1.
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 8): m455-6, 2013.
Article
in English
| MEDLINE
| ID: mdl-24109278
ABSTRACT
The title dinuclear complex mol-ecule, [Cu2(C13H9N4)2(PF6)2], lies about an inversion center. The Cu(II) atom shows a square-pyramidal coordination geometry with the basal plane formed by four N atoms of the two bis-chelating 3,5-bis-(pyridin-2-yl)pyrazolate ions and with one F atom of the hexa-fluoro-phosphate ion in the apical position. Mol-ecules are stacked in a column along the a axis through C-Hâ¯F hydrogen bonds. The columns are further linked by other C-Hâ¯F hydrogen bonds, forming a three-dimensional network.