an additive due to its similarity to resorcinol (activation sites and pKa); while melamine and cyanuric acid show differing behavior depending on the level of addition. Low concentrations show melamine to have the most impact due to increased activation and competition for formaldehyde; while at high concentrations, cyanuric acid is shown to have the greatest impact as it creates a more acidic environment, which diminishes textural character, possibly attributable to larger clusters and/or weaker cross-linking of the system.

15.
Gels ; 6(1)2020 Mar 02.
Article in English | MEDLINE | ID: mdl-32131423

ABSTRACT

This study investigates the synthesis of formaldehyde-based xerogels using alternative aromatic precursors, with comparison to traditional resorcinol-formaldehyde analogues, in order to alter the chemical composition of the resulting gels. By replacing resorcinol with aromatic amine molecules, i.e., ammeline, melamine and melem, each expected to undergo similar reactions with formaldehyde as the substituted species, we found that for all substituted gels, at low additive contents, the gel structure was compromised and non-porous materials were formed, as opposed to the most abundant monomers, and therefore, these additives seem to act as impurities at low levels. Working towards higher additive contents, melem monomers exhibited low solubility (~5%), even at elevated temperatures, thereby limiting the range to which melem could act as a substitute, while melamine could be incorporated up to ~40% under acidic conditions, with enhanced microporosity over this range. Pure gels were successfully synthesised from ammeline, but their performance was inferior to resorcinol-formaldehyde gels, while melamine-formaldehyde analogues required acidic reaction conditions but shrank considerably on sub-critical drying, adversely affecting the gel properties and demonstrating their lack of potential as sorbents. This demonstrates the potential for the inclusion of aminated aromatics within resorcinol-based gel systems, however, only as partial substitutes and not complete replacements.

16.
RSC Adv ; 9(35): 20065-20074, 2019 Jun 25.
Article in English | MEDLINE | ID: mdl-35514715

ABSTRACT

There has been significant research interest invested into the study of the formation and properties of porous organic materials, due to their widespread applications. However, present models in the literature do not fully explain the observations made for these systems, therefore, this work presents a model developed to fully capture growth from the monomeric species present in the initial stages of the gelation composition. In this work, we employ a two-dimensional lattice-based kinetic Monte Carlo model to investigate how growth processes impact the structural properties of model gels. Experimentally, gel growth is primarily controlled through catalyst concentration, which determines the density of species that are activated for rapid growth, and solids concentration; our model captures both of these dependencies. Increasing both solids content and percentage of activated monomers leads to a higher ratio of closed porosity, and higher values of accessible surface area with increasing level of activation. The generated structures are analysed for their fractal properties using a correlation dimension. Increasing both solids content and percentage of activated species leads to an increase in correlation dimension, which plateaus at a value of 2, independent of catalyst concentration, suggesting little structural change at high solid loadings, over 50%. The Hurst exponent of a random walker diffusing in the accessible pores shows the opposite trend, varying from ½ for unconstrained diffusion and reducing to ⅓ for diffusion through the pore network at the threshold of percolation. These characteristics support visual observations of increasing complexity and tortuosity of pore structures in the model cluster structures. The implications of these results, for the design of porous structures tailored to particular applications, are discussed.

17.
Chemosphere ; 202: 94-104, 2018 Jul.
Article in English | MEDLINE | ID: mdl-29554512

ABSTRACT

The herbicide terbuthylazine (TBA) has displaced atrazine in most of EU countries, becoming one of the most regularly used pesticides and, therefore, frequently detected in natural waters. The affinity of TBA for soil organic matter suggests prolonged contamination; degradation leads to the release of the metabolite desethylterbuthylazine (DET), which has higher water solubility and binds more weakly to organic matter compared to the parent compound, resulting in higher associated risk for contamination of groundwater resources. Additionally, TBA and DET are chemicals of emerging concern because of their persistence and toxicity towards aquatic organisms; moreover, they are known to have significant endocrine disruption capacity to wildlife and humans. Conventional treatments applied during drinking water production do not lead to the complete removal of these chemicals; activated carbon provides the greatest efficiency, whereas ozonation can generate by-products with comparable oestrogenic activity to atrazine. Hydrogen peroxide alone is ineffective to degrade TBA, while UV/H2O2 advanced oxidation and photocatalysis are the most effective processes for oxidation of TBA. It has been determined that direct photolysis gives the highest degradation efficiency of all UV/H2O2 treatments, while most of the photocatalytic degradation is attributed to OH radicals, and TiO2 solar-photocatalytic ozonation can lead to almost complete TBA removal in ∼30 min. Constructed wetlands provide a valuable buffer capacity, protecting downstream surface waters from contaminated runoff. TBA and DET occurrence are summarized and removal techniques are critically evaluated and compared, to provide the reader with a comprehensive guide to state-of-the-art TBA removal and potential future treatments.


Subject(s)
Herbicides/metabolism , Photolysis , Triazines/metabolism , Water Pollutants, Chemical/metabolism , Herbicides/analysis , Herbicides/chemistry , Herbicides/isolation & purification , Hydrogen Peroxide/chemistry , Oxidation-Reduction , Triazines/analysis , Triazines/chemistry , Triazines/isolation & purification , Water Pollutants, Chemical/analysis , Water Pollutants, Chemical/chemistry , Water Pollutants, Chemical/isolation & purification
18.
Article in English | MEDLINE | ID: mdl-29173038

ABSTRACT

In recent years, the presence of Endocrine Disrupting Chemicals (EDCs) in wastewater discharges from agricultural and industrial sources, [1] fresh- and estuarine-waters, as well as soils, has been reported in the literature. [2] Studies of adverse changes in wildlife, linked to environmental exposure to these substances, and the suggestion that humans could also be at similar risk of adverse health effects, [3-5] have raised concern for urgent action to understand and reduce such risks. 3,4-Dichloroaniline (3,4-DCA) has been recognized as an EDC, with regards to endocrine disruption data for both wildlife populations and human health. [5] 3,4-DCA is present in the environment as a product of the biodegradation of phenylurea and phenylcarbamate pesticides [6,7] ; furthermore, it can be introduced from industrial and municipal wastewater that is insufficiently purified, or via accidental spills. [8-10] Increasing concentrations of 3,4-DCA in soil and water are the result of its high persistence and accumulation, as well as its low biodegradability. [11,12] Hence, remediation techniques require in-depth study, especially when considering the low removal achieved by traditional activated sludge treatments, and the generation of carcinogenic trihalomethanes as a consequence of the chlorine oxidation methods frequently used in drinking water plants. [13] Fe0/H2O2 systems, photodegradation using doped TiO2, and the use of dielectric barrier discharge reactors, seem to be the most promising techniques for the removal of 3,4-DCA from water.


Subject(s)
Aniline Compounds/chemistry , Endocrine Disruptors/chemistry , Environmental Restoration and Remediation/methods , Water Pollutants, Chemical/chemistry , Biodegradation, Environmental , Environmental Exposure , Sewage/chemistry , Wastewater/chemistry
19.
Gels ; 4(2)2018 Apr 17.
Article in English | MEDLINE | ID: mdl-30674812

ABSTRACT

Influence of process parameters of resorcinol⁻formaldehyde xerogel manufacture on final gel structure was studied, including solids content, preparation/drying temperature, solvent exchange, and drying method. Xerogels produced using a range of solids content between 10 and 40 w/v% show improved textural character up to 30 w/v% with a subsequent decrease thereafter. Preparation/drying temperature shows a minimal threshold temperature of 55 °C is required to obtain a viable gel structure, with minimal impact on gel properties for further thermal increase. Improving the solvent exchange method by splitting the same amount of acetone used in this phase over the period of solvent exchange, rather than in a single application, shows an increase in total pore volume and average pore diameter, suggesting less shrinkage occurs during drying when using the improved method. Finally, comparing samples dried under vacuum and at ambient pressure, there seems to be less shrinkage when using vacuum drying compared to ambient drying, but these changes are insubstantial. Therefore, of the process parameters investigated, improved solvent exchange seems the most significant, and it is recommended that, economically, gels are produced using a solids content of 20 w/v% at a minimum temperature of 55 °C, with regular solvent replenishment in the exchange step, followed by ambient drying.

20.
Nat Chem ; 9(9): 882-889, 2017 09.
Article in English | MEDLINE | ID: mdl-28837170

ABSTRACT

Understanding the behaviour of flexible metal-organic frameworks (MOFs)-porous crystalline materials that undergo a structural change upon exposure to an external stimulus-underpins their design as responsive materials for specific applications, such as gas separation, molecular sensing, catalysis and drug delivery. Reversible transformations of a MOF between open- and closed-pore forms-a behaviour known as 'breathing'-typically occur through well-defined crystallographic transitions. By contrast, continuous breathing is rare, and detailed characterization has remained very limited. Here we report a continuous-breathing mechanism that was studied by single-crystal diffraction in a MOF with a diamondoid network, (Me2NH2)[In(ABDC)2] (ABDC, 2-aminobenzene-1,4-dicarboxylate). Desolvation of the MOF in two different solvents leads to two polymorphic activated forms with very different pore openings, markedly different gas-adsorption capacities and different CO2 versus CH4 selectivities. Partial desolvation introduces a gating pressure associated with CO2 adsorption, which shows that the framework can also undergo a combination of stepped and continuous breathing.

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