Isothermal drying kinetics of sewage sludge using weathered coal fly ash as adjuvant for agronomic application.

This study aims to evaluate the effect of weathered coal fly ash (CFA) as a drying adjuvant of sewage sludge (SS) to produce a soil amendment. The high amount of SS and CFA creates a complex waste management problem in many countries, requiring more research efforts. Towards a circular economy, CFA can be viewed as an anthropogenic inorganic by-product with valuable nutrients (e.g. K), which can be recovered in combination with SS (rich in organic matter, N, and P). Different temperatures (70, 85, 100, 115, and 130 °C) are tested to dry small SS cylinders, without and with 0.15 g CFA g-1 of SSwet basis (wb). By fitting appropriate models to the experimental drying curves, it is possible to observe an improvement of 1-17% in the diffusion coefficient and 7-19% in the kinetic constants, using CFA. The best drying conditions are achieved with CFA as an adjuvant at 130 °C, where the drying rate is 31.61 gH2O kg-1 SSwb min-1. Phytotoxicity and growth assays are performed to evaluate the effect of the produced materials in the soil. The product with SS and CFA shows the potential to improve soil condition due to (i) the organic matter, N, P, and K content, (ii) the lower phytotoxic effect when compared to raw SS; (iii) the soil pH correction. Thus, not only the addition of weathered CFA facilitates the drying of SS but also the final product has benefits to soil conditions.

Thermal dehydration of urban biosolids with green liquor dregs from pulp and paper mill.

This study aims to investigate the sewage sludge (SS) drying process by incorporating a by-product formed in the pulp and paper industry (green liquor dregs - GLD) as drying adjuvant. Through an innovative approach, the drying kinetics was modelled, and the final dried product was tested for soil applications. After the characterization phase, small cylinders of SS without and with 0.15 g GLD g SS-1wb (SS_GLD) were dried in isothermal conditions at 70, 100, and 130 °C. The experimental data were fitted by Fick's second law and thin-layer models, and good results were achieved in both cases (R2 > 0.98 and RMSE <0.05). Although only a slight improvement was observed, the best conditions for drying biosolids were found with the addition of GLD at 130 °C, where the drying rate was 30.88 gH2O kg-1 SSwb min-1. In this condition, a decrease of 8% in the energy required for moisture evaporation was observed. Regarding the phytotoxicity tests with Lepidium sativum L. (garden cress), 60% improvement in EC50 was noticed for the sample with GLD when compared to the raw SS. The dried product SS_GLD complied with the regulations for soil applications regarding the potentially toxic metals (Cr, Ni, Cu, Pb, Zn, and Cd), and promoted an increase in soil organic matter and pH. However, further and in-depth studies should be conducted to assess the potential of SS_GLD application in agricultural soil.

Analysis of potentially toxic metal constraints to apply sewage sludge in Portuguese agricultural soils.

The application of sewage sludge (SS) in the soil can be a valuable way to increase its content of organic matter. However, the concentration of potentially toxic metal (PTM) in both SS and soil can hinder this route of management. Thus, the main objective of this work was to evaluate the compliance with the restrictions related to PTM contained in SS from wastewater treatment plants (WWTP) for agricultural land application. The regulatory constraints associated with SS and soil in respect to PTM (Cd, Cr, Cu, Ni, Pb, and Zn) were analyzed. These metals showed a deleterious effect on germination of Lepidium sativum seeds, and their phytotoxicity may be ranked as Cd > Cu > Cr(VI) > Cr(III) ~ Zn ~ Ni > Pb. Portuguese SS samples from different WWTP, from a national sludge management operator, and from the literature were considered. The results revealed that the content of these metals, in general, complies with the regulatory threshold values. The content of PTM in the soil is not restrictive to receive SS in at least 90% of the national territory. The assessment of ecological risk based on the geoaccumulation index (Igeo), pollution index (PI), and potential ecological risk index (PERI) showed low risk for all metals. The exception was Igeo of Cd, Cu, and Zn, which presented moderate to high level of pollution. According to the state of the art, no significant negative impacts have been detected on human health and the environment due to SS applications in the soil. Thus, in a country with low carbon content in the land and whenever compliance with regulations is achieved, the main route for SS management may be agricultural soil.