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J Am Chem Soc ; 127(42): 14540-1, 2005 Oct 26.
Article in English | MEDLINE | ID: mdl-16231884

ABSTRACT

The oxidized octaethyltetraphenylporphyrin (1, OETPP) and the corresponding newly prepared octaisobutyltetraphenylporphyrin (3, OisoBuTPP) could be isolated from the reaction of OETPPLi2 (or OisoBuTPPLi2) with SOCl2. The X-ray analysis and the characteristic UV-vis spectra of 1 and 3 revealed that these are the first examples of 16 pi nonaromatic porphyrins.


Subject(s)
Porphyrins/chemical synthesis , Crystallography, X-Ray , Models, Molecular , Molecular Structure , Porphyrins/chemistry
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