ABSTRACT
Expression of concern for 'Acceleration of ammonium phosphate hydrolysis using TiO2 microspheres as a catalyst for hydrogen production' by Ayman H. Zaki et al., Nanoscale Adv., 2020, 2, 2080-2086, https://doi.org/10.1039/D0NA00204F.
ABSTRACT
Finding suitable non-expensive electrocatalyst materials for methanol oxidation is a significant challenge. Waste valorization of spent wastewater nanoadsorbents is a promising route toward achieving circular economy guidelines. In this study, the residual of layered double hydroxide (LDH) can be used as an electrocatalyst in direct methanol fuel cells as a novel approach. The Co-Ni-Zn-Fe LDH was prepared by the co-precipitation method followed by the adsorption of methyl orange (MO). Moreover, the spent adsorbent was calcined at different temperatures (200, 400, and 600 °C) to be converted to the corresponding mixed metal oxides (MMO). The prepared samples were characterized using XRD, FTIR, HRTEM, zeta potential, and hydrodynamic size measurements. The spent adsorbent was tested as an electro-catalyst for direct methanol electro-oxidation. The spent LDH/MO adsorbent showed a maximum current density of 6.66 mA/cm2 at a 50 mV/s scan rate and a 1 M methanol concentration. The spent MMO/MO adsorbent showed a maximum current density of 8.40 mA/cm2 at a 200 °C calcination temperature, 50 mV/s scan rate, and a 3 M methanol concentration. Both samples show reasonable stability over time, as indicated by the chronoamperometric response. Further nanoengineering of used nanoadsorbents could be a promising path to repurposing these wastes as electro-oxidation catalysts.
Subject(s)
Methanol , Wastewater , Hydroxides , Oxides , ZincABSTRACT
Titania microspheres are considered an adequate material with low cost and easily attainable pathways, and can be utilized in photocatalytic H2 production to solve the energy crisis. Spherical porous titanium dioxide materials, with nanostructure composition, were chemically synthesized from titanate nanotubes via a simple hydrothermal technique, then added as a catalyst to accelerate the route of ammonium phosphate hydrolysis for hydrogen production. The mechanism of sphere formation from titanate nanotubes is elucidated in detail through the current study. The prepared materials were applied as a photocatalyst to facilitate the separation and transfer of photoinduced electrons, while preventing the recombination of electron-hole pairs. Experimental results show that the obtained microspheres possess significantly enhanced photocatalytic hydrogen (H2) production performance. The amount of photocatalytic hydrogen product using the microspheres is found to be â¼2.5 fold greater than that of titanate nanotubes. Analytical techniques such as field-emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HR-TEM), simulated visible solar light and X-ray diffraction (XRD) were used for the evaluation and characterization of the developed products, as well as the elucidation of the route of hydrolysis in the hydrogen production process.