1.
RSC Adv
; 8(25): 13643-13648, 2018 Apr 11.
Article
in English
| MEDLINE
| ID: mdl-35539348
ABSTRACT
A highly efficient room-temperature borylation strategy of aryl chlorides is described. Utilizing Buchwald's second-generation preformed catalyst, boronate esters were obtained for a wide range of substrates in high yield. The method was also applied to Suzuki-Miyaura cross-coupling reaction in a one-pot two-step sequential manner, providing a facile and convenient access to the direct synthesis of biaryl compounds from aryl chlorides.