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A rare example of a porous Ca-MOF for the controlled release of biologically active NO.

Miller, Stuart R; Alvarez, Elsa; Fradcourt, Lucie; Devic, Thomas; Wuttke, Stefan; Wheatley, Paul S; Steunou, Nathalie; Bonhomme, Christian; Gervais, Christel; Laurencin, Danielle; Morris, Russell E; Vimont, Alexandre; Daturi, Marco; Horcajada, Patricia; Serre, Christian.

Chem Commun (Camb) ; 49(71): 7773-5, 2013 Sep 14.

Article in English | MEDLINE | ID: mdl-23687655

ABSTRACT

A 1D-microporous 3D calcium tetracarboxylate MOF has been solvothermally prepared and its structure solved from single crystal data. It exhibits coordinatively unsaturated Ca(2+) Lewis acid sites able to trap and deliver nitric oxide at a biological level.

Subject(s)

Calcium/chemistry , Nitric Oxide/metabolism , Biocompatible Materials/chemistry , Biocompatible Materials/metabolism , Lewis Acids/chemistry , Porosity

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