1.
Org Biomol Chem
; 14(36): 8433-7, 2016 Sep 28.
Article
in English
| MEDLINE
| ID: mdl-27529324
ABSTRACT
The first total synthesis aimed at the naturally occurring eicosanoid bicycle mucosin is reported. A practical route has been devised allowing the issues relating to the previous assignment of stereochemistry to be examined. X-ray crystallography was performed on a late stage intermediate to pinpoint the topological relationship displayed by the featured bicyclo[4.3.0]non-3-ene scaffold.