Dynamics of a Quantum System Interacting with White Non-Gaussian Baths: Poisson Noise Master Equation.

Quantum systems are unavoidably open to their surrounding degrees of freedom. The theory of open quantum systems is thus crucial to understanding the fluctuations, dissipation, and decoherence of a quantum system of interest. Typically, the bath is modeled as an ensemble of harmonic oscillators, which yields Gaussian statistics of the bath influence on the quantum systems. However, there are also phenomena in which the bath consists of two-state systems, spins, or anharmonic oscillators; therefore, the non-Gaussian properties of the bath become important. Nevertheless, a theoretical framework to describe quantum systems under the influence of such non-Gaussian baths is not well established. Here, we develop a theory to describe quantum dissipative systems affected by Poisson noise properties of the bath, because the Lévi-Itô decomposition theorem asserts that Poisson noise is fundamental in describing arbitrary white noise beyond Gaussian properties. We introduce a quantum bath model that allows for the consistent description of dissipative quantum systems. The obtained master equation reveals non-Gaussian bath effects in the white noise regime, and provides an essential step toward describing open quantum dynamics under the influence of generic baths.

Superconducting-like Heat Current: Effective Cancellation of Current-Dissipation Trade-Off by Quantum Coherence.

Quantum coherence is a useful resource for increasing the speed and decreasing the irreversibility of quantum dynamics. Because of this feature, coherence is used to enhance the performance of various quantum information processing devices beyond the limitations set by classical mechanics. However, when we consider thermodynamic processes, such as energy conversion in nanoscale devices, it is still unclear whether coherence provides similar advantages. Here we establish a universal framework, clarifying how coherence affects the speed and irreversibility in thermodynamic processes described by the Lindblad master equation, and give general rules for when coherence enhances or reduces the performance of thermodynamic devices. Our results show that a proper use of coherence enhances the heat current without increasing dissipation; i.e., coherence can reduce friction. In particular, if the amount of coherence is large enough, this friction becomes virtually zero, realizing a superconducting-like "dissipation-less" heat current. Since our framework clarifies a general relation among coherence, energy flow, and dissipation, it can be applied to many branches of science from quantum information theory to biology. As an application to energy science, we construct a quantum heat engine cycle that exceeds the power-efficiency trade-off bound on classical engines and effectively attains the Carnot efficiency with finite power in fast cycles.

General Bound on the Performance of Counter-Diabatic Driving Acting on Dissipative Spin Systems.

Counter-diabatic driving (CD) is a technique in quantum control theory designed to counteract nonadiabatic excitations and guide the system to follow its instantaneous energy eigenstates, and hence has applications in state preparation, quantum annealing, and quantum thermodynamics. However, in many practical situations, the effect of the environment cannot be neglected, and the performance of the CD is expected to degrade. To arrive at general bounds on the resulting error of CD in this situation we consider a driven spin-boson model as a prototypical setup. The inequalities we obtain, in terms of either the Bures angle or the fidelity, allow us to estimate the maximum error solely characterized by the parameters of the system and the bath. By utilizing the analytical form of the upper bound, we demonstrate that the error can be systematically reduced through optimization of the external driving protocol of the system. We also show that if we allow a time-dependent system-bath coupling angle, the obtained bound can be saturated and realizes unit fidelity.

Shortcuts to Adiabatic Pumping in Classical Stochastic Systems.

Adiabatic pumping is characterized by a geometric contribution to the pumped charge, which can be nonzero even in the absence of a bias. However, as the driving speed is increased, nonadiabatic excitations gradually reduce the pumped charge, thereby limiting the maximal applicable driving frequencies. To circumvent this problem, we here extend the concept of shortcuts to adiabaticity to construct a control protocol which enables geometric pumping well beyond the adiabatic regime. Our protocol allows for an increase, by more than an order of magnitude, in the driving frequencies, and the method is also robust against moderate fluctuations of the control field. We provide a geometric interpretation of the control protocol and analyze the thermodynamic cost of implementing it. Our findings can be realized using current technology and potentially enable fast pumping of charge or heat in quantum dots, as well as in other stochastic systems from physics, chemistry, and biology.

Speed Limit for Classical Stochastic Processes.

We consider the speed limit for classical stochastic Markov processes with and without the local detailed balance condition. We find that, for both cases, a trade-off inequality exists between the speed of the state transformation and the entropy production. The dynamical activity is related to a time scale and plays a crucial role in the inequality. For the dynamics without the local detailed balance condition, we use the Hatano-Sasa entropy production instead of the standard entropy production. Our inequalities consist of the quantities that are commonly used in stochastic thermodynamics and explicitly show underlying physical mechanisms.

Path Integral Approach to Quantum Thermodynamics.

Work belongs to the most basic notions in thermodynamics but it is not well understood in quantum systems, especially in open quantum systems. By introducing a novel concept of the work functional along an individual Feynman path, we invent a new approach to study thermodynamics in the quantum regime. Using the work functional, we derive a path integral expression for the work statistics. By performing the ℏ expansion, we analytically prove the quantum-classical correspondence of the work statistics. In addition, we obtain the quantum correction to the classical fluctuating work. We can also apply this approach to an open quantum system in the strong coupling regime described by the quantum Brownian motion model. This approach provides an effective way to calculate the work in open quantum systems by utilizing various path integral techniques. As an example, we calculate the work statistics for a dragged harmonic oscillator in both isolated and open quantum systems.

Path integral approach to heat in quantum thermodynamics.

We study the heat statistics of a quantum Brownian motion described by the Caldeira-Leggett model. By using the path integral approach, we introduce a concept of the quantum heat functional along every pair of Feynman paths. This approach has the advantage of improving our understanding about heat in quantum systems. First, we demonstrate the microscopic reversibility of the system by connecting the heat functional to the forward and time-reversed probabilities. Second, we analytically prove the quantum-classical correspondence of the heat functional and their statistics, which allows us to obtain better intuitions about the difference between classical and quantum heat.

Universal Work Fluctuations During Shortcuts to Adiabaticity by Counterdiabatic Driving.

Counterdiabatic driving (CD) exploits auxiliary control fields to tailor the nonequilibrium dynamics of a quantum system, making possible the suppression of dissipated work in finite-time thermodynamics and the engineering of optimal thermal machines with no friction. We show that while the mean work done by the auxiliary controls vanishes, CD leads to a broadening of the work distribution. We derive a fundamental inequality that relates nonequilibrium work fluctuations to the operation time and quantifies the thermodynamic cost of CD in both critical and noncritical systems.

Work fluctuation and total entropy production in nonequilibrium processes.

Work fluctuation and total entropy production play crucial roles in small thermodynamic systems subject to large thermal fluctuations. We investigate a trade-off relation between them in a nonequilibrium situation in which a system starts from an arbitrary nonequilibrium state. We apply a variational method to study this problem and find a stationary solution against variations over protocols that describe the time dependence of the Hamiltonian of the system. Using the stationary solution, we find the minimum of the total entropy production for a given amount of work fluctuation. An explicit protocol that achieves this is constructed from an adiabatic process followed by a quasistatic process. The obtained results suggest how one can control the nonequilibrium dynamics of the system while suppressing its work fluctuation and total entropy production.

Work Fluctuation-Dissipation Trade-Off in Heat Engines.

Reducing work fluctuation and dissipation in heat engines or, more generally, information heat engines that perform feedback control, is vital to maximize their efficiency. The same problem arises when we attempt to maximize the efficiency of a given thermodynamic task that undergoes nonequilibrium processes for arbitrary initial and final states. We find that the most general trade-off relation between work fluctuation and dissipation applicable to arbitrary nonequilibrium processes is bounded from below by the information distance characterizing how far the system is from thermal equilibrium. The minimum amount of dissipation is found to be given in terms of the relative entropy and the Renyi divergence, both of which quantify the information distance between the state of the system and the canonical distribution. We give an explicit protocol that achieves the fundamental lower bound of the trade-off relation.

General achievable bound of extractable work under feedback control.

A general achievable upper bound of extractable work under feedback control is given, where nonequilibrium equalities are generalized so as to be applicable to error-free measurements. The upper bound involves a term which arises from the part of the process whose information becomes unavailable and is related to the weight of the singular part of the reference probability measure. The obtained upper bound of extractable work is more stringent than the hitherto known one and sets a general achievable bound for a given feedback protocol. Guiding principles of designing the optimal protocol are also suggested. Examples are presented to illustrate our general results.

Nonequilibrium equalities in absolutely irreversible processes.

We generalize nonequilibrium integral equalities to situations involving absolutely irreversible processes for which the forward-path probability vanishes and the entropy production diverges, rendering conventional integral fluctuation theorems inapplicable. We identify the mathematical origins of absolute irreversibility as the singularity of probability measure. We demonstrate the validity of the obtained equalities for several models.

Strong local passivity in finite quantum systems.

Passive states of quantum systems are states from which no system energy can be extracted by any cyclic (unitary) process. Gibbs states of all temperatures are passive. Strong local (SL) passive states are defined to allow any general quantum operation, but the operation is required to be local, being applied only to a specific subsystem. Any mixture of eigenstates in a system-dependent neighborhood of a nondegenerate entangled ground state is found to be SL passive. In particular, Gibbs states are SL passive with respect to a subsystem only at or below a critical system-dependent temperature. SL passivity is associated in many-body systems with the presence of ground state entanglement in a way suggestive of collective quantum phenomena such as quantum phase transitions, superconductivity, and the quantum Hall effect. The presence of SL passivity is detailed for some simple spin systems where it is found that SL passivity is neither confined to systems of only a few particles nor limited to the near vicinity of the ground state.

Integral quantum fluctuation theorems under measurement and feedback control.

We derive integral quantum fluctuation theorems and quantum Jarzynski equalities for a feedback-controlled system and a memory which registers outcomes of the measurement. The obtained equalities involve the information content, which reflects the information exchange between the system and the memory, and take into account the back action of a general measurement contrary to the classical case. The generalized second law of thermodynamics under measurement and feedback control is reproduced from these equalities.