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Phys Chem Chem Phys ; 13(46): 20615-9, 2011 Dec 14.
Article in English | MEDLINE | ID: mdl-21904767

ABSTRACT

Here we explore in silico an alternative to make planar eight π-electron bare ring systems with substitutions of some cyclooctatetraene ring carbon atoms by heavier group 14 elements. We found that the most stable eight membered rings with formulae C(4)Si(4)H(8), C(4)Ge(4)H(8), and C(4)Sn(4)H(8) have a perfect planar structure, enhancing delocalization energy as compared to cot.

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