1.
Chem Commun (Camb)
; 54(48): 6165-6168, 2018 Jun 12.
Article
in English
| MEDLINE
| ID: mdl-29809217
ABSTRACT
The first enantioselective total synthesis of eremophilane-type sesquiterpenoids, sagittacin E and related natural products, was achieved. This synthesis features an asymmetric desymmetrization by Shi asymmetric epoxidation, intramolecular aldol-type cyclization, allylic oxidation of a 1,4-diene compound, and stereoselective epoxidation.