ABSTRACT
Hydrogel sensors are fascinating as flexible sensors and electronic skin due to their excellent biocompatibility and structure controllability. However, developing conductive hydrogels possessing both excellent mechanical and antifreezing properties for environmental-adaptive sensors remains a challenge. Herein, a strategy of combining betaine and metal ions to construct poly(acrylic acid) (PAA)-based high-conductive hydrogels has been reported. PAA-Al3+/betaine hydrogels with high toughness and antifreezing property were prepared by a one-step UV curing method. Their high toughness is attributed to the coordination of metal ions with the carboxylic groups in PAA, the interaction of betaine with PAA, and the formation of hydrogen bonds between them and water molecules. Moreover, the significant antifreezing property is due to the reduction of free water in the hydrogel. This, in turn, is attributed to the hydration of metal ions and the synergistic hydrogen bonding between betaine and water. The experiments demonstrate that the hydrogel has excellent mechanical property, high conductivity, superior transparency, antiswelling property, antipuncture as well as shape memory properties, and especially, low cytotoxicity. It can be used as a sensor for motion detection and information recognition. This work provides new insights into the application of flexible sensors and human-machine interfaces in multienvironmental conditions.
ABSTRACT
Development of conductive hydrogels with high sensitivity and excellent mechanical properties remains a challenge for constructing flexible sensor devices. Herein, a universal strategy is presented for enhancing the mechanical strength of Mxene-based double-network hydrogels through metal ion coordination effects. Polyacrylamide (PAM)/sodium alginate (SA)/Mxene double-network (PSM-DN) hydrogels were prepared by metal ion impregnation of PAM/SA/Mxene (PSM) hydrogels. High electrical conductivity is achieved due to MXene nanosheets, while the strong coordination bond between metal ions and SA constructs a second network that increases the mechanical strength of the hydrogel by an order of magnitude. Mechanical tests demonstrated that the elastic modulus of hydrogels matches that of human tissues. Hence, they can be used as a highly sensitive electronic skin sensor to recognize the movement of different joints in humans and also as a pressure sensing interface to recognize characters for anticounterfeiting and information transfer. This work can promote the practical application of conductive hydrogels in high-tech fields, such as flexible electronic skin and interface interaction.
