1.
Chem Commun (Camb)
; (18): 2016-7, 2004 Sep 21.
Article
in English
| MEDLINE
| ID: mdl-15367953
ABSTRACT
(Z)-3-[2H1]-Phenylprop-2-enone is isomerised by hydroperoxide to an equimolar mixture of the (Z)- and (E)-isomers prior to epoxidation. Poly-(L)-leucine (10 mole %) accelerates the addition of hydroperoxide by an order of magnitude and sequesters hydroperoxide from THF.