Green and Sustainable Membranes: A review.

Membranes are ubiquitous tools for modern water treatment technology that critically eliminate hazardous materials such as organic, inorganic, heavy metals, and biomedical pollutants. Nowadays, nano-membranes are of particular interest for myriad applications such as water treatment, desalination, ion exchange, ion concentration control, and several kinds of biomedical applications. However, this state-of-the-art technology suffers from some drawbacks, e.g., toxicity and fouling of contaminants, which makes the synthesis of green and sustainable membranes indeed safety-threatening. Typically, sustainability, non-toxicity, performance optimization, and commercialization are concerns centered on manufacturing green synthesized membranes. Thus, critical issues related to toxicity, biosafety, and mechanistic aspects of green-synthesized nano-membranes have to be systematically and comprehensively reviewed and discussed. Herein we evaluate various aspects of green nano-membranes in terms of their synthesis, characterization, recycling, and commercialization aspects. Nanomaterials intended for nano-membrane development are classified in view of their chemistry/synthesis, advantages, and limitations. Indeed, attaining prominent adsorption capacity and selectivity in green-synthesized nano-membranes requires multi-objective optimization of a number of materials and manufacturing parameters. In addition, the efficacy and removal performance of green nano-membranes are analyzed theoretically and experimentally to provide researchers and manufacturers with a comprehensive image of green nano-membrane efficiency under real environmental conditions.

Reviewing and screening ionic liquids and deep eutectic solvents for effective CO2 capture.

CO2 capture is essential for both mitigating CO2 emissions and purifying/conditioning gases for fuel and chemical production. To further improve the process performance with low environmental impacts, different strategies have been proposed, where developing liquid green absorbent for capturing CO2 is one of the effective options. Ionic liquids (IL)/deep eutectic solvents (DES) have recently emerged as green absorbents with unique properties, especially DESs also benefit from facile synthesis, low toxicity, and high biodegradability. To promote their development, this work summarized the recent research progress on ILs/DESs developed for CO2 capture from the aspects of those physical- and chemical-based, and COSMO-RS was combined to predict the properties that are unavailable from published articles in order to evaluate their performance based on the key properties for different IL/DES-based technologies. Finally, top 10 ILs/DESs were listed based on the corresponding criteria. The shared information will provide insight into screening and further developing IL/DES-based technologies for CO2 capture.

Fabrication of superhydrophobic coatings with self-cleaning properties on cotton fabric based on Octa vinyl polyhedral oligomeric silsesquioxane/polydimethylsiloxane (OV-POSS/PDMS) nanocomposite.

HYPOTHESIS: Wetting behavior of solid surfaces plays an important role in various industrials and even daily life applications. Controlling the surface wettability through fabricating strongly hydrophilic or hydrophobic properties is achieved by tailoring surface topography and chemical composition. Polyhedral oligomeric silsesquioxanes (POSSs) are a class of hybrid materials with the possibility of hydrophobicity enhancement through simultaneous increase in surface roughness and reduction of surface energy. EXPERIMENTS: In this study, octavinyl-POSS (OV-POSS) structures were utilized in fabrication of superhydrophobic cotton fabric. Coating was successfully performed through creating a two-layer topography via spraying method. In brief, surface roughness was enhanced by spraying a base layer of TiO2 sol over the surface followed by applying a nanocomposite layer composed of 0.02 wt% of POSS in polydimethylsiloxane (PDMS). FINDINGS: It was observed that, water contact angle (WCA) of pristine and TiO2 coated fabric was enhanced from 0° up to ∼168° using 0.02 wt% OV-POSS/PDMS nanocomposite with a water sliding angle (WSA) of <10°. According to the results, environmentally friendly nature of precursors, high thermal, mechanical and chemical stability, self-cleaning and anti-adhesion propertiesof the as-prepared coating and simple preparation method with no special post-treatment requirement, confirm that the as-prepared coating is perfect candidate for large-scaled applications.