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1.
Chem Rev ; 121(11): 6610-6653, 2021 06 09.
Article in English | MEDLINE | ID: mdl-33961414

ABSTRACT

The bidentate phosphine ligand 1,2-bis(di-tert-butylphosphinomethyl)benzene (1,2-DTBPMB) has been reported over the years as being one of, if not the, best ligands for achieving the alkoxycarbonylation of various unsaturated compounds. Bonded to palladium, the ligand provides the basis for the first step in the commercial (Alpha) production of methyl methacrylate as well as very high selectivity to linear esters and acids from terminal or internal double bonds. The present review is an overview covering the literature dealing with the 1,2-DTBPMB ligand: from its first reference, its catalysis, including the alkoxycarbonylation reaction and its mechanism, its isomerization abilities including the highly selective isomerizing methoxycarbonylation, other reactions such as cross-coupling, recycling approaches, and the development of improved, modified ligands, in which some tert-butyl ligands are replaced by 2-pyridyl moieties and which show exceptional rates for carbonylation reactions at low temperatures.

2.
Dalton Trans ; 42(20): 7345-53, 2013 May 28.
Article in English | MEDLINE | ID: mdl-23348096

ABSTRACT

A series of N-heterocyclic carbene (NHC)/PR3 palladium(II) and palladium(0) complexes has been synthesized and fully characterized. X-ray crystallographic data have allowed comparison of ligand steric properties. The NHC ligand was found to vary its steric properties as a function of the phosphine co-ligand. These complexes display interesting catalytic properties in the Suzuki-Miyaura reaction performed in aqueous media. The pre-catalyst [PdCl2(IPr)(XPhos)] (IPr = N,N'-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene; XPhos = 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl) was found to be the most efficient system, promoting the coupling of a wide range of aryl chlorides with boronic acids in aqueous media with a typical catalyst loading of 0.03 mol%.

4.
Chem Commun (Camb) ; 46(37): 6924-5, 2010 Oct 07.
Article in English | MEDLINE | ID: mdl-20730180

ABSTRACT

A method is described that makes use of easily prepared, inexpensive copper synthons as N-heterocyclic carbene (NHC) transfer agents to generate catalytically relevant gold and palladium complexes.


Subject(s)
Copper/chemistry , Heterocyclic Compounds/chemistry , Methane/analogs & derivatives , Organometallic Compounds/chemistry , Organometallic Compounds/chemical synthesis , Gold/chemistry , Methane/chemistry , Molecular Structure , Palladium/chemistry , Stereoisomerism
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