Field-based soil-plant uptake measurements of natural radionuclides for key vegetables and ghaf leaves in Abu Dhabi.

With the thriving fossil fuel and nuclear based industries in the nation, radioecology has become necessary for the radiation safety and emergency-preparedness for the United Arab Emirates (UAE). Environmental radiation transport modelling in the UAE and the Arabian Peninsula are severely limited, as we discuss in this paper, due to lack of experiments specific to arid desert climates. To fill the missing gaps in the baseline arid region radioecological database, especially for the soil-plant uptake studies, rigorous field works have been conducted for the first time on the soil and plant in the farms and open fields of the UAE. We present Abu Dhabi based measurements of activity concentrations of radionuclides of natural origins, in soils, key vegetables (cucumber, tomato, and bell pepper), and leaves of ghaf - a prominent native tree. The empirical data are utilized to get the first published estimates of UAE-specific plant-soil concentration ratios (CR), measuring root uptake of radionuclides in nonleafy vegetables and native trees. Such systematic studies are very rare for arid sandy soils. For the 27 samples analyzed, the activity concentrations' (unit Bq kg-1) ranges are: 169-1746 for 40K, 12-19.5 for 226Ra, and 2.7-23.1 for 228Ra. Likewise, wide variability is seen in the averages of concentration ratios also, ranging in 1.05-4.94 for 40K, 0.14-1.82 for 226Ra, and 0.53-2.78 for 228Ra. A net bioaccumulation (concentration ratio >1) of some of these natural radionuclides is found in many samples, but no significant doses or hazard indices are found due to these three radionuclides in the UAE's soils and vegetations. The paper discusses the careful work through tens of field sampling exercises, well controlled sample processing, high resolution gamma spectrometry, and treatment of data from gamma counting rates to accumulated dose rate estimations.

Conceptualization of arid region radioecology strategies for agricultural ecosystems of the United Arab Emirates (UAE).

Since the last decade, ambitious nuclear power programmes have begun maturing in the Arab countries, most importantly in the United Arab Emirates (UAE). The region's environment and population, therefore, are prone to adverse, long-term impacts of radionuclide discharges. To calculate the associated exposure scenarios, to estimate doses and their consequences, and finally, to lay out a radiological emergency management plan, arid region radioecology is taking shape in the UAE as a major field of research. Geography, demography, food habits, weather, soil, water, flora, and fauna of the desert-marine regions are quite distinct from their temperate counterparts. This results in the need to increase the knowhows of environmental migration and bioaccumulation of radionuclides in the region's agricultural ecosystems. In this paper, we present a detailed review of the measured data from the UAE and nearby nations, generating insights for the soil radioactivity and soil-to-plant transfer phenomena under local arid conditions. In the literature, the radionuclide activity concentrations (in Bq kg-1) vary over five orders of magnitude depending on nuclide type, sample type, and locality. Variabilities over six orders of magnitude are observed for transfer parameters too, and in-depth studies on the transfer mechanisms are usually scarce. We discuss the recent progresses made in root and foliar uptake studies with methods relatively new to sandy soils, like controlled potting, and soil Kd measurements. Showing the serious gaps in the data and interpretations, we provide a justification for the immediate experimentation in the understudied aspects of radioecology in the UAE and in arid lands in general.

Solution-phase parallel synthesis of a 1140-member ureidothiophene carboxylic acid library.

A 1140-library of thiophene ureidoacids was synthesized by the reaction of a set of 60 primary or secondary amines with a number of 19 thieno[3,2-d]- or thieno[2,3-d][1,3]oxazine-2,4-diones. All compounds were obtained by a simple solution-phase combinatorial strategy on a 200-400-mg scale with over 70% yields and purities over 80%. Sixty library members chosen at random were successfully characterized by standard 1H NMR, HPLC/MS, and IR studies. Analgesic, antalgic, and antiinflammatory potential were investigated. The 1140-member ureidothiophene carboxylic acid library will be used in high-throughput screening assays.