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1.
Front Nutr ; 11: 1385232, 2024.
Article in English | MEDLINE | ID: mdl-38769988

ABSTRACT

In recent decades, scarcity of available resources, population growth and the widening in the consumption of processed foods and of animal origin have made the current food system unsustainable. High-income countries have shifted towards food consumption patterns which is causing an increasingly process of environmental degradation and depletion of natural resources, with the increased incidence of malnutrition due to excess (obesity and non-communicable disease) and due to chronic food deprivation. An urgent challenge is, therefore, to move towards more healthy and sustainable eating choices and reorientating food production and distribution to obtain a human and planetary health benefit. In this regard, legumes represent a less expensive source of nutrients for low-income countries, and a sustainable healthier option than animal-based proteins in developed countries. Although legumes are the basis of many traditional dishes worldwide, and in recent years they have also been used in the formulation of new food products, their consumption is still scarce. Common beans, which are among the most consumed pulses worldwide, have been the focus of many studies to boost their nutritional properties, to find strategies to facilitate cultivation under biotic/abiotic stress, to increase yield, reduce antinutrients contents and rise the micronutrient level. The versatility of beans could be the key for the increase of their consumption, as it allows to include them in a vast range of food preparations, to create new formulations and to reinvent traditional legume-based recipes with optimal nutritional healthy characteristics.

2.
Nat Commun ; 15(1): 3753, 2024 May 04.
Article in English | MEDLINE | ID: mdl-38704394

ABSTRACT

The European ammonia industry emits 36 million tons of carbon dioxide annually, primarily from steam methane reforming (SMR) hydrogen production. These emissions can be mitigated by producing hydrogen via water electrolysis using dedicated renewables with grid backup. This study investigates the impact of decarbonization targets for hydrogen synthesis on the economic viability and technical feasibility of retrofitting existing European ammonia plants for on-site, semi-islanded electrolytic hydrogen production. Results show that electrolytic hydrogen cuts emissions, on average, by 85% (36%-100% based on grid price and carbon intensity), even without enforcing emission limits. However, an optimal lifespan average well-to-gate emission cap of 1 kg carbon dioxide equivalent (CO2e)/kg H2 leads to a 95% reduction (92%-100%) while maintaining cost-competitiveness with SMR in renewable-rich regions (mean levelized cost of hydrogen (LCOH) of 4.1 euro/kg H2). Conversely, a 100% emissions reduction target dramatically increases costs (mean LCOH: 6.3 euro/kg H2) and land area for renewables installations, likely hindering the transition to electrolytic hydrogen in regions with poor renewables and limited land. Increasing plant flexibility effectively reduces costs, particularly in off-grid plants (mean reduction: 32%). This work guides policymakers in defining cost-effective decarbonization targets and identifying region-based strategies to support an electrolytic hydrogen-fed ammonia industry.

3.
Nat Food ; 2024 May 16.
Article in English | MEDLINE | ID: mdl-38755344

ABSTRACT

The current centralized configuration of the ammonia industry makes the production of nitrogen fertilizers susceptible to the volatility of fossil fuel prices and involves complex supply chains with long-distance transport costs. An alternative consists of on-site decentralized ammonia production using small modular technologies, such as electric Haber-Bosch or electrocatalytic reduction. Here we evaluate the cost-competitiveness of producing low-carbon ammonia at the farm scale, from a solar agrivoltaic system, or using electricity from the grid, within a novel global fertilizer industry. Projected costs for decentralized ammonia production are compared with historical market prices from centralized production. We find that the cost-competitiveness of decentralized production relies on transport costs and supply chain disruptions. Taking both factors into account, decentralized production could achieve cost-competitiveness for up to 96% of the global ammonia demand by 2030. These results show the potential of decentralized ammonia technologies in revolutionizing the fertilizer industry, particularly in regions facing food insecurity.

4.
Ind Eng Chem Res ; 63(13): 5901-5911, 2024 Apr 03.
Article in English | MEDLINE | ID: mdl-38586215

ABSTRACT

The equations governing gas flow dynamics are computationally challenging for energy network optimization. This paper proposes an efficient solution procedure to enable tractability for an hourly resolved yearly decision horizon. The solution procedure deploys linear and second-order cone gas flow models alternatively based on the length-diameter ratio of pipes, achieving maximum efficiency within accuracy limits. Moreover, it addresses the computational complexity of bidirectional pipe flows by fixing the associated integer variables according to a preceding optimization with a static flow approximation. The procedure also precisely aggregates parallel and serial pipes for increased efficiency. Mathematical derivations and single-pipe analyses substantiate the model selection criterion. Network optimizations validate the accuracy, success rate, and scalability of the procedure, achieving up to 3.1% cost savings compared to static models, enhancing the success rate by a minimum of 96%, and boosting computational efficiency up to 3 orders of magnitude over full dynamic models.

5.
Nutrients ; 16(8)2024 Apr 12.
Article in English | MEDLINE | ID: mdl-38674842

ABSTRACT

Ready-to-eat (RTE) and ready-to-heat (RTH) dishes are food items that help save time, physical energy, and mental effort in all food-related activities. Convenience of use, variability of supply, and adaptability to different consumption occasions have led to an increase of acceptance among consumers through the years. Specialized databases can help in this context, where food composition databases can provide information and data to create sustainable nutritional models by reducing the now growing number of chronic diseases. This paper aims at developing a database of LanguaLTM and FoodEx2 codes of 50 food preparations and ready-to-eat dishes designed for consumption outside the home. LanguaLTM, as well as FoodEx2, are classification and description systems for indexing, in the sense of a systematic description, of foods based on a hierarchical model (parent-child relationship), thus facilitating the international exchange of data on food composition, consumption, assessing chronic and/or acute exposure to a certain agent, and not least the assessment of nutrient intake. The database, here presented, consists of the codes of fifty ready-to-eat products present on the market in Italy, obtained by using the two mostly commonly used and widely recognized coding systems: LanguaLTM and FoodEx2. This database represents a tool and a guideline for other compilers and users to apply coding systems to ready-to-eat products. Moreover, it can be represented a resource for several applications, such as nutritional cards, nutritional facts, food labels, or booklet and brochures for promotion of food products, to be used at health and food nutrition interface, useful for consumers, dieticians, and food producers.


Subject(s)
Databases, Factual , Fast Foods , Humans , Fast Foods/analysis , Italy , Nutritive Value , Food Labeling
6.
Nat Commun ; 14(1): 5532, 2023 Sep 08.
Article in English | MEDLINE | ID: mdl-37684237

ABSTRACT

Proposals for achieving net-zero emissions by 2050 include scaling-up electrolytic hydrogen production, however, this poses technical, economic, and environmental challenges. One such challenge is for policymakers to ensure a sustainable future for the environment including freshwater and land resources while facilitating low-carbon hydrogen production using renewable wind and solar energy. We establish a country-by-country reference scenario for hydrogen demand in 2050 and compare it with land and water availability. Our analysis highlights countries that will be constrained by domestic natural resources to achieve electrolytic hydrogen self-sufficiency in a net-zero target. Depending on land allocation for the installation of solar panels or wind turbines, less than 50% of hydrogen demand in 2050 could be met through a local production without land or water scarcity. Our findings identify potential importers and exporters of hydrogen or, conversely, exporters or importers of industries that would rely on electrolytic hydrogen. The abundance of land and water resources in Southern and Central-East Africa, West Africa, South America, Canada, and Australia make these countries potential leaders in hydrogen export.

7.
Chemosphere ; 340: 139757, 2023 Nov.
Article in English | MEDLINE | ID: mdl-37574091

ABSTRACT

Relics of World War One (WW1) were buried in alpine glaciers around 100 years ago. Today, these are emerging from the ice due to widespread glacier retreat, and are in direct contact with glacial meltwater-fed streams. To address a possible emergent contamination, we quantified major and trace elements (M-TEs) by mass spectrometry in water and larvae of Diamesa zernyi from three glacial streams fed by glaciers differently impacted by the Italian Austro-Hungarian war, in the Adamello-Presanella mountain range (Italian Alps): Lares and Presena, the two main battlefields, and Amola, 8 km from the front. M-TEs in stream water were interpreted using the crustal enrichment factor (EFc) while larval uptake was quantified by adopting the bioaccumulation factor (BAF). Despite low M-TEs concentrations in the water, in a range between 1 ng L-1 (Ag, Ta) and 1-2 mg L-1 (Al, Fe, Mg), low to moderate enrichments (10 ≥ EFc≥ 6) were observed for Sb and U in Presena and for Ag, As, Bi, Cd, Li, Mo, Pb, Sb and U in Lares. In addition, M-TE mass concentrations in larvae were up to ninety thousand times higher than in water, from 20 to 50 ng g-1 dry weight (d.w.; for Bi, Sb, Ta, Tl) to 1-4 mg g-1 d.w. (for Al, Fe, Na, and Mg). Larvae from Lares accumulated the largest amount of metals and metalloids, including those mostly used in the manufacture of artillery shells (As, Cu, Ni, Pb, Sb; BAFs from 375 to about 11,500). This was expected as most of the WW1 battles in this mountain range were fought on the Lares glacier, where the greatest number of war relics are emerging. These results provide preliminary evidence of water contamination and bioaccumulation of metals and metalloids by glacial fauna as a possible legacy of WW1 in the Alps.


Subject(s)
Chironomidae , Trace Elements , Animals , Water/analysis , Lead/analysis , Environmental Monitoring/methods , Ice Cover/chemistry , Italy , Trace Elements/analysis
8.
Nat Commun ; 14(1): 3989, 2023 Jul 06.
Article in English | MEDLINE | ID: mdl-37414843

ABSTRACT

The European aviation sector must substantially reduce climate impacts to reach net-zero goals. This reduction, however, must not be limited to flight CO2 emissions since such a narrow focus leaves up to 80% of climate impacts unaccounted for. Based on rigorous life-cycle assessment and a time-dependent quantification of non-CO2 climate impacts, here we show that, from a technological standpoint, using electricity-based synthetic jet fuels and compensating climate impacts via direct air carbon capture and storage (DACCS) can enable climate-neutral aviation. However, with a continuous increase in air traffic, synthetic jet fuel produced with electricity from renewables would exert excessive pressure on economic and natural resources. Alternatively, compensating climate impacts of fossil jet fuel via DACCS would require massive CO2 storage volumes and prolong dependence on fossil fuels. Here, we demonstrate that a European climate-neutral aviation will fly if air traffic is reduced to limit the scale of the climate impacts to mitigate.


Subject(s)
Air Pollution , Aviation , Climate , Fossil Fuels
9.
Foods ; 12(10)2023 May 11.
Article in English | MEDLINE | ID: mdl-37238768

ABSTRACT

'Tonda Gentile Romana' and 'Tonda di Giffoni' (Corylus avellana L.) are two Italian hazelnut cultivars, recognized under the quality labels "Protected Designation of Origin" (PDO) and "Protected Geographical Indication" (PGI), respectively. Hazelnut seeds are characterized by a complex microstructure and the presence of different physical compartments. This peculiarity has been studied and evidenced by Time Domain (TD) Nuclear Magnetic Resonance (NMR) experiments. This technique allowed the assessment of the presence of different diffusion compartments, or domains, by evaluating the distribution of the spin-spin relaxation time (T2).The aim of this research was to develop a method based on 1H NMR relaxometry to study the mobility in fresh hazelnut seeds ('Tonda di Giffoni' and 'Tonda Gentile Romana'), in order to determine differences in seed structure and matrix mobility between the two cultivars. TD-NMR measurements were performed from 8 to 55 °C in order to mimic post-harvest processing as well the microscopic textural properties of hazelnut. The Carr-Purcell-Meiboom-Gill (CPMG) experiments showed five components for 'Tonda Gentile Romana' and four components for 'Tonda di Giffoni' relaxation times. The two slowest components of relaxation (T2,a about 30-40% of the NMR signal, and T2,b about 50% of the NMR signal) were attributed to the protons of the lipid molecules organized in the organelles (oleosomes), both for the 'Tonda Gentile Romana' and for the 'Tonda di Giffoni' samples. The component of relaxation T2,c was assigned to cytoplasmic water molecules, and showed a T2 value dominated by diffusive exchange with a reduced value compared to that of pure water at the same temperature. This can be attributed to the water molecules affected by the relaxation effect of the cell walls. The experiments carried out as a function of temperature showed, for 'Tonda Gentile Romana', an unexpected trend between 30 and 45 °C, indicating a phase transition in its oil component. This study provides information that could be used to strengthen the specifications underlying the definitions of "Protected Designation of Origin" (PDO) and "Protected Geographical Indication" (PGI).

10.
iScience ; 26(5): 106750, 2023 May 19.
Article in English | MEDLINE | ID: mdl-37250341

ABSTRACT

Following the disruption of Russian natural gas flows to Europe, we investigate the impact of collaborative and selfish behavior of European countries to tackle energy scarcity and supply electricity, heat, and industrial gas to end users. We study how the operation of the European energy system will need to adapt to the disruption and identify optimal strategies to overcome the unavailability of Russian gas. Those strategies include diversifying gas imports, shifting energy generation to non-gas-based technologies, and reducing energy demands. Findings suggest that: (1) selfish behavior of Central European countries exacerbates the energy scarcity for many Southeastern European countries; (2) proactive collaborative energy savings, together with a mild winter, can fully relieve the stress of the gas shortage; (3) diversification of gas imports leads to bottlenecks in the gas network, especially in Southeastern Europe; and (4) electricity generation is mostly shifted to coal-based power plants, causing higher carbon emissions.

11.
Molecules ; 28(10)2023 May 22.
Article in English | MEDLINE | ID: mdl-37241990

ABSTRACT

Chlorophyll pigments are thought to be responsible for the highly appreciated green color of unfermented Castelvetrano-style table olives, but no studies have considered the effects of a controlled addition of copper during storage or packaging at the industrial level. For this purpose, chlorophyll derivatives were analyzed in Nocellara cultivar table olives debittered industrially using the Castelvetrano method, via means of HPLC and MS analyses, following the addition of copper in alkaline brines stored at 4 °C for 3 months in 220 L barrels, and during the subsequent storage in acid brines in commercial 400 g packages at 4 °C for up to 18 months. The presence of copper in storage or in packaging brines both contributed significantly to maintaining the green color of the olives, which was associated with a specific pattern of chlorophyll derivatives, as evidenced by principal component analysis. Notably, re-greening was rapidly achievable also for olives that had yellowed for 18 months at a copper concentration below the limit of EU legislation. Finally, by means of PCA, we also demonstrated that a short-term thermic treatment can work as an accelerated predictive tool in determining the fate of chlorophyll derivatives.


Subject(s)
Copper , Olea , Copper/analysis , Chlorophyll/analysis , Salts , Fermentation
12.
Int J Sports Med ; 44(11): 820-829, 2023 Oct.
Article in English | MEDLINE | ID: mdl-37094810

ABSTRACT

Data from recent studies suggest that whole-body electromyostimulation (WB-EMS) is a time-effective and tailored intervention for chronic lower back pain (CLBP). The aim of this non-randomized controlled study was to compare the efficacy of a WB-EMS training and the association between WB-EMS specific training with passive stretching (Well Back System, [WBS]) on CLBP. Forty patients with CLBP, 43-81 years old, were assigned to one of the two groups: WB-EMS (n=20) and WB-EMS+WBS (n=20). Both groups completed 12 sessions (8 weeks) of the WB-EMS protocol (2×20 minutes/week). The second group performed core-specific exercises with WB-EMS plus 6 extra stretching sessions (30 minutes each). Primary study endpoints were based on changes on the visual analogue scale (VAS) and changes on the Oswestry Low Back Disability Questionnaire (ODI). Secondary study endpoints were percentage changes of maximum trunk flexion (Sit & Reach, [SR]) and changes in consumption of painkillers. Both interventions significantly improved VAS, ODI, and SR values (p range: 0.04;<0.001). However, the change of VAS (-46% vs. -17%, p<0.001), ODI (-53% vs. -17%, p<0.001), and SR (+ 7 vs.+3 cm, p=0.001) were significantly higher in the WB-EMS+WBS group compared to the WB-EMS group. The working method with WB-EMS+WBS can be a joint-friendly, individualized form to decrease CLBP.


Subject(s)
Electric Stimulation Therapy , Low Back Pain , Humans , Adult , Middle Aged , Aged , Aged, 80 and over , Low Back Pain/therapy , Electric Stimulation Therapy/methods , Exercise Therapy/methods , Exercise/physiology , Body Composition/physiology
13.
Sci Total Environ ; 881: 163450, 2023 Jul 10.
Article in English | MEDLINE | ID: mdl-37061058

ABSTRACT

Antarctic ice cores have revealed the interplay between dust and climate in the Southern Hemisphere. Yet, so far, no continuous record of dust provenance has been established through the last deglaciation. Here, using a new database of 207 Rare Earth Element (REE) patterns measured in dust and sediments/soils from well-known potential source areas (PSA) of the Southern Hemisphere, we developed a statistical model combining those inputs to provide the best fit to the REE patterns measured in EPICA Dronning Maud Land (EDML) ice core (E. Antarctica). Out of 398 samples measured in the EDML core, 386 samples have been un-mixed with statistical significance. Combined with the total atmospheric deposition, we quantified the dust flux from each PSA to EDML between 7 and 27 kyr BP. Our results reveal that the dust composition was relatively uniform up until 14.5 kyr BP despite a large drop in atmospheric deposition at ∼18 kyr with a large contribution from Patagonia yielding ∼68 % of total dust deposition. The remaining dust was supplied from Australia (14-15 %), Southern Africa (∼9 %), New Zealand (∼3-4 %) and Puna-Altiplano (∼2-3 %). The most striking change occurred ∼14.5 kyr BP when Patagonia dropped below 50 % on average while low-latitude PSA increased their contributions to 21-23 % for Southern Africa, 13-21 % for Australia and âˆ¼ 4-10 % for Puna-Altiplano. We argue that this shift is linked to long-lasting changes in the hydrology of Patagonian rivers and to sudden acceleration of the submersion of Patagonian shelf at 14.5 kyr BP, highlighting a relationship between dust composition and eustatic sea level. Early Holocene dust composition is highly variable, with Patagonian contribution being still prevalent, at ∼50 % on average. Provided a good coverage of local and distal PSA, our statistical model based on REE pattern offers a straightforward and cost-effective method to trace dust source in ice cores.

14.
Foods ; 12(6)2023 Mar 20.
Article in English | MEDLINE | ID: mdl-36981253

ABSTRACT

Rapeseed meal (RSM), a by-product of rapeseed oil extraction, is currently used for low-value purposes. With a biorefinery approach, rapeseed proteins may be extracted and recovered for high-end uses to fully exploit their nutritional and functional properties. This study reports the application of RSM protein isolate, the main output of a biorefining process aimed at recovering high-value molecules from rapeseed meal, as a supplement to texture-modified (TM) food designed for elderly people with mastication and dysphagia problems. The compositional (macronutrients by Official Methods of Analyses, and mineral and trace element profiles using Inductively Coupled Plasma Optical Emission Spectrometry ICP-OES), nutritional and sensory evaluations of TM chicken breast, carrots and bread formulated without and with RSM protein supplementation (5% w/w) are hereby reported. The results show that the texture modification of food combined with rapeseed protein isolate supplementation has a positive impact on the nutritional and sensory profile of food, meeting the special requirements of seniors. TM chicken breast and bread supplemented with RSM protein isolate showed unaltered or even improved sensory properties and a higher nutrient density, with particular regard to proteins (+20-40%) and minerals (+10-16%). Supplemented TM carrots, in spite of the high nutrient density, showed a limited acceptability, due to poor sensory properties that could be overcome with an adjustment to the formulation. This study highlights the potentialities of RSM as a sustainable novel protein source in the food sector. The application of RSM protein proposed here is in line with the major current challenges of food systems such as the responsible management of natural resources, the valorization of agri-food by-products, and healthy nutrition with focus on elderly people.

15.
iScience ; 25(8): 104701, 2022 Aug 19.
Article in English | MEDLINE | ID: mdl-35874101

ABSTRACT

We propose a contractual setup, the proxy storage power purchase agreement (PPA), to foster the deployment of energy storage technologies. We define a threshold price below which the PPA becomes financially attractive for PPA buyers. We compute the threshold price for several storage technologies and configurations, in seven European countries. Such threshold prices overlap with the best-case forecast of the battery levelized cost of storage in 2030, indicating that proxy storage PPAs can play a role in enabling battery storage installations within the next ten years in Europe (generating about €180 million per year). Moreover, we identify UK and Germany as the most attractive countries for storage PPAs in Europe due to the high projected threshold prices and planned storage capacities. We show that revenues are maximized when coupling storage with wind energy generation rather than solar. This points to the design of policies that efficiently subsidize storage installations.

16.
Molecules ; 26(22)2021 Nov 10.
Article in English | MEDLINE | ID: mdl-34833884

ABSTRACT

Rapeseed meal (RSM), a by-product of oilseed extraction connected to the agri-food and biofuel sectors, is currently used as animal feed and for other low-value purposes. With a biorefinery approach, RSM could be valorized as a source of bio-based molecules for high-value applications. This study provides a chemical characterization of RSM in the perspective of its valorization. A qualitative study of main functional groups by fourier transform infrared (FTIR) spectroscopy was integrated with a chemical characterization of macronutrients, minerals by inductively coupled plasma optical emission spectrometry (ICP-OES), phenolic acids and lipid components by high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS), HPLC-diode-array detector (HPLC-DAD) and gas chromatography-mass spectrometry/flame ionization detector (GC-MS/FID). The study, conducted on different lots of RSM collected over a one-year period from an oil pressing factory serving a biofuel biorefinery, highlighted a constant quality over time of RSM, characterized by high protein (31-34%), fiber (33-40%) and mineral (5.5-6.8%) contents. Polyphenol extracts showed a significant antioxidant activity and a prevalence of sinapic acid, accounting for more than 85% of total phenolic acids (395-437 mg kg-1 RSM). Results highlight the potentialities of RSM for further valorization strategies that may lead to the creation of new cross-sector interconnections and bio-based value chains with improvement of the economics and sustainability of the bioeconomy sectors involved.


Subject(s)
Brassica napus/chemistry , Industrial Waste/analysis , Waste Management/methods , Animal Feed/analysis , Antioxidants/chemistry , Biofuels/analysis , Brassica napus/metabolism , Gas Chromatography-Mass Spectrometry/methods , Industrial Waste/economics , Minerals/chemistry , Spectroscopy, Fourier Transform Infrared/methods , Tandem Mass Spectrometry/methods , Waste Products/analysis
17.
J Sports Med Phys Fitness ; 61(5): 656-665, 2021 May.
Article in English | MEDLINE | ID: mdl-33480511

ABSTRACT

BACKGROUND: The aim of this study was to examine the fitness profile of the Italian national male Team-Handball players of different competitive level. METHODS: Forty-one male handball players from the senior (N.=21, height 1.90±0.06m, body mass 94.04±11.59kg, BMI 26.13±2.45) to the junior category (N.=20, height 1.86±0.06m, body weight 84.99±12.52kg, BMI: 24.56±3.35) Italian National Teams participated in this study. Players were tested for lower and upper limbs muscle strength, change of direction ability and specific endurance. Lower limbs explosive strength was assessed with squat (SJ) countermovement (CMJ), stiff leg (stiffness) jumps. Explosive strength was assessed by measuring kinematic aspects of squat and bench exercises. Change of direction ability was assessed with the 505 test. The Yo-Yo intermittent recovery test (YYIR1) was considered for specific endurance. RESULTS: Large and significant differences (d>1; partial η2>0.14; P<0.01) between senior and junior national team players were found in anthropometrics, jumping, power, sprint, agility, and aerobic fitness (junior body weight accounting for 10% less than the senior one, P=0.021; SJ and CMJ in juniors smaller than the seniors by 15% and 12%, P=0.000 and P=0.001, respectively). Similar differences were found among positional roles (goalkeepers, backs, centers, pivots, wings), suggesting practical implications for training. CONCLUSIONS: The differences between the competitive level and the playing role in relevant handball performance were reported in Italian national team players. The magnitude of the differences suggests the need of individual training approach when dealing with the young handball players.


Subject(s)
Athletic Performance/physiology , Competitive Behavior/physiology , Physical Fitness , Sports/physiology , Body Height , Body Mass Index , Exercise Test , Humans , Italy , Lower Extremity/physiology , Male , Motor Skills/physiology , Muscle Strength , Physical Conditioning, Human , Upper Extremity/physiology , Young Adult
18.
J Sports Med Phys Fitness ; 60(8): 1072-1080, 2020 Aug.
Article in English | MEDLINE | ID: mdl-32955833

ABSTRACT

BACKGROUND: This study aims at describing and comparing each other male and female soccer players kicking instep a stationary ball. The different measures we collected by the 3D motion capture system Movit G1 and the High-Speed Camera (240 fps) were considered as dependent variables, whereas the gender was considered as the independent one. METHODS: Twenty soccer well trained non-professional players: 10 men (age: 25.3±6.5 yrs; height 1.80±0.07 m; body mass 76.9±13.2 kg) and 10 women (age: 19±3.34 yrs; height 1.64±0.07 m; body mass 58.2±7.2 kg) volunteered to participate in the study. RESULTS: Gender differences were found, with a statistical significance (P<0.05) or interesting magnitude (Cohen d>0.5). The most relevant ones were the differences in hip extension of the kicking leg when the foot of the supporting one touches the ground, just before the impact on the ball (independent sample t-Test; P=0.03; Cohen d=1.64) and the speed of the ball, reached immediately after kicking (P<0.001;d=1.23). CONCLUSIONS: These results, together with the greater pelvic acceleration shown by men compared to women, highlight the need to develop a gender-differentiated training model, in order to customize the kicking technique in women and to reduce the likelihood, currently higher than for men, of kicking related injuries.


Subject(s)
Lower Extremity/physiology , Soccer/physiology , Acceleration , Adult , Biomechanical Phenomena , Female , Foot/physiology , Hip/physiology , Humans , Knee/physiology , Male , Pelvis/physiology , Sex Characteristics , Sex Factors , Time and Motion Studies , Young Adult
19.
Molecules ; 25(15)2020 Aug 03.
Article in English | MEDLINE | ID: mdl-32756471

ABSTRACT

First-generation biofuel biorefineries may be a starting point for the development of new value chains, as their by-products and side streams retain nutrients and valuable molecules that may be recovered and valorized for high-value applications. This study provides a chemical characterization of post-fermentation corn oil and thin stillage, side streams of dry-grind corn bioethanol production, in view of their valorization. An overall long-term study was conducted on the two co-products collected over 1 year from a bioethanol plant. Water content, acid value, sedimentation, mineral composition, and fatty acid profiles were analyzed on post-fermentation corn oil. Results highlighted that its acid value was high (19.72-24.29 mg KOH/g), indicating high levels of free fatty acids, but stable over the year due to standardized operating conditions. The fatty acid profile was that typical of corn oil, with a prevalence of linoleic (54-59% of total fatty acids) over oleic (23-27%) and palmitic (12-17%) acids. Macronutrients, fatty acid, and mineral profiles were investigated in thin stillage. Results revealed the acidic pH (4.05-4.68) and high dilution (90-93% water) of this side stream. The dry mass was composed of fats (19-30%), proteins (8.8-12.8%), ash (8.7-9.5%), and fiber (7.3-9.8%). The concomitant presence of a variegate complex of molecules of nutritional interest in corn bioethanol co-products, with several potential high-value market applications, make the perspective of their recovery a promising strategy to create new cross-sector interconnections according to circular economy principles.


Subject(s)
Biofuels , Corn Oil/metabolism , Zea mays/metabolism , Batch Cell Culture Techniques , Corn Oil/chemistry , Hydrogen-Ion Concentration , Linoleic Acid/analysis , Minerals/analysis , Oleic Acid/analysis , Palmitic Acid/analysis , Zea mays/chemistry
20.
Int J Sports Med ; 41(11): 751-758, 2020 Oct.
Article in English | MEDLINE | ID: mdl-32485778

ABSTRACT

We investigated early effects of Whole-Body Electromyostimulation added to hypocaloric diet on metabolic syndrome features in sedentary middle-aged individuals. We randomly assigned 25 patients to Whole-Body Electromyostimulation plus caloric restriction or caloric restriction alone for 26 weeks. Anthropometrics, blood pressure, fasting glucose and insulin, HOMA-IR, glycated hemoglobin, lipids, uric acid, creatinphosphokynase, C-reactive protein were assessed. Body composition was evaluated with direct-segmental, multi-frequency Bioelectrical Impedance Analysis. Both groups lost approximately 10% of weight, with similar effects on waist circumference and fat mass. Change in free-fat mass was significantly different between groups (caloric restriction -1.5±0.2 vs. Whole-Body Electromyostimulation plus caloric restriction +1.1±0.4 kg, p=0.03). Whole-Body Electromyostimulation plus caloric restriction group experienced greater percent reductions in insulin (-45.5±4.4 vs. -28.2±3.6%, p=0.002), HOMA-IR (-51.3±3.2 vs. -25.1±1.8%, p=0.001), triglycerides (-22.5±2.9 vs. -4.1±1.6%, p=0.004) and triglycerides/HDL (p=0.028). Subjects trained with Whole-Body Electromyostimulation had also significant improvement in systolic pressure (138±4 vs. 126±7 mmHg, p=0.038). No discontinuations for adverse events occurred. In middle-aged sedentary subjects with the metabolic syndrome, Whole-Body Electromyostimulation with caloric restriction for 26 weeks can improve insulin-resistance and lipid profile compared to diet alone. Further studies are needed to ascertain long-term efficacy and feasibility of this approach in individuals with the metabolic syndrome.


Subject(s)
Caloric Restriction , Electric Stimulation Therapy/methods , Metabolic Syndrome/therapy , Anthropometry , Biomarkers/blood , Blood Glucose/metabolism , Cholesterol/blood , Cholesterol, HDL/blood , Creatine Kinase/blood , Diet, Reducing , Electric Stimulation Therapy/adverse effects , Female , Humans , Insulin/blood , Insulin Resistance , Male , Metabolic Syndrome/blood , Metabolic Syndrome/diet therapy , Middle Aged , Muscle, Skeletal/enzymology , Muscle, Skeletal/injuries , Proof of Concept Study , Triglycerides/blood , Weight Loss
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